Long-term performance of novel high-calcium one-part alkali-activated cement developed from thermally activated lime kiln dust

The traditional activation approach for alkali-activated cement AAC has several problems resulting mainly from the hazardous and corrosiveness of the alkaline chemicals, such as (NaOH, Na2SiO3), which in turn impede the utilisation of AAC in the construction fields. In this study, A second generation of alkali activated binder was developed using Metakaolin (MK) and natural pozzolan material (NP) (as a source of alumina-silicate), these materials were activated using high-calcium lime kiln dust as solid activator to transform the alumina-silicate crystalline phases to cementitious hydrated products. This was achieved with the aid of heat treatment of materials at different temperatures. Raw materials and final AAC samples were characterised using analytical methods, such X-Ray powder diffraction (XRD), Thermogravimetric Analysis (TG-DTA), Fourier Transform Infrared Spectroscopy (FTIR) and Scanning Electron Microscope (SEM). Additionally, long-term compressive strength, chemical and microstructural performance were investigated. The transformation of raw materials from crystalline to amorphous phases happened due to the effect of the heat treatment and the formation of stratlingite products in the final AAC paste, which were evidenced using the mentioned characterisation methods. The findings of the present study proved that the compressive strength of the new binder reached 27 MPa and 51 MPa after 28 and 180 days of curing, respectively, ensuring a progressive as well as a higher degree of alkali-activation and disappearance of unreacted alkaline substances in the final AAC products

Developing One-Part Alkali-Activated metakaolin/natural pozzolan Binders using Lime Waste as activation Agent

Among the several schemes that have been reported to be a satisfactory alternative to Portland cement is Alkali Activated Cement (AAC), which has recently started to gain greater consideration in construction sectors. Conventional two-part alkali activation has many drawbacks, including the activating solution being viscous, problematic and non-user friendly to handle. Thus, this research aims to produce a one-part alkali activated metakaolin/natural pozzolan, by using an earth alkaline source (rich in CaO) from waste material (lime kiln dust), as an activating precursor to break the alumina-silicate crystalline phases. Thermal treatment of materials at two levels of treatment (450°C and 950°C), was used as an assisted activation approach. Analytical techniques including X-Ray powder diffraction XRD, Thermogravimetric Analysis TG-DTA, Fourier Transform Infrared Spectroscopy FTIR and Scanning Electron Microscope SEM, were utilised to investigate the performance of the developed materials at a molecular level. Reduction of crystalline peaks as well as the appearance of new wollastonite minerals within the calcined lime kiln dust, contributed to the development of 27 MPa compressive strength after 28 days. The dissolution made through the pozzolanic reaction as well as thermal treatment evidently contributed to transform crystalline to amorphous phases

Production of Ternary Blend Binder as an Alternative to Portland Cement

Environmental pollution and the relatively high cost of waste disposal have been a major focus for scientists around the world, leading researchers to find a solution to reuse waste materials in different applications. Additionally, landfills are considered one of the biggest crisis facing the Iraqi government. Therefore, this study aims to present a new ternary mixture that consists of OPC in addition to Pulverized Fuel Ash (PFA), Ground Granulated Blast Furnace Slag (GGBS) by utilizing it as a partial substitution of cement. A new ternary mortar mixtures containing four substitution levels of cement with GGBS and PFA (0%, 30 %, 50% and 70% by weight) were carried out. The Ultrasonic Pulse Velocity (UPV) and compressive strength tests were adopted to show the influence of GGBS and PFA on mechanical features of cement mortar. Findings indicated that, the compressive strength values were reduced with increasing the GGBS and PFA proportions at all curing ages. For 70% replacement, the compressive strength values were the lowest values comparison with that for control specimens. In contrast, the GGBS and PFA had a negative and positive impacts on the UPV of mortar depending on the substitution ratio. At 30 % substitution levels, the velocity value was enhanced, while other substitution ratios affected negatively on the UPV values

Influence of High Volume RHA on Properties of Cement Mortar

This work study the impact of partial cement replacement by high volume Rice Husk Ash (RHA) on some characteristics of cement mortar like compressive strength and flexural strength at different ages. In this research, RHA was used in three different ratios (20, 40, and 60)% as a cement substitution and the findings were compared with control mixture (0% RHA). The findings demonstrated that the replacement of cement by RHA reduced the compressive strength of all selected ratios and the increase in the content of RHA lead to reduce compressive strength comparative to control sample with 100% cement as a binder at all ages. However, the flexural strength results indicated that the RHA in 20% showed approximately same results as control sample at early ages while increasing the curing period lead to improve flexural strength. Increasing RHA higher than 20% lead to decrease Flexural strength at all selected ages

Influence of acute pancreatitis on the in vitro responsiveness of rat mesenteric and pulmonary arteries

<p>Abstract</p> <p>Background</p> <p>Acute pancreatitis is an inflammatory disease characterized by local tissue injury and systemic inflammatory response leading to massive nitric oxide (NO) production and haemodynamic disturbances. Therefore, the aim of this work was to evaluate the vascular reactivity of pulmonary and mesenteric artery rings from rats submitted to experimental pancreatitis.</p> <p>Male Wistar rats were divided into three groups: saline (SAL); tauracholate (TAU) and phospholipase A₂(PLA₂). Pancreatitis was induced by administration of TAU or PLA₂from <it>Naja mocambique mocambique </it>into the common bile duct of rats, and after 4 h of duct injection the animals were sacrificed. Concentration-response curves to acetylcholine (ACh), sodium nitroprusside (SNP) and phenylephrine (PHE) in isolated mesenteric and pulmonary arteries were obtained. Potency (pEC₅₀) and maximal responses (E_MAX) were determined. Blood samples were collected for biochemical analysis.</p> <p>Results</p> <p>In mesenteric rings, the potency for ACh was significantly decreased from animals treated with TAU (about 4.2-fold) or PLA₂(about 6.9-fold) compared to saline group without changes in the maximal responses. Neither pEC₅₀nor E_MAXvalues for Ach were altered in pulmonary rings in any group. Similarly, the pEC₅₀and the E_MAXvalues for SNP were not changed in both preparations in any group. The potency for PHE was significantly decreased in rat mesenteric and pulmonary rings from TAU group compared to SAL group (about 2.2- and 2.69-fold, for mesenteric and pulmonary rings, respectively). No changes were seen in the E_MAXfor PHE. The nitrite/nitrate (NO_x^-) levels were markedly increased in animals submitted to acute pancreatitis as compared to SAL group, approximately 76 and 68% in TAU and PLA₂protocol, respectively.</p> <p>Conclusion</p> <p>Acute pancreatitis provoked deleterious effects in endothelium-dependent relaxing response for ACh in mesenteric rings that were strongly associated with high plasma NO_x^-levels as consequence of intense inflammatory responses. Furthermore, the subsensitivity of contractile response to PHE in both mesenteric and pulmonary rings might be due to the complications of this pathological condition in the early stage of pancreatitis.</p

Women’s, partners’ and healthcare providers’ views and experiences of assisted vaginal birth: a systematic mixed methods review

Background When certain complications arise during the second stage of labour, assisted vaginal delivery (AVD), a vaginal birth with forceps or vacuum extractor, can effectively improve outcomes by ending prolonged labour or by ensuring rapid birth in response to maternal or fetal compromise. In recent decades, the use of AVD has decreased in many settings in favour of caesarean section (CS). This review aimed to improve understanding of experiences, barriers and facilitators for AVD use. Methods Systematic searches of eight databases using predefined search terms to identify studies reporting views and experiences of maternity service users, their partners, health care providers, policymakers, and funders in relation to AVD. Relevant studies were assessed for methodological quality. Qualitative findings were synthesised using a meta-ethnographic approach. Confidence in review findings was assessed using GRADE CERQual. Findings from quantitative studies were synthesised narratively and assessed using an adaptation of CERQual. Qualitative and quantitative review findings were triangulated using a convergence coding matrix. Results Forty-two studies (published 1985–2019) were included: six qualitative, one mixed-method and 35 quantitative. Thirty-five were from high-income countries, and seven from LMIC settings. Confidence in the findings was moderate or low. Spontaneous vaginal birth was most likely to be associated with positive short and long-term outcomes, and emergency CS least likely. Views and experiences of AVD tended to fall somewhere between these two extremes. Where indicated, AVD can be an effective, acceptable alternative to caesarean section. There was agreement or partial agreement across qualitative studies and surveys that the experience of AVD is impacted by the unexpected nature of events and, particularly in high-income settings, unmet expectations. Positive relationships, good communication, involvement in decision-making, and (believing in) the reason for intervention were important mediators of birth experience. Professional attitudes and skills (development) were simultaneously barriers and facilitators of AVD in quantitative studies. Conclusions Information, positive interaction and communication with providers and respectful care are facilitators for acceptance of AVD. Barriers include lack of training and skills for decision-making and use of instruments