37 research outputs found
Highly oriented surface-growth and covalent dye labeling of mesoporous metal-organic frameworks
Mesoporous amino-functionalized metal-organic framework thin films with the UiO-68 topology were grown in a highly oriented fashion on two different self-assembled monolayers on gold. The oriented MOF films were covalently modified with the fluorescent dye Rhodamine B inside the pore system, as demonstrated with size-selective fluorescence quenching studies. Our study suggests that mesoporous metal-organic frameworks are promising hosts for the covalent attachment of numerous functional moieties in a molecularly designed crystalline environment. © The Royal Society of Chemistry 2012
Selection on Floral Morphology and Environmental Determinants of Fecundity in a Hawk Moth-Pollinated Violet
This paper presents the results of a 5—yr field study on the determinants of individual variation in maternal fecundity (seed production) in the narrowly endemic violet Viola cazorlensis (Violaceae), at a southeastern Spanish locality. Flowers of this species are characterized by a very long, thin spur and broad morphological variability, and are pollinated by a single species of day—flying hawk moth (Macroglossum stellatarum; Lepidoptera, Sphingidae). The primary aim of this investigation was to answer the question, What are the relative importances, as explanations of individual differences in fecundity, of variability in floral traits and of other fecundity determinants that are of an extrinsic nature, such as microhabitat type and interactions with herbivores? The floral morphology of individual V. cazorlensis plants was characterized by means of both "conventional," linear measurements of the size of flower parts (petals, spur, peduncle), and shape analysis of corolla outline (using thin—plate splines relative warps analysis). Spatial (among substrate types) and temporal (among years) patterns of variation in flower, fruit, and seed production by V. cazorlensis plants are described, with particular emphasis on the comparative effects of floral morphology, herbivory (by mammalian ungulates and two species of lepidopteran larvae), and substrate type (rock cliffs, bare rocks at ground level, and sandy soils), on cumulative seed production at the individual plant level. Cumulative seed production of individual V. cazorlensis plants depended significantly on average floral morphology (both size and shape components), thus revealing the existence of phenotypic selection on the floral morphology of this species at the study population. Among all the floral traits examined, spur length was the only one for which no significant relationship with fecundity was found. Type of substrate largely determined differences between V. cazorlensis plants in the impact of herbivory (plants growing on the soil exhibited the greatest reproductive losses to herbivores), and it also influenced plant size and flower production per reproductive episode. Plant size, in turn, influenced the supra—annual frequency of flowering and the number of flowers produced in each reproductive event. Flower production and herbivory levels significantly influenced (positively and negatively, respectively) fruit number, which was the major direct determinant of seed production. Path analysis revealed that the main determinants of individual variation in cumulative seed production over the study period were, in decreasing order of importance (absolute value of "effect coefficient" in parentheses), cumulative fruit production (0.946), mean flower production per reproductive event (0.868), plant size (0.441), herbivory by ungulates (—0.221), and average score on the first relative warp (0.107), a descriptor of flower shape. After accounting for the effects of substrate type, herbivory, plant size, and flower and fruit production, individual variation in floral morphology (aspects of size and shape) explained a negligible proportion (2.1%) of total individual variation in cumulative fruit production. Phenotypic selection on the floral morphology of V. cazorlensis at the study population, although statistically significant, was therefore almost inconsequential as a source of individual variation in maternal fitness, its effects being heavily "dilute" by the overwhelming influence of other factors. As exemplified by this study, selection on the floral phenotype may often become largely irrelevant in evolutionary terms because other ecological factors are far more important determinants of fitness differences among plants. A realistic assessment of the potential relevance of selection on plant reproductive traits thus requires a quantitative evaluation, in its natural scenario, of the predictable consequences of such selectionPeer reviewe
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Overview of converting abandoned coal mines to underground pumped storage systems: Focus on the underground reservoir
The utilization of Underground Pumped Storage Power Systems (UPSP) addresses the growing need for energy storage in the face of increasing intermittent energy sources. Simultaneously, the closure of mining activities has resulted in vast underground spaces potentially becoming available for alternative purposes. This paper explores the potential of repurposing abandoned mines, particularly coal mines, as lower reservoirs for UPSPs.
The challenges associated with employing abandoned mines as lower reservoirs are multifaceted. The foremost challenge stems from limited knowledge about the current state of the mines due to post-mining processes, such as weathering, dissolution, hydration, leaching, swelling, slacking, subsidence, creeping along faults, gas migration, and precipitation, along with corrosion and deterioration of the support elements. This study documents and discusses the various processes related to cyclical pumping and discharge within the context of UPSPs, encompassing hydraulic discharge processes, cyclic loading, dry and wet processes, as well as fatigue and thermal stress. These processes significantly impact the safety, productivity, and stability of the lower reservoir.
To address these challenges, the paper presents different numerical solutions available to comprehend and mitigate cyclical processes in abandoned mines. Finally, it explores the economic feasibility of repurposing mines as lower reservoirs and the conditions required are examined, including favorable rock mass properties, reduced land acquisition costs, the necessity of permanent water pumping, and the potential income from excavated rock as a revenue source in case of new excavations.
This research contributes to the understanding of utilizing abandoned mines for UPSPs, highlighting the challenges associated with the use of coal mines as lower reservoirs and presenting several main processes to prevent safety and productivity issues