Cation mono- and co-doped anatase TiO2_2 nanotubes: An {\em ab initio} investigation of electronic and optical properties

The structural, electronic, and optical properties of metal (Si, Ge, Sn, and Pb) mono- and co-doped anatase TiO$_{2}$ nanotubes are investigated, in order to elucidate their potential for photocatalytic applications. It is found that Si doped TiO$_{2}$ nanotubes are more stable than those doped with Ge, Sn, or Pb. All dopants lower the band gap, except the (Ge, Sn) co-doped structure, the decrease depending on the concentration and the type of dopant. Correspondingly, a redshift in the optical properties for all kinds of dopings is obtained. Even though a Pb mono- and co-doped TiO$_{2}$ nanotube has the lowest band gap, these systems are not suitable for water splitting, due to the location of the conduction band edges, in contrast to Si, Ge, and Sn mono-doped TiO$_{2}$ nanotubes. On the other hand, co-doping of TiO$_{2}$ does not improve its photocatalytic properties. Our findings are consistent with recent experiments which show an enhancement of light absorption for Si and Sn doped TiO$_{2}$ nanotubes.Comment: revised and updated, 23 pages (preprint style), 7 figures, 5 table

Thermodynamic properties and phase diagrams of spin-1 quantum Ising systems with three-spin interactions

The spin-1 quantum Ising systems with three-spin interactions on two-dimensional triangular lattices are studied by mean-field method. The thermal variations of order parameters and phase diagrams are investigated in detail. The stable, metastable and unstable branches of the order parameters are obtained. According to the stable conditions at critical point, we find that the systems exhibit tricritical points. With crystal field and biquadratic interactions, the system has rich phase diagrams with single reentrant or double reentrant phase transitions for appropriate ranges of the both parameters.Comment: 10 pages, 5 figure

Use of low-energy hydrogen ion implants in high-efficiency crystalline-silicon solar cells

The use of low-energy hydrogen implants in the fabrication of high-efficiency crystalline silicon solar cells was investigated. Low-energy hydrogen implants result in hydrogen-caused effects in all three regions of a solar cell: emitter, space charge region, and base. In web, Czochralski (Cz), and floating zone (Fz) material, low-energy hydrogen implants reduced surface recombination velocity. In all three, the implants passivated the space charge region recombination centers. It was established that hydrogen implants can alter the diffusion properties of ion-implanted boron in silicon, but not ion-implated arsenic

AMPHIBIAN DISTRIBUTION IN THE GEORGIA SEA ISLANDS: IMPLICATIONS FROM THE PAST AND FOR THE FUTURE

We summarized amphibian distributions for 12 coastal islands in Georgia, USA. Occurrence among islands was correlated with life history traits, habitats, island size, distance to other islands, and island geological age. Species’ distributions were determined from published literature. Island sizes and vegetation types were derived from 2011 Georgia Department of Natural Resources habitat maps, which included both federal and state vegetation classification systems. Species occurring on more islands tended to have greater total reproductive output (i.e., life span >4 years, and annual egg production >1,000 eggs) and adults had tolerance of brackish environs. Larger islands had great­er area of freshwater wetlands, predominantly short hydroperiod (<6 months). Species tied to long hydroperiod wetlands (>6 months) were more restricted in their distribution across islands. Overall, larger islands supported more species, but the correlation was weaker for geologically younger Ho­locene islands (age <11,000 years). While Euclidean distance between islands does not necessarily preclude inter-island dispersal, inhospitable habitat for amphibians (brackish tidal marshes and creeks interspersed with wide rivers) suggests that inter-island dispersal is very limited. The paucity of recent occurrence data for amphibians in this dynamic coastal region, let alone standardized annual moni­toring data, hinders efforts to model species’ vulnerability in a region susceptible to sea level rise and development pressure. The most common survey method, standardized amphibian vocal surveys, will detect Anuran reproductive efforts, but is unlikely to ascertain if breeding was successful or to detect salamanders. While it will not replace actual population data, consideration of critical life-history traits and breeding habitat availability can be used to direct management to support long-term species per­sistence in changing environs. Even common amphibians in coastal conservation areas of Georgia are vulnerable to increasing population isolation caused by unsuitable habitat

Non-Abelian Proca model based on the improved BFT formalism

We present the newly improved Batalin-Fradkin-Tyutin (BFT) Hamiltonian formalism and the generalization to the Lagrangian formulation, which provide the much more simple and transparent insight to the usual BFT method, with application to the non-Abelian Proca model which has been an difficult problem in the usual BFT method. The infinite terms of the effectively first class constraints can be made to be the regular power series forms by ingenious choice of $X_{\alpha \beta}$ and $\omega^{\alpha \beta}$-matrices. In this new method, the first class Hamiltonian, which also needs infinite correction terms is obtained simply by replacing the original variables in the original Hamiltonian with the BFT physical variables. Remarkably all the infinite correction terms can be expressed in the compact exponential form. We also show that in our model the Poisson brackets of the BFT physical variables in the extended phase space are the same structure as the Dirac brackets of the original phase space variables. With the help of both our newly developed Lagrangian formulation and Hamilton's equations of motion, we obtain the desired classical Lagrangian corresponding to the first class Hamiltonian which can be reduced to the generalized St\"uckelberg Lagrangian which is non-trivial conjecture in our infinitely many terms involved in Hamiltonian and Lagrangian.Comment: Notable improvements in Sec. I

Low Scale Non-universal, Non-anomalous U(1)'_F in a Minimal Supersymmetric Standard Model

We propose a non-universal U(1)'_F symmetry combined with the Minimal Supersymmetric Standard Model. All anomaly cancellation conditions are satisfied without exotic fields other than three right-handed neutrinos. Because our model allows all three generations of chiral superfields to have different U(1)'_F charges, upon the breaking of the U(1)'_F symmetry at a low scale, realistic masses and mixing angles in both the quark and lepton sectors are obtained. In our model, neutrinos are predicted to be Dirac fermions and their mass ordering is of the inverted hierarchy type. The U(1)'_F charges of the chiral super-fields also naturally suppress the mu term and automatically forbid baryon number and lepton number violating operators. While all flavor-changing neutral current constraints in the down quark and charged lepton sectors can be satisfied, we find that constraint from D0-D0bar turns out to be much more stringent than the constraints from the precision electroweak data.Comment: 21 pages, 2 figures; v2: discussion on sparticle mass spectrum included, 27 pages, 2 figure