Nanowires: A route to efficient thermoelectric devices

Miniaturization of electronic devices aims at manufacturing ever smaller products, from mesoscopic to nanoscopic sizes. This trend is challenging because the increased levels of dissipated power demands a better understanding of heat transport in small volumes. A significant amount of the consumed energy is transformed into heat and dissipated to the environment. Thermoelectric materials offer the possibility to harness dissipated energy and make devices less energy-demanding. Heat-to-electricity conversion requires materials with a strongly suppressed thermal conductivity but still high electronic conduction. Nanowires can meet nicely these two requirements because enhanced phonon scattering at the surface and defects reduces the lattice thermal conductivity while electric conductivity is not deteriorated, leading to an overall remarkable thermoelectric efficiency. Therefore, nanowires are regarded as a promising route to achieving valuable thermoelectric materials at the nanoscale. In this paper, we present an overview of key experimental and theoretical results concerning the thermoelectric properties of nanowires. The focus of this review is put on the physical mechanisms by which the efficiency of nanowires can be improved. Phonon scattering at surfaces and interfaces, enhancement of the power factor by quantum effects and topological protection of electron states to prevent the degradation of electrical conductivity in nanowires are thoroughly discussed

Interactions and thermoelectric effects in a parallel-coupled double quantum dot

We investigate the nonequilibrium transport properties of a double quantum dot system connected in parallel to two leads, including intradot electron-electron interaction. In the absence of interactions the system supports a bound state in the continuum. This state is revealed as a Fano antiresonance in the transmission when the energy levels of the dots are detuned. Using the Keldysh nonequilibrium Green's function formalism, we find that the occurrence of the Fano antiresonance survives in the presence of Coulomb repulsion. We give precise predictions for the experimental detection of bound states in the continuum. First, we calculate the differential conductance as a function of the applied voltage and the dot level detuning and find that crossing points in the diamond structure are revealed as minima due to the transmission antiresonances. Second, we determine the thermoelectric current in response to an applied temperature bias. In the linear regime, quantum interference gives rise to sharp peaks in the thermoelectric conductance. Remarkably, we find interaction induced strong current nonlinearities for large thermal gradients that may lead to several nontrivial zeros in the thermocurrent. The latter property is especially attractive for thermoelectric applications.Comment: 9 pages, 8 figure

Effect of influenza-induced fever on human bioimpedance values

BACKGROUND AND AIMS: Bioelectrical impedance analysis (BIA) is a widely used technique to assess body composition and nutritional status. While bioelectrical values are affected by diverse variables, there has been little research on validation of BIA in acute illness, especially to understand prognostic significance. Here we report the use of BIA in acute febrile states induced by influenza. METHODS: Bioimpedance studies were conducted during an H1N1 influenza A outbreak in Venezuelan Amerindian villages from the Amazonas. Measurements were performed on 52 subjects between 1 and 40 years of age, and 7 children were re-examined after starting Oseltamivir treatment. Bioelectrical Impedance Vector Analysis (BIVA) and permutation tests were applied. RESULTS: For the entire sample, febrile individuals showed a tendency toward greater reactance (p=0.058) and phase angle (p=0.037) than afebrile individuals, while resistance and impedance were similar in the two groups. Individuals with repeated measurements showed significant differences in bioimpedance values associated with fever, including increased reactance (p<0.001) and phase angle (p=0.007), and decreased resistance (p=0.007) and impedance (p<0.001). CONCLUSIONS: There are bioelectrical variations induced by influenza that can be related to dehydration, with lower extracellular to intracellular water ratio in febrile individuals, or a direct thermal effect. Caution is recommended when interpreting bioimpedance results in febrile states

Size-Controlled Water-Soluble Ag Nanoparticles

Ag nanoparticles of two different sizes (1 and 4 nm) were prepared within an apoferritin cavity by using an Ag+-loaded apoferritin as a nanoconfined environment for their construction. The initial amount of Ag' ions injected in the apoferritin cavity dictates the size of the final Ag particles. The protein shell prevents bulk aggregation of the metal particles, which renders them water soluble and extremely stable

Stellar population analysis of MaNGA early-type galaxies: IMF dependence and systematic effects

We study systematics associated with estimating simple stellar population (SSP) parameters -- age, metallicity [M/H], $\alpha$-enhancement [$\alpha$/Fe] and IMF shape -- and associated $M_*/L$ gradients, of elliptical slow rotators (E-SRs), fast rotators (E-FRs) and S0s from stacked spectra of galaxies in the MaNGA survey. These systematics arise from (i) how one normalizes the spectra when stacking; (ii) having to subtract emission before estimating absorption line strengths; (iii) the decision to fit the whole spectrum or just a few absorption lines; (iv) SSP model differences (e.g. isochrones, enrichment, IMF). The MILES+Padova SSP models, fit to the H$_\beta$, $\langle$Fe$\rangle$, TiO$_{\rm 2SDSS}$ and [MgFe] Lick indices in the stacks, indicate that out to the half-light radius $R_e$: (a) ages are younger and [$\alpha$/Fe] values are lower in the central regions but the opposite is true of [M/H]; (b) the IMF is more bottom-heavy in the center, but is close to Kroupa beyond about $R_e/2$; (c) this makes $M_*/L$ about $2\times$ larger in the central regions than beyond $R_e/2$. While the models of Conroy et al. (2018) return similar [M/H] and [$\alpha$/Fe] profiles, the age and (hence) $M_*/L$ profiles can differ significantly even for solar abundances and a Kroupa IMF; different responses to non-solar abundances and IMF parametrization further compound these differences. There are clear (model independent) differences between E-SRs, E-FRs and S0s: younger ages and less enhanced [$\alpha$/Fe] values suggest that E-FRs and S0s are not SSPs, but relaxing this assumption is unlikely to change their inferred $M_*/L$ gradients significantly.Comment: 22 pages, 23 figures, accepted for publication in MNRA

The half mass radius of MaNGA galaxies: Effect of IMF gradients

Gradients in the stellar populations (SP) of galaxies -- e.g., in age, metallicity, stellar Initial Mass Function (IMF) -- can result in gradients in the stellar mass to light ratio, $M_*/L$. Such gradients imply that the distribution of the stellar mass and light are different. For old SPs, e.g., in early-type galaxies at $z\sim 0$, the $M_*/L$ gradients are weak if driven by variations in age and metallicity, but significantly larger if driven by the IMF. A gradient which has larger $M_*/L$ in the center increases the estimated total stellar mass ($M_*$) and reduces the scale which contains half this mass ($R_{e,*}$), compared to when the gradient is ignored. For the IMF gradients inferred from fitting MILES simple SP models to the H$_\beta$, $\langle$Fe$\rangle$, [MgFe] and TiO$_{\rm 2SDSS}$ absorption lines measured in spatially resolved spectra of early-type galaxies in the MaNGA survey, the fractional change in $R_{e,*}$ can be significantly larger than that in $M_*$, especially when the light is more centrally concentrated. The $R_{e,*}-M_*$ correlation which results is offset by 0.3 dex to smaller sizes compared to when these gradients are ignored. Comparisons with `quiescent' galaxies at higher-$z$ must account for evolution in SP gradients (especially age and IMF) and the light profile before drawing conclusions about how $R_{e,*}$ and $M_*$ evolve. The implied merging between higher-$z$ and the present is less contrived if $R_{e,*}/R_e$ at $z\sim 0$ is closer to our IMF-driven gradient calibration than to unity.Comment: 16 pages, 15 figures, accepted for publication in MNRA

The origin of the Acheulean: the 1.7 million-year-old site of FLK West, Olduvai Gorge (Tanzania)

The appearance of the Acheulean is one of the hallmarks of human evolution. It represents the emergence of a complex behavior, expressed in the recurrent manufacture of large-sized tools, with standardized forms, implying more advance forethought and planning by hominins than those required by the precedent Oldowan technology. The earliest known evidence of this technology dates back to c. 1.7 Ma. and is limited to two sites (Kokiselei [Kenya] and Konso [Ethiopia]), both of which lack fauna. The functionality of these earliest Acheulean assemblages remains unknown. Here we present the discovery of another early Acheulean site also dating to c. 1.7 Ma from Olduvai Gorge. This site provides evidence of the earliest steps in developing the Acheulean technology and is the oldest Acheulean site in which stone tools occur spatially and functionally associated with the exploitation of fauna. Simple and elaborate large-cutting tools (LCT) and handaxes co-exist at FLK West, showing that complex cognition was present from the earliest stages of the Acheulean. Here we provide a detailed technological study and evidence of the use of these tools on the butchery and consumption of fauna, probably by early Homo erectus sensu lato