Rapid Cycling and Exceptional Yield in a Metal-Organic Framework Water Harvester.

Sorbent-assisted water harvesting from air represents an attractive way to address water scarcity in arid climates. Hitherto, sorbents developed for this technology have exclusively been designed to perform one water harvesting cycle (WHC) per day, but the productivities attained with this approach cannot reasonably meet the rising demand for drinking water. This work shows that a microporous aluminum-based metal-organic framework, MOF-303, can perform an adsorption-desorption cycle within minutes under a mild temperature swing, which opens the way for high-productivity water harvesting through rapid, continuous WHCs. Additionally, the favorable dynamic water sorption properties of MOF-303 allow it to outperform other commercial sorbents displaying excellent steady-state characteristics under similar experimental conditions. Finally, these findings are implemented in a new water harvester capable of generating 1.3 L kgMOF -1 day-1 in an indoor arid environment (32% relative humidity, 27 °C) and 0.7 L kgMOF -1 day-1 in the Mojave Desert (in conditions as extreme as 10% RH, 27 °C), representing an improvement by 1 order of magnitude over previously reported devices. This study demonstrates that creating sorbents capable of rapid water sorption dynamics, rather than merely focusing on high water capacities, is crucial to reach water production on a scale matching human consumption

Three-Dimensional Phthalocyanine Metal-Catecholates for High Electrochemical Carbon Dioxide Reduction.

The synthesis of a new anionic 3D metal-catecholate framework, termed MOF-1992, is achieved by linking tetratopic cobalt phthalocyanin-2,3,9,10,16,17,23,24-octaol linkers with Fe3(-C2O2-)6(OH2)2 trimers into an extended framework of roc topology. MOF-1992 exhibits sterically accessible Co active sites together with charge transfer properties. Cathodes based on MOF-1992 and carbon black (CB) display a high coverage of electroactive sites (270 nmol cm-2) and a high current density (-16.5 mA cm-2; overpotential, -0.52 V) for the CO2 to CO reduction reaction in water (faradaic efficiency, 80%). Over the 6 h experiment, MOF-1992/CB cathodes reach turnover numbers of 5800 with turnover frequencies of 0.20 s-1 per active site

UV Extinction Towards a Quiescent Molecular Cloud in the SMC

Context: The mean UV extinction law for the Small Magellanic Cloud (SMC) is usually taken as a template for low-metallicity galaxies. However, its current derivation is based on only five stars, thus placing doubts on its universality. An increase in the number of targets with measured extinction laws in the SMC is necessary to determine its possible dependence on parameters such as metallicity and star-forming activity. Aims: To measure the UV extinction law for several stars in the quiescent molecular cloud SMC B1-1. Methods: We obtained HST/STIS slitless UV spectroscopy of a 25"x25" field of view and we combined it with ground-based NIR and visible photometry of the stars in the field. The results were processed using the Bayesian photometric package CHORIZOS to derive the visible-NIR extinction values for each star. The unextinguished Spectral Energy Distributions (SEDs) obtained in this way were then used to derive the UV extinction law for the four most extinguished stars. We also recalculated the visible-NIR extinction for the five SMC stars with preexisting UV extinction laws. Results: The UV extinction law for four SMC B1-1 stars within several pc of each other differs significantly from star to star. The 2175 {\AA} bump is moderately strong in one, weak in two, and absent in the fourth.Comment: 10 pages, 5 figures, accepted for publication in Astronomy & Astrophysic

Étude de vingt-cinq foyers récents de botulisme animal

Prévot A. R., Huet M., Tardieux P. Étude de vingt-cinq foyers récents de botulisme animal. In: Bulletin de l'Académie Vétérinaire de France tome 103 n°9, 1950. pp. 481-487

Fast-neutron induced background in LaBr3:Ce detectors

The response of a scintillation detector with a cylindrical 1.5-inch LaBr3:Ce crystal to incident neutrons has been measured in the energy range En = 2-12 MeV. Neutrons were produced by proton irradiation of a Li target at Ep = 5-14.6 MeV with pulsed proton beams. Using the time-of-flight information between target and detector, energy spectra of the LaBr3:Ce detector resulting from fast neutron interactions have been obtained at 4 different neutron energies. Neutron-induced gamma rays emitted by the LaBr3:Ce crystal were also measured in a nearby Ge detector at the lowest proton beam energy. In addition, we obtained data for neutron irradiation of a large-volume high-purity Ge detector and of a NE-213 liquid scintillator detector, both serving as monitor detectors in the experiment. Monte-Carlo type simulations for neutron interactions in the liquid scintillator, the Ge and LaBr3:Ce crystals have been performed and compared with measured data. Good agreement being obtained with the data, we present the results of simulations to predict the response of LaBr3:Ce detectors for a range of crystal sizes to neutron irradiation in the energy range En = 0.5-10 MeVComment: 28 pages, 10 figures, 4 Table

Enzootie à « W. perfringens A » dans un élevage de visons

Prévot A., Villemin Martial, Kréguer A., Vallée A. Enzootie à “W. perfringens A” dans un élevage de visons. In: Bulletin de l'Académie Vétérinaire de France tome 114 n°3, 1961. pp. 115-117

EROS Variable Stars : Discovery of Beat Cepheids in the Small Magellanic Cloud and the effect of metallicity on pulsation

We report the discovery of eleven beat Cepheids in the Small Magellanic Cloud, using data obtained by the EROS microlensing survey. Four stars are beating in the fundamental and first overtone mode (F/1OT), seven are beating in the first and second overtone (1OT/2OT). The SMC F/1OT ratio is systematically higher than the LMC F/1OT, while the 1OT/2OT period ratio in the SMC Cepheids is the same as the LMC one.Comment: 4 pages, Latex file with 4 .ps figures. accepted for publication in A A Letter

Absolute magnitude and kinematics of Barium stars

The absolute magnitude of barium stars has been obtained from kinematical data using a new algorithm based on the maximum-likelihood principle. The method allows to separate a sample into groups characterized by different mean absolute magnitudes, kinematics and z-scale heights. It also takes into account, simultaneously, the censorship in the sample and the errors on the observables. The method has been applied to a sample of 318 barium stars. Four groups have been detected. Three of them show a kinematical behaviour corresponding to disk population stars. The fourth group contains stars with halo kinematics. The luminosities of the disk population groups spread a large range. The intrinsically brightest one (M_v_=-1.5mag, σ_M_=0.5mag) seems to be an inhomogeneous group containing barium binaries as well as AGB single stars. The most numerous group (about 150 stars) has a mean absolute magnitude corresponding to stars in the red giant branch (M_v_=0.9mag, σ_M_=0.8mag). The third group contains barium dwarfs, the obtained mean absolute magnitude is characteristic of stars on the main sequence or on the subgiant branch (M_v_=3.3mag, σ_M_=0.5mag). The obtained mean luminosities as well as the kinematical results are compatible with an evolutionary link between barium dwarfs and classical barium giants. The highly luminous group is not linked with these last two groups. More high-resolution spectroscopic data will be necessary in order to better discriminate between barium and non-barium stars