Study of Metal/Polymer Interface of Parts Produced by a Hybrid Additive Manufacturing Approach

Acknowledgments This research work was supported by the Portuguese Foundation for Science and Technology (FCT) and Centro2020 through the Project reference: UID/Multi/04044/2013, PAMI - ROTEIRO/0328/2013 (Nº 022158) and Portuguese National Innovation Agency (ANI) through the Project reference POCI-01-0247-FEDER-017963, NEXT.parts – Next Generation of Advanced Hybrid Parts (co-promotion nº 17963).The additive manufacturing of multimaterial parts, e.g. metal/plastic, with functional gradients represents for current market demands a great potential of applications [1]. Metal Polymer parts combine the good mechanical properties of the metals with the low weight characteristics, good impact strength, good vibration and sound absorption of the polymers. Nevertheless, the coupling between metal and polymers is a great challenge since the processing factors for each one of them are very different. In addition, a system that makes the hybrid processing - metal/polymer - using only one operation is unknown [2, 3]. To overcome this drawback, a hybrid additive manufacturing system based on the additive technologies of SLM and SL was recently developed by the authors. The SLM and SL techniques joined enabling the production of a photopolymerization of the polymer in the voids of a 3D metal mesh previously produced by SLM [4]. The purpose of this work is the study on the metal/polymer interface of hybrid parts manufactured from the hybrid additive manufacturing system [5]. For this, a core of tool steel (H13) and two different types of photopolymers: one elastomeric (BR3D-DL-Flex) and another one rigid (BR3D-DL-Hard) are considered. A set of six samples for each one of metal core/polymer combination was manufactured and submitted to tensile tests.info:eu-repo/semantics/publishedVersio

The Use of Polypropylene and High-Density Polyethylene on Cork Plastic Composites for Large Scale 3D Printing

Acknowledgements This work is supported by the Fundação para a Ciência e a Tecnologia (FCT) and Centro2020 through the Project references: UID/Multi/04044/2013 and PAMI - ROTEIRO/0328/2013 (Nº 022158). In addition, the authors acknowledge the funding from the project World of Outstanding Wool and Wood (WOWW), POCI-01-0247-FEDER-017574 from the Portuguese National Innovation Agency. The authors gratefully acknowledge to Amorim Cork Composites for the cork powder. We thank Ana O. Tojeira and Ana R. Fonseca for the support provided in performing the laboratorial tests as Laboratory Managing Engineers.This work focuses on studying the possibility of 3D printing of composite materials composed by cork and a polymer matrix (CPC). Initially the cork was mixed with two types of polymers (HDPE and PP) in different proportions and later processed using extrusion and injection. The composites were tested to study the physical, chemical and mechanical properties. The material was then tested on a large-scale 3D printer to study its feasibility and the ability to produce new products through 3D printing. Attention was focused on the use of pure cork, varying the concentration of cork and coupling agent in thermoplastic matrix composites of PP and HDPE. It was demonstrated that the increase of 5wt.% of coupling agent in the two types of polymers significantly improved the mechanical properties and adhesion between the phases but the increase in cork concentration decreased mechanical properties and crystallinity. The CPCs with PP showed to have better mechanical properties, better aesthetic and internal structural quality, and easier processability than those with HDPE matrix. Nevertheless, the HDPE CPCs showed a high degree of crystallization. Concerning 3D printing, it was demonstrated the possibility of making new products based on natural cork fibers, showing promising results, although additional research is still needed to optimize the process.info:eu-repo/semantics/publishedVersio

Challenge clusters facing LCA in environmental decision-making—what we can learn from biofuels

Purpose Bioenergy is increasingly used to help meet greenhouse gas (GHG) and renewable energy targets. However, bioenergy’s sustainability has been questioned, resulting in increasing use of life cycle assessment (LCA). Bioenergy systems are global and complex, and market forces can result in significant changes, relevant to LCA and policy. The goal of this paper is to illustrate the complexities associated with LCA, with particular focus on bioenergy and associated policy development, so that its use can more effectively inform policymakers. Methods The review is based on the results from a series of workshops focused on bioenergy life cycle assessment. Expert submissions were compiled and categorized within the first two workshops. Over 100 issues emerged. Accounting for redundancies and close similarities in the list, this reduced to around 60 challenges, many of which are deeply interrelated. Some of these issues were then explored further at a policyfacing workshop in London, UK. The authors applied a rigorous approach to categorize the challenges identified to be at the intersection of biofuels/bioenergy LCA and policy. Results and discussion The credibility of LCA is core to its use in policy. Even LCAs that comply with ISO standards and policy and regulatory instruments leave a great deal of scope for interpretation and flexibility. Within the bioenergy sector, this has led to frustration and at times a lack of obvious direction. This paper identifies the main challenge clusters: overarching issues, application and practice and value and ethical judgments. Many of these are reflective of the transition from application of LCA to assess individual products or systems to the wider approach that is becoming more common. Uncertainty in impact assessment strongly influences planning and compliance due to challenges in assigning accountability, and communicating the inherent complexity and uncertainty within bioenergy is becoming of greater importance. Conclusions The emergence of LCA in bioenergy governance is particularly significant because other sectors are likely to transition to similar governance models. LCA is being stretched to accommodate complex and broad policy-relevant questions, seeking to incorporate externalities that have major implications for long-term sustainability. As policy increasingly relies on LCA, the strains placed on the methodology are becoming both clearer and impedimentary. The implications for energy policy, and in particular bioenergy, are large

Optimization of a Wood Plastic Composite for Architectural Applications

The actual demand for sustainable construction has fostered the research of alternative products made of new materials, such as composites based on renewable resources obtained directly from nature or, most importantly in this context, from the wastes of industries thus encouraging the implementation of recycling processes. This study reports the optimization of wood plastic composites (WPC) made of industrial residues of pine sawdust, high density polyethylene (HDPE) and maleic anhydride-grafted-polyethylene (PE-g-MA) as coupling agent. These composites were specifically designed for the production of an innovative shading system to apply in the forefront of buildings, thus requiring an adequate combination of material properties concerning resistance to weather conditions, with mechanical and functional performance of the final products. The composites were optimized to enable their production and the fabrication of the shutter units through sequential extrusion processing. The optimization of the composites started with a thorough characterization of the raw materials and the mixtures were prepared after analysing the effect of the concentration of pine sawdust in the polymeric matrix, with variable amounts of the coupling agent. Torque rheometry was used to determine the most adequate viscosities for extrusion processing. The composites with optimized contents of pine sawdust and additives were characterized using SEM, FTIR, DSC-TGA, tensile testing, measurements of water contact angle and water absorption capacity. This allowed determining the respective microstructure, chemical interactions, thermal stability, mechanical properties, surface wettability and swelling capacity

Integrating life-cycle assessment and multi-criteria decision analysis to compare alternative biodiesel chains

This is the author version of an article copyrighted by Springer. The journal version, after typesetting and proof revisions is available at: http://link.springer.com/article/10.1007/s10479-016-2329-

Cyclic plastic behaviour of 7075 aluminium alloy

This paper aims at studying the cyclic plastic behaviour of the 7075-T651 aluminium alloy under fully-reversed strain-controlled conditions. Tests are conducted under strain-control mode, at room temperature, in a conventional servo-hydraulic machine, from smooth samples, using the single step method, with strain amplitudes (/2) in the range ±0.5 to ±2.75%. This material has exhibited a mixed behaviour, i.e. cyclic strain-hardens at higher strain amplitudes (/2/>1.1%) and cyclic strain-softens at lower strain amplitudes (/2<1.1%). A linear relationship between the degree of cyclic strain-hardening and the strain amplitude has been established for higher strain amplitudes. Fatigue-ductility and fatigue-strength properties agree with those found in the open literature for the same loading condition

Fabrication of Poly(ε-caprolactone) Scaffolds Reinforced with Cellulose Nanofibers, with and without the Addition of Hydroxyapatite Nanoparticles

Biomaterial properties and controlled architecture of scaffolds are essential features to provide an adequate biological and mechanical support for tissue regeneration, mimicking the ingrowth tissues. In this study, a bioextrusion system was used to produce 3D biodegradable scaffolds with controlled architecture, comprising three types of constructs: (i) poly(ε-caprolactone) (PCL) matrix as reference; (ii) PCL-based matrix reinforced with cellulose nanofibers (CNF); and (iii) PCL-based matrix reinforced with CNF and hydroxyapatite nanoparticles (HANP). The effect of the addition and/or combination of CNF and HANP into the polymeric matrix of PCL was investigated, with the effects of the biomaterial composition on the constructs (morphological, thermal, and mechanical performances) being analysed. Scaffolds were produced using a single lay-down pattern of 0/90°, with the same processing parameters among all constructs being assured. The performed morphological analyses showed a satisfactory distribution of CNF within the polymer matrix and high reliability was obtained among the produced scaffolds. Significant effects on surface wettability and thermal properties were observed, among scaffolds. Regarding the mechanical properties, higher scaffold stiffness in the reinforced scaffolds was obtained. Results from the cytotoxicity assay suggest that all the composite scaffolds presented good biocompatibility. The results of this first study on cellulose and hydroxyapatite reinforced constructs with controlled architecture clearly demonstrate the potential of these 3D composite constructs for cell cultivation with enhanced mechanical properties

Cooperação entre a comunidade e o ensino superior

info:eu-repo/semantics/publishedVersio