Dissolved major and trace elements in meteoric depositions on the flanks of Mt. Etna (Italy): the impact of volcanic activity on the environment

In the framework of the “Save the Etna World” research project, which investigates the impact of the volcanic activity on the surrounding environment, three bulk collectors were deployed on the flank of the Mt. Etna volcano to collect the meteoric depositions. The sampling sites were at distances between 5.5 and 13 km from the summit vents of the volcano on its eastern flank, that is the most exposed to the volcanic plume due to the high-altitude prevailing winds direction. The sites were selected in order to have a gradient of exposition with respect to the volcanic emissions, the most exposed being CIT, the intermediate ILI and the least NIC. Samples were collected monthly from July 2017 to July 2018 and analysed for major ions and for a large suite of trace elements. The influence of volcanic emissions is evidenced by the low pH of the collected depositions in the most exposed site, showing values mostly below 3.5 and never exceeding 5.72. The lowest values are related to high fluoride, chloride and sulfate concentrations in the collected water, deriving from the acid gases (HF, HCl and SO2) of the volcanic plume. The other two sites show pH values in range from 3.95 to 7.21. While the lowest values indicate a lower but significant volcanic influence, the highest values can be related to the dissolution of geogenic (mainly carbonate) particulate of local or regional (Saharan) origin. The latter process is evidenced by high concentrations of Ca and HCO3 in the samples with the highest pHs. Trace elements show almost all higher concentrations in the most exposed site. Highly volatile elements like Pb, Te and Tl, which are known to have strong enrichment factors in volcanic plumes with respect to the average upper crust composition, are found at CIT at concentrations always at least one order of magnitude higher than at NIC. Also lithophile elements like Si, Al, Ti and Fe are sometimes strongly enriched at CIT deriving from the interaction of the acid gases of the plume with the occasionally emitted volcanic ash. These new results confirm the importance of meteoric deposition as main carrier of volcanogenic elements to earth’s surface. “Etna World” is a fascinating natural laboratory, and the study of atmospheric depositions in this peculiar environment allows to understand better the general processes that influence the cycles of trace metals. Furthermore, the quantitative estimation of both emission and deposition of volcanogenic elements is a key factor for complementary studies on the geochemical mobility of trace elements and their distribution between atmosphere, soils, vegetation, and lastly, animals and humans in active volcanic areas

Magmatic Signature in Submarine Hydrothermal Fluids Vented Offshore Ventotene and Zannone Islands (Pontine Archipelago, Central Italy)

Geochemical investigations carried out on submarine hydrothermal fluids vented offshore the Pontine Islands (Tyrrhenian Sea) revealed the existence of gas vents to the W of Zannone Island and SW of Ventotene Island. The geochemical features of the CO2-rich gas samples show a clear mantle-derived signature with3He/4He of 3.72-3.75 Ra and 1.33 Ra at Zannone and Ventotene, respectively. Gas geochemistry denotes how CO2-rich gases undergo fractionation processes due to CO2dissolution to a variable extent favoring enrichment in the less soluble gas species, i.e., CH4, N2, and He. The carbon isotope composition of CO2, expressed asδ13C vs. V-PDB, ranges from -0.71 and -6.16‰ at Zannone to 1.93‰ at Ventotene. Preliminary geothermometric and geobarometric estimations indicate equilibrium temperatures in the range of 150-200°C at Zannone and >200°C at Ventotene besides H2O pressures in the range of 5 bar and 20 bar at Zannone and Ventotene, respectively. Although the latest volcanic activity at the Pontine Archipelago is dated Middle Pleistocene, the combination of the new geochemical information along with geothermometric estimations indicates that cooling magmas are likely releasing enough thermal energy to form an efficient hydrothermal system

Spontaneous urinary bladder rupture in a dog with lymphoplasmacytic cystitis

A 10-­ year-­ old male mixed-­ breed dog presented with vomiting and anuria. The dog was living indoors, and no trauma was reported by the owner. Ultrasonography and a retrograde urethrogram revealed the presence of a urinary bladder leakage. A celiotomy was performed to repair a urinary bladder tear, along with a biopsy of the urinary bladder wall. Histopathological features consisted of lymphoplasmacytic cystitis with haemorrhages and multifocal fibrotic areas within the muscular layers. Spontaneous rupture of the urinary bladder without evidence of trauma is a well-­ known, though rare, condition in human medicine. The chronic inflammation detected in the present case, along with fibrosis, caused the weakening of the urinary bladder wall, leading to perforation. This is the first documented veterinary case of spontaneous rupture of the urinary bladder secondary to chronic inflammation and highlights the importance of including this condition in the differential diagnosis of patients presenting with uroperitoneum without underlying trauma

Hazard Scenarios Related to Submarine Volcanic-Hydrothermal Activity and Advanced Monitoring Strategies: A Study Case from the Panarea Volcanic Group (Aeolian Islands, Italy)

Geohazards associated to submarine hydrothermal systems still represent a tricky enigma to face and solve for the scientific community. The poor knowledge of a submarine environment, the rare and scarce monitoring activities, and the expensive and sometimes complicated logistics are the main problems to deal with. The submarine low-energy explosion, which occurred last November 3, 2002, off the volcanic island of Panarea, highlighted the absence of any hazard scenario to be used to manage the volcanic crisis. The "unrest" of the volcanic activity was triggered by a sudden input of deep magmatic fluids, which caused boiling water at the sea surface with a massive CO2 release besides changes in the fluids' geochemistry. That event dramatically pushed scientists to develop new methods to monitor the seafloor venting activity. Coupling the information from geochemical investigations and data collected during the unrest of volcanic activity, we were able to (a) develop theoretical models to gain a better insight on the submarine hydrothermal system and its relationships with the local volcanic and tectonic structures and (b) to develop a preliminary submarine volcanic hazard assessment connected to the Panarea system (Aeolian Islands). In order to mitigate the potential submarine volcanic hazard, three different scenarios are described here: (1) ordinary hydrothermal venting, (2) gas burst, and (3) volcanic eruption. The experience carried out at Panarea demonstrates that the best way to face any submarine volcanic-hydrothermal hazard is to improve the collection of data in near real-time mode by multidisciplinary seafloor observatories and to combine it with periodical sampling activity

Flexibility Services to Minimize the Electricity Production from Fossil Fuels. A Case Study in a Mediterranean Small Island

The design of multi-carrier energy systems (MES) has become increasingly important in the last decades, due to the need to move towards more efficient, flexible and reliable power systems. In a MES, electricity, heating, cooling, water and other resources interact at various levels, in order to get optimized operation. The aim of this study is to identify the optimal combination of components, their optimal sizes and operating schedule allowing minimizing the annual cost for meeting the energy demand of Pantelleria, a Mediterranean island. Starting from the existing energy system (comprising diesel generators, desalination plant, freshwater storage, heat pumps and domestic hot water storages) the installation of solar resources (photovoltaic and solar thermal) and electrical storage were considered. In this way, the optimal scheduling of storage units injections, water desalination operation and domestic hot water production was deduced. An energy hub model was implemented using MATLAB to represent the problem. All equations in the model are linear functions, and variables are real or integer. Thus, a mixed integer linear programming algorithm was used for the solution of the optimization problem. Results prove that the method allows a strong reduction of operating costs of diesel generators also in the existing configuration

Challenges and Solutions for Designing a COVID-19 Vaccination Hub: A Simulation Approach

It is the intent of the work to support experts in the organization process of Covid-19 vaccination hubs. An approach based on Modelling & Simulation (M&S) is proposed and in particular, a simulation model of a real vaccination hub, located in South of Italy, has been developed. The simulation model recreates, with satisfactory accuracy, the evolution over the time of the real system and it has been used to analyze the system behavior under several operative scenarios. The generation of the alternative operative scenarios comes from the variation of multiple design parameters that affect multiple performance measures. The quantitative evaluation of the effects of the multiple design parameters on the multiple performance measures can be used as starting point to improve processes as well as to plan effectively available resources within vaccination hubs

Efficacy and Accuracy of Using Magnetic Seed for Preoperative Non-Palpable Breast Lesions Localization: Our Experience with Magseed

In this retrospective study we share our single-center experience using a magnetic seed for the preoperative localization of non-palpable breast lesions. Patients who underwent a preoperative localization with Magseed® (Endomagnetics, Cambridge, UK) placement between 2020 and 2022 were enrolled. Indications to Magseed placement have been established during multidisciplinary meetings prior to surgery and all patients underwent breast-conserving surgery (BCS). 45 patients were included. Magnetic seeds have been introduced under ultrasound guidance in 40 patients (88.9%) and under stereotactic guidance in 5 patients (11.1%). We registered a highly successful placement rate (97.8%), with only one case of migration (2.2%). After BCS, all the magnetic seeds were recovered (100% retrieval rate). The re-excision rate for positive margins was 0%. Our experience, with a highly successful placement and retrieval rate and a re-excision rate equal to 0%, is consistent with the encouraging literature published on Magseed so far, suggesting this technique to be extremely effective. Moreover, our single case of seed migration supports the existing data stating that Magseed migration is rare. In conclusion, despite acknowledging Magseed limitations, we highly value the advantages linked to this technique, and we, therefore, uphold its use

A framework for self-enforced optimal interaction between connected vehicles

This paper proposes a decision-making framework for Connected Autonomous Vehicle interactions. It provides and justifies algorithms for strategic selection of control references for cruising, platooning and overtaking. The algorithm is based on the trade-off between energy consumption and time. The consequent cooperation opportunities originating from agent heterogeneity are captured by a game-theoretic cooperative-competitive solution concept to provide a computationally feasible, self-enforced, cooperative traffic management framework

Shallow Hydrothermal vent system at Panarea Island (Italy): a multidisciplinary study based on geochemical, geophysical and biochemical aspects in an extreme marine environment

Exploration of Shallow Hydrothermal Vents (SHVs) is usually focused on analysis of major chemical species while few studies focused are focused on the fate of trace and Rare Earth Elements (REEs) and the consequences spread on the marine environment. Here, we show progress concerning trace elements and REE geochemistry and biochemical aspects about the natural system in the surrounding area of Panarea Island (Eolian Islands, Italy). Samples were collected from submerged vents at different depths and analyzed for major and trace elements and REEs from June 2017 to August 2022. Measured chemical-physical parameters, such as pH and Eh, span from 2.5 to 8.2 and from -292 to 254 mV, respectively, that express an inverse correlation compared to Fe, Al, Mn and REEs, revealing pH control precipitation/dissolution process of solid phases. A positive correlation is also observed for REEs and Fe-Al- Mn in fluid, showing simultaneous variations of these elements due to coprecipitation and adsorption onto the surface of oxyhydroxide of Fe, Al and Mn, involving scavenging process of REEs. Hydrothermal discharging fluids are responsible for generating Fe, Al and Mn-bearing minerals controlling the fractionation of REEs and trace elements.We propose a further multidisciplinary study involving geochemical, biochemical and geophysical observation, and analysis of the microbial community in two different seasons (May – August 2022) and the correlation with hydrothermal flow measurements data from a permanent multiparametric observatory (infrastructure of IPANEMA Project), located nearby the hydrothermal vent, known as Black Point (23m b.s.l.). The microbial community was investigated to understand microbial biodiversity and its role in the homeostasis of this extreme ecosystem. The metagenomic DNA was extracted from seawater, marine sediment and biofouling. The microbial community was determined by sequencing a bacterial marker gene (16S rRNA gene). We observed differences in hydrothermal flow corresponding to variations in the abundance of different phyla, showing that the microbial community changes in dependence on physical-chemical conditions and that each sample carries its bacterial fingerprint. The study of hydrothermal flow variations could give insights into how the microbial communities and hydrothermal areas interact and to what extent