Studying the electrochemical deposition process of molybdenum from aqueous solution of molybdate ions

In this study, the tracing of the electroreduction process of molybdate ions in aqueous media at different conditions is achieved for obtaining molybdenum metal in a simple and easy way. The kinetics and the mechanism of the electroreduction of molybdate ions are studied using cathodic polarization technique. It is observed that, the speed of the electroreduction process depends on the speed of the change of the cathodic potential sweep as well as on the temperature of the electrodeposition bath. Moreover, it is observed that, at the potential range from the stationary potential (Est = 0.25 V) to −0.7 V, the electroreduction of molybdate ions occurs into two steps. Moreover it is observed that, after −0.7 V the electroreduction process of molybdate is accompanying with evolution of hydrogen

Electrochemical behaviour of selenite ions in tartaric electrolytes

In recent years, a great interest has been emerged on electrochemical preparation of semiconductor films based on selenium. Therefore, a study of electrochemical reduction of selenium could be very important. In this work, the kinetics and mechanism of the electrochemical reduction of selenite ions on the Pt cathode have been studied in the electrolyte containing selenious and tartaric acids. The study shows that electroreduction of selenite ions from tartaric electrolytes proceeds in two stages. The effect of various factors on the cathodic reduction of selenium ions has also been studied. The effective activation energy was calculated using the polarization curves of the temperature dependence of the electroreduction process of selenite ions. It was established that the process of electroreduction under investigation is proceeding by mixed kinetics, at first by concentration and then by electrochemical polarization

1. Effect of empagliflozin on cardiovascular death in subgroups by age: Results from EMPA-REG outcome

Clinical Research. Presentation type: Poster Presentation. Introduction: Empagliflozin is a potent and selective SGLT2-I used in the treatment of T2DM. Methodology: Study design: Patients with T2DM and established CV disease, and estimated glomerular filtration rate (eGFR;) ⩾30 ml/min/1.73 m2 were randomized to receive empagliflozin 10 mg, 25 mg, or placebo once daily in addition to standard of care for T2DM and CV risk management. The trial continued until 691 patients experienced an adjudicated event included in the primary outcome: 3P-MACE Analyses. Outcomes were assessed in patients treated with ⩾1 dose of study drug CV death was analysed in the pooled empagliflozin group vs placebo in subgroups by baseline age Cumulative incidence function estimates were corrected for mortality as a competing risk. Results: The reduction in risk of CV death with empagliflozin vs placebo was consistent across age categories. Conclusion: Empagliflozin in addition to standard of care reduced the risk of CV death in patients with T2DM and high CV risk irrespective of age at baseline. Across age subgroups, reported adverse events were consistent with the known safety profile of empagliflozin. Greater proportions of patients had events consistent with genital infections with the empagliflozin than placebo in all age subgroups. Diabetic ketoacidosis adverse events were rare and balanced overall between the empagliflozin and placebo groups. Events consistent with volume depletion were comparable between empagliflozin and placebo groups, except for a slightly higher frequency with empagliflozin than placebo in patients aged ⩾75 years

Enhanced Nitrate Ions Remediation Using Fe0 Nanoparticles from Underground Water: Synthesis, Characterizations, and Performance under Optimizing Conditions

The presence of nitrates in water in large amounts is one of the most dangerous health issues. The greatest risk posed by nitrates is hemoglobin oxidation, which results in Methemoglobin in the human body, resulting in Methemoglobinemia. There are many ways to eliminate nitrates from underground water. One of the most effective and selective methods is using zero-valent iron (ZVI) nanoparticles. ZVI nanoparticles can be easily synthesized by reducing ferric or ferrous ions using sodium borohydride. The prepared ZVI nanoparticles were examined by scanning electron microscopy (SEM), energy dispersive X-ray spectroscopy (EDX), electron microscopy (TEM), X-ray diffraction (XRD), Brunauer–Emmett–Teller (BET) surface area, and zeta potential. We aim to eliminate or reduce the nitrates in water to be at the acceptable range, according to the world health organization (WHO), of 10.0 mg/L. Nitrate concentration in water after and before treatment is measured using the UV scanning method at 220 nm wavelength for the synthetic contaminated water and electrochemical method for the naturally contaminated water. The conditions were optimized for obtaining an efficient removing process. The removal efficiency reaches about 91% at the optimized conditions

Removal of the Harmful Nitrate Anions from Potable Water Using Different Methods and Materials, including Zero-Valent Iron

Drinking water containing nitrate ions at a higher concentration level of more than 10 mg/L, according to the World Health Organization (WHO), poses a considerable peril to humans. This danger lies in its reduction of nitrite ions. These ions cause methemoglobinemia during the oxidation of hemoglobin into methemoglobin. Many protocols can be applied to the remediation of nitrate ions from hydra solutions such as Zn metal and amino sulfonic acid. Furthermore, the electrochemical process is a potent protocol that is useful for this purpose. Designing varying parameters, such as the type of cathodic electrode (Sn, Al, Fe, Cu), the type of electrolyte, and its concentration, temperature, pH, and current density, can give the best conditions to eliminate the nitrate as a pollutant. Moreover, the use of accessible, functional, and inexpensive adsorbents such as granular ferric hydroxide, modified zeolite, rice chaff, chitosan, perlite, red mud, and activated carbon are considered a possible approach for nitrate removal. Additionally, biological denitrification is considered one of the most promising methodologies attributable to its outstanding performance. Among these powerful methods and materials exist zero-valent iron (ZVI), which is used effectively in the deletion process of nitrate ions. Non-precious synthesis pathways are utilized to reduce the Fe2+ or Fe3+ ions by borohydride to obtain ZVI. The structural and morphological characteristics of ZVI are elucidated using UV–Vis spectroscopy, zeta potential, XRD, FE-SEM, and TEM. The adsorptive properties are estimated through batch experiments, which are achieved to control the feasibility of ZVI as an adsorbent under the effects of Fe0 dose, concentration of NO3− ions, and pH. The obtained literature findings recommend that ZVI is an appropriate applicant adsorbent for the remediation of nitrate ions