Evidence for Coupling of Velocity and Composition Fluctuations in a Binary Liquid Mixture

A critical mixture of isobutyric acid and water was quenched from the one-phase region into the two-phase region and, after the spinodal ring was well developed, a reverse quench returned the system to the one-phase region. Light-scattering measurements for this process exhibit a clearly nondiffusive relaxation which, at least for early times after the quench reversal, is in good agreement with Ruiz\u27s scheme for the coupling of velocity and composition fluctuations

Decay of Correlations in a Topological Glass

In this paper we continue the study of a topological glassy system. The state space of the model is given by all triangulations of a sphere with $N$ nodes, half of which are red and half are blue. Red nodes want to have 5 neighbors while blue ones want 7. Energies of nodes with other numbers of neighbors are supposed to be positive. The dynamics is that of flipping the diagonal between two adjacent triangles, with a temperature dependent probability. We consider the system at very low temperatures. We concentrate on several new aspects of this model: Starting from a detailed description of the stationary state, we conclude that pairs of defects (nodes with the "wrong" degree) move with very high mobility along 1-dimensional paths. As they wander around, they encounter single defects, which they then move "sideways" with a geometrically defined probability. This induces a diffusive motion of the single defects. If they meet, they annihilate, lowering the energy of the system. We both estimate the decay of energy to equilibrium, as well as the correlations. In particular, we find a decay like $t^{-0.4}$

Plan of Young/Maher Subdivision, Main Street, Cumberland, Maine, 1990

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Ordering block copolymers

A method for ordering block copolymers including forming a first layer having a first preference mode; and providing a reactive agent in selected regions of the first layer that modifies the selected regions to a second preference mode, wherein the selected regions define other regions of the first layer retaining the first preference mode thereby forming an alignment layer for block copolymers.Board of Regents, University of Texas Syste

Electron Beam Nano-Etching in Oxides, Fluorides, Metals and Semiconductors

Etching, lithography, hole formation, surface restructuring and external machining can all be performed on a nanometre scale using an intense electron beam. Results are presented for a range of different materials which demonstrate the variety of mechanisms by which electron beam nano-etching can occur. For example, in crystalline 13-alumina hole formation occurs by surface indentations growing inwards to join up and form a nanometre diameter hole. In amorphous alumina, on the other hand, hole formation is from the inside-out: oxygen gas bubbles form under the electron beam, coalesce, and burst to leave a well defined nanometre diameter hole. In MgO and Si, holes develop from the electron exit surface: whereas in Al voids form along the irradiated volume, leading eventually to the development of a hole at the electron entrance surface. The potential of electron beam nano-etching to lithography and information storage is demonstrated by showing that the entire contents of the Encyclopaedia Britannica can be written on a pinhead

Hypertensive disorders of pregnancy and risk of neurodevelopmental disorders in the offspring: a systematic review and meta-analysis protocol

Introduction Hypertensive disorders of pregnancy (HDPs), that is chronic hypertension, gestational hypertension, pre-eclampsia (de novo or superimposed on chronic hypertension) and white coat hypertension, affect approximately 5%–15% of pregnancies. HDP exposure has been linked to an increased risk of autism spectrum disorder, attention deficit/hyperactivity disorder and other neurodevelopmental disorders in children. However, findings are inconsistent, and a clear consensus on the impact of HDPs on the risk of neurodevelopmental disorders is needed. Therefore, we aim to synthesise the published literature on the relationship between HDPs and the risk of neurodevelopmental disorders in the form of a systematic review and meta-analysis. Methods and analysis We will include cohort, case– control and cross-sectional studies in which diagnosis of an HDP was reported, and neurodevelopmental disorders were the outcome of interest based on a preprepared protocol. A systematic search of PubMed, CINAHL, Embase, PsycINFO and Web of Science will be conducted in accordance with a detailed search strategy. Two authors will independently review the titles and abstracts of all studies, perform data extraction using a standardised data collection form and assess study quality using a bias classification tool. Meta-analyses will be performed to calculate overall pooled estimates using the generic inverse variance method. This systematic review will be reported according to the Preferred Reporting Items for Systematic reviews and Meta-Analyses. Ethics and dissemination This proposed systematic review and meta-analysis is based on published data, therefore, does not require ethics approval. Findings will be presented at scientific conferences and disseminated through publication in a peer-reviewed journal. Registration CRD42017068258

Conductance-Based Profiling of Nanopores: Accommodating Fabrication Irregularities

Solid-state nanopores are nanoscale channels through otherwise impermeable membranes. Single molecules or particles can be passed through electrolyte-filled nanopores by, e.g. electrophoresis, and then detected through the resulting physical displacement of ions within the nanopore. Nanopore size, shape, and surface chemistry must be carefully controlled, and on extremely challengingwork, confirmed the suitability of the basic conductance equation using the results of a time-dependent experimental conductance measurement during nanopore fabrication by Yanagi et al., and then deliberately relaxed the model constraints to allow for (1) the presence of defects; and (2) the formation of two small pores instead of one larger one. Our simulations demonstrated that the time-dependent conductance formalism supports the detection and characterization of defects, as well as the determination of pore number, but with implementation performance depending on the measurement context and results. In some cases, the ability to discriminate numerically between the correct and incorrect nanopore profiles was slight, but with accompanying differences in candidate nanopore dimensions that could yield to post-fabrication conductance profiling, or be used as convenient uncertainty bounds. Time-dependent nanopore conductance thus offers insight into nanopore structure and function, even in the presence of fabrication defects

Evaluation of health effects of air pollution in the Chestnut Ridge area : preliminary analysis

This project involves several tasks designed to take advantage of (1) a very extensive air pollution monitoring system that is operating ..n the Chestnut Ridge.region of Western Pennsylvania and (2) -the very well developed analytic dispersion models that have been previously fine-tuned to this particular area.. The major task in this project is to establish, through several distinct epidemiolopic approaches, health data to be used to test hypotheses about relations of air pollution exposures to morbidity and mortality rates in this region. Because the air quality monitoring network involves no expense to this contract this project affords a very cost-effective 6pportunity-for state-of-the-art techniques to be used in both costly areas of air pollution and health -effects data col1 ection. . The closely spaced network of monitors, plus the dispersion modeling capabilities,.allow for the investigation- of health impacts of. various pollutant gradients in neighboring geographic areas, thus minimizing -the confounding effects of social, ethnic, and economic factors. The pollutants that are monitored in this network include total gaseous sulfur, sulfates, total suspended particulates, NOx, NO, ozone/oxidants, and coefficient of haze. In addition to enabling the simulation of exposure profiles between monitors, the air quality2 modeling, along with extensive source and background inventories, will allow for upgrading the quality of the monitored data. as well as simulating the exposure levels for about 25 additional air pollutants. Another important goal of this project is to collect and test the many available models for associating.health effects with air pollution, to determine their predictive validity and their usefulness in the choice and siting of future energy facilities