Comportamento do fósforo em solos argiluviados da Região do Alentejo: sorção de fosfato

O Encontro decorreu na Universidade do Algarve.O poster apresenta os resultaos de um estudo sobre o comportamento do fósforo em solos argiluviados da Região do Alentejo

Phosphate desorption in luvisols and solonetz from a Mediterranean region

Poster apresentado no 6th International Phosphorus Workshop, que decorreu em Sevilha de 27 de Setembro a 1 de Outubro de 2010.Transfer of P from soil to water is controlled by the P retention capacity in the solid phase, namely by the equilibrium between adsorbed and precipitated forms. Desorption of P and/or phosphate dissolution govern the amount of P released into drainage water, runoff or freshwater. Soil P evaluated by Olsen method showed a strong correlation with the capacity of soil to desorb P and, within certain limits, to the transfer of P to water. This transfer of P relates to losses that occur either in surface horizons, or in subsurface horizons (to drainage water, to runoff or by soil erosion to freshwater)

Teaching Laminar-flow reactors: From experimentation to CFD simulation

An integrated chemical engineering lab experiment is described in this paper. It makes use of a laminar-flow tubular reactor (LFTR) through consecutive lab sessions. In a first session (not described here), the pseudo first-order kinetic constant for the reaction between crystal violet and sodium hydroxide is determined at different temperatures in a batch reactor. Then a tracer experiment is used to characterize the flow, pattern in the LFTR, and finally the steady-state conversion of crystal violet in the reactor is measured. For computing the theoretical reactor conversion, students must use the previously collected kinetic and tracer data, in a concept-integration exercise. A computational fluid dynamics (CFD) code (Fluent) is also used to simulate both the tracer and the isothermal reaction experiments performed in the LFTR. A very good agreement is obtained between experimental and simulated results and both only differ slightly from the theoretical predictions. The use of the CFD program is particularly noteworthy. For instance, transient simulations allow a very nice visualization of the tracer concentration front evolution, while the steady-state profiles along the axial position provide a good perspective of how reactant concentration varies within the reactor

Changes induced by malathion, methylparathion and parathion on membrane lipid physicochemical properties correlate with their toxicity

Perturbations induced by malathion, methylparathion and parathion on the physicochemical properties of dipalmitoylphosphatidylcholine (DPPC) were studied by fluorescence anisotropy of DPH and DPH-PA and by differential scanning calorimetry (DSC). Methylparathion and parathion (50 [mu]M) increased the fluorescence anisotropy evaluated by DPH-PA and DPH, either in gel or in the fluid phase of DPPC bilayers, but mainly in the fluid phase. Parathion is more effective than methylparathion. On the other hand, malathion had almost no effect. All the three xenobiotics displaced the phase transition midpoint to lower temperature values and broadened the phase transition profile of DPPC, the effectiveness following the sequence: parathion>methylparathion>>malathion. A shifting and broadening of the phase transition was also observed by DSC. Furthermore, at methylparathion/lipid molar ratio of 1/2 and at parathion/lipid molar ratio of 1/7, the DSC thermograms displayed a shoulder in the main peak, in the low temperature side, suggesting coexistence of phases. For higher ratios, the phase transition profile becomes sharp as the control transition, but the midpoint is shifted to the previous shoulder position. Conversely to methylparathion and parathion, malathion did not promote phase separation. The overall data from fluorescence anisotropy and calorimetry indicate that the degree of effect of the insecticides on the physicochemical membrane properties correlates with toxicity to mammals. Therefore, the in vivo effects of organophosphorus compounds may be in part related with their ability to perturb the phospholipid bilayer structure, whose integrity is essential for normal cell function.http://www.sciencedirect.com/science/article/B6T1T-42NY32W-K/1/9c5c8320a8dff42bbf122281b5056b8

Proposal of a BEPU-FSAR

The accident analysis performance consists of a fundamental part of the licensing of the Nuclear Power Plants (NPP). There are conservative and best estimated methods to perform this analysis. Although Best Estimated Plus Uncertainty (BEPU) is used for qualified computational tools and methods of the accident analysis, it can be used in other parts of the Final Safety Analysis Report (FSAR), which require Analytical Techniques (AT). The need for uncertainty quantification and harmonization of the approaches to use the computer codes is an important issue constituting the background to perform a BEPU-FSAR. The objective of this paper is to present the BEPU-FSAR concept and discuss how-to and why-to perform it

A family of graded epistemic logics

Multi-Agent Epistemic Logic has been investigated in Computer Science [Fagin, R., J. Halpern, Y. Moses and M. Vardi, “Reasoning about Knowledge,” MIT Press, USA, 1995] to represent and reason about agents or groups of agents knowledge and beliefs. Some extensions aimed to reasoning about knowledge and probabilities [Fagin, R. and J. Halpern, Reasoning about knowledge and probability, Journal of the ACM 41 (1994), pp. 340–367] and also with a fuzzy semantics have been proposed [Fitting, M., Many-valued modal logics, Fundam. Inform. 15 (1991), pp. 235–254; Maruyama, Y., Reasoning about fuzzy belief and common belief: With emphasis on incomparable beliefs, in: IJCAI 2011, Proceedings of the 22nd International Joint Conference on Artificial Intelligence, Barcelona, Catalonia, Spain, July 16–22, 2011, 2011, pp. 1008–1013]. This paper introduces a parametric method to build graded epistemic logics inspired in the systematic method to build Multi-valued Dynamic Logics introduced in [Madeira, A., R. Neves and M. A. Martins, An exercise on the generation of many-valued dynamic logics, J. Log. Algebr. Meth. Program. 85 (2016), pp. 1011–1037. URL http://dx.doi.org/10.1016/j.jlamp.2016.03.004; Madeira, A., R. Neves, M. A. Martins and L. S. Barbosa, A dynamic logic for every season, in: C. Braga and N. Martí-Oliet, editors, Formal Methods: Foundations and Applications – 17th Brazilian Symposium, SBMF 2014, Maceió, AL, Brazil, September 29-October 1, 2014. Proceedings, Lecture Notes in Computer Science 8941 (2014), pp. 130–145. URL http://dx.doi.org/10.1007/978-3-319-15075-8_9]. The parameter in both methods is the same: an action lattice [Kozen, D., On action algebras, Logic and Information Flow (1994), pp. 78–88]. This algebraic structure supports a generic space of agent knowledge operators, as choice, composition and closure (as a Kleene algebra), but also a proper truth space for possible non bivalent interpretation of the assertions (as a residuated lattice).publishe