Crystal structure of 9-methacryloylanthracene

The authors would like to thank the Graduate College and Chemistry Department at Cleveland State University for support, the Ohio Supercomputing Center for a grant of computer time, and the National Science Foundation (CHE-0840446) for funds used to purchase the Bruker APEXII DUO X-ray diffractometer used in this research.Peer reviewedPublisher PD

The Shape of Cas A

Based on optical, IR and X-ray studies of Cas A, we propose a geometry for the remnant based on a "jet-induced" scenario with significant systematic departures from axial symmetry. In this model, the main jet axis is oriented in the direction of strong blue-shifted motion at an angle of 110 - 120 degrees East of North and about 40 - 50 degrees to the East of the line of sight. Normal to this axis would be an expanding torus as predicted by jet-induced models. In the proposed geometry, iron-peak elements in the main jet-like flow could appear "beyond" the portions of the remnant rich in silicon by projection effects, not the effect of mixing. In the context of the proposed geometry, the displacement of the compact object from the kinematic center of the remnant at a position angle of ~169 degrees can be accommodated if the motion of the compact object is near to, but slightly off from, the direction of the main "jet" axis by of order 30 degrees. In this model, the classical NE "jet," the SW "counter-jet" and other protrusions, particularly the "hole" in the North, are non-asymmetric flows approximately in the equatorial plane, e.g., out through the perimeter of the expanding torus, rather than being associated with the main jet. We explore the spoke-like flow in the equatorial plane in terms of Rayleigh-Taylor, Richtmyer-Meshkov and Kelvin-Helmholz instabilities and illustrate these instabilities with a jet-induced simulation.Comment: 25 pages, 4 figures. Accepted for publication in the Astrophysical Journa

The Use of a Vaginal Conductivity Probe to Influence Calf Sex Ratio via Altered Insemination Time

One hundred eighty-nine mixed breed beef heifers from 13 consignors enrolled in the MACEP heifer development project were utilized in this study. Heifers were synchronized by feeding 0.5 mg melengestrol acetate (MGA) per head per day for 14 days followed by an injection of prostaglandin F2a (PGF2a; 25 mg Lutalyse®) 17 days after the last MGA feeding. Each heifer was fitted with a Heatwatch® transmitter on the morning of PGF2a administration to facilitate detection of estrus. Vaginal conductivity measurements were taken using an Ovatec® probe every 12 hours for 96 hours beginning at the time of PGF2a injection. Heifers randomly assigned to produce a female calf were inseminated near the onset of estrus (as indicated by probe values of £ 55 on the decline). Heifers randomly assigned to produce a male calf were inseminated approximately 24 hours after the onset of estrus (as indicated by probe values of ³ 60 on the incline). All heifers not inseminated by 96 hours after PGF2a were mass inseminated in an attempt to impregnate as many heifers as possible. Heifers that were diagnosed as pregnant as a result of the artificial insemination were subjected to ultrasonography for fetal sex determination. Only 70 of the 189 heifers (37.0%) exhibited estrus according to Heatwatch® and incidence of estrus was influenced by heifer average daily gain, reproductive tract score, and disposition score. Heifers receiving a disposition score of 3 (78.7) had a higher (P\u3c.05) probe reading at AI than those receiving a disposition score of 1 or 2 (70.8 and 72.5, respectively). Heifers with probe readings at insemination of 80 - 84 and \u3e 84 had lower (P\u3c.05) pregnancy rates to AI (13.6 and 0.0%, respectively) than heifers with probe readings in the ranges of \u3c 60, 60 - 64, 65 - 69, 70 - 74, and 75 - 79 (35.7, 40.9, 31.4, 35.3, and 26.9% respectively). Heifers that were bred when probe values were increasing had a lower (P\u3c.05) percentage of male fetuses (34.4%) than those bred during a period of decreasing probe values (69.2% male fetuses). These results demonstrate that a vaginal conductivity probe may be a useful tool to determine an insemination time that could potentially alter calf sex ratio

Offenders' Crime Narratives across Different Types of Crimes

The current study explores the roles offenders see themselves playing during an offence and their relationship to different crime types. One hundred and twenty incarcerated offenders indicated the narrative roles they acted out whilst committing a specific crime they remembered well. The data were subjected to Smallest Space Analysis (SSA) and four themes were identified: Hero, Professional, Revenger and Victim in line with the recent theoretical framework posited for Narrative Offence Roles (Youngs & Canter, 2012). Further analysis showed that different subsets of crimes were more like to be associated with different narrative offence roles. Hero and Professional were found to be associated with property offences (theft, burglary and shoplifting), drug offences and robbery and Revenger and Victim were found to be associated with violence, sexual offences and murder. The theoretical implications for understanding crime on the basis of offenders' narrative roles as well as practical implications are discussed

Numerical modeling of oscillating Taylor bubbles

In this study, computational fluid dynamics (CFD) modeling is used to simulate Taylor bubbles rising in vertical pipes. Experiments indicate that in large diameter (0.29 m) pipes for an air–water system, the bubbles can rise in a oscillatory manner, depending on the method of air injection. The CFD models are able to capture this oscillatory behavior because the air phase is modeled as a compressible ideal gas. Insights into the flow field ahead and behind the bubble during contraction and expansion are shown. For a bubble with an initial pressure equal to the hydrostatic pressure at its nose, no oscillations are seen in the bubble as it rises. If the initial pressure in the bubble is set less than or greater than the hydrostatic pressure then the length of the bubble oscillates with an amplitude that depends on the magnitude of the initial bubble pressure relative to the hydrostatic pressure. The frequency of the oscillations is inversely proportional to the square root of the head of water above the bubble and so the frequency increases as the bubble approaches the water surface. The predicted frequency also depends inversely on the square root of the average bubble length, in agreement with experimental observations and an analytical model that is also presented. In this model, a viscous damping term due to the presence of a Stokes boundary layer for the oscillating cases is introduced for the first time and used to assess the effect on the oscillations of increasing the liquid viscosity by several orders of magnitude

Criminal narrative experience: relating emotions to offence narrative roles during crime commission

A neglected area of research within criminality has been that of the experience of the offence for the offender. The present study investigates the emotions and narrative roles that are experienced by an offender while committing a broad range of crimes and proposes a model of Criminal Narrative Experience (CNE). Hypotheses were derived from the Circumplex of Emotions (Russell, 1997), Frye (1957), Narrative Theory (McAdams, 1988) and its link with Investigative Psychology (Canter, 1994). The analysis was based on 120 cases. Convicted for a variety of crimes, incarcerated criminals were interviewed and the data were subjected to Smallest Space Analysis (SSA). Four themes of Criminal Narrative Experience (CNE) were identified: Elated Hero, Calm Professional, Distressed Revenger and Depressed Victim in line with the recent theoretical framework posited for Narrative Offence Roles (Youngs & Canter, 2012). The theoretical implications for understanding crime on the basis of the Criminal Narrative Experience (CNE) as well as practical implications are discussed

Sustainable Agriculture and the Structure of North Dakota Agriculture

Environmental Economics and Policy, Industrial Organization, Production Economics,

Selected Characteristics of North Dakota Farm Families Engaged in Sustainable Agricultural Practices

Environmental Economics and Policy, Farm Management, Resource /Energy Economics and Policy,