On the narrative form of simulations.

Understanding complex physical systems through the use of simulations often takes on a narrative character. That is, scientists using simulations seek an understanding of processes occurring in time by generating them from a dynamic model, thereby producing something like a historical narrative. This paper focuses on simulations of the Diels-Alder reaction, which is widely used in organic chemistry. It calls on several well-known works on historical narrative to draw out the ways in which use of these simulations mirrors aspects of narrative understanding: Gallie for "followability" and "contingency"; Mink for "synoptic judgment"; Ricoeur for "temporal dialectic"; and Hawthorn for a related dialectic of the "actual and the possible". Through these reflections on narrative, the paper aims for a better grasp of the role that temporal development sometimes plays in understanding physical processes and of how considerations of possibility enhance that understanding

Heat addition to a subsonic boundary layer: A preliminary analytical study

A preliminary analytical study of the effects of heat addition to the subsonic boundary layer flow over a typical airfoil shape is presented. This phenomenon becomes of interest in the space shuttle mission since heat absorbed by the wing structure during re-entry will be rejected to the boundary layer during the subsequent low speed maneuvering and landing phase. A survey of existing literature and analytical solutions for both laminar and turbulent flow indicate that a heated surface generally destabilizes the boundary layer. Specifically, the boundary layer thickness is increased, the skin friction at the surface is decreased and the point of flow separation is moved forward. In addition, limited analytical results predict that the angle of attack at which a heated airfoil will stall is significantly less than the stall angle of an unheated wing. These effects could adversely affect the lift and drag, and thus the maneuvering capabilities of booster and orbiter shuttle vehicles

A Serendipitous XMM-Newton Observation of the Intermediate Polar WX Pyx

We briefly describe a serendipitous observation of the little-studied intermediate polar WX Pyx using XMM-Newton. The X-ray spin period is 1557.3 sec, confirming the optical period published in 1996. An orbital period of approximately 5.54 hr is inferred from the separation of the spin-orbit sidelobe components. The soft and hard band spin-folded light curves are nearly sinusoidal in shape. The best-fit spectrum is consistent with a bremsstrahlung temperature of about 18 keV. An upper limit of approximately 300 eV is assigned to the presence of Fe line emission. WX Pyx lies near TX and TV Col in the P_spin-P_orb plane.Comment: 5 pages, 5 figs; accepted A&A 2004 Dec

Periodicities In The X-Ray Intensity Variations of TV Columbae: An Intermediate Polar

We present results from a temporal analysis of the longest and the most sensitive X-ray observations of TV Columbae--an intermediate polar. The observations were carried out with the RXTE PCA, ROSAT PSPC, and ASCA. Data were analyzed using a 1-dimensional CLEAN and Bayesian algorithms. The presence of a nearly sinusoidal modulation due to the spin of the white dwarf is seen clearly in all the data, confirming the previous reports based on the EXOSAT data. An improved period of 1909.7+/-2.5s is derived for the spin from the RXTE data.The binary period of 5.5hr is detected unambiguously in X-rays for the first time. Several side-bands due to the interaction of these periods are observed in the power spectra, thereby suggesting contributions from both the disk-fed and the stream-fed accretion for TV Col. The accretion disk could perhaps be precessing as side-bands due to the influence of 4 day period on the orbital period are seen. The presence of a significant power at certain side-bands of the spin frequency indicates that the emission poles are asymmetrically located. The strong power at the orbital side-bands seen in both the RXTE and ROSAT data gives an indication for an absorption site fixed in the orbital frame. Both the spin and the binary modulation are found to be energy-dependent. Increased hardness ratio during a broad dip in the intensity at binary phase of 0.75--1.0 confirms the presence of a strong attenuation due to additional absorbers probably from an impact site of the accretion stream with the disk or magnetosphere. Hardness ratio variations and the energy dependent modulation depth during the spin modulation can be explained by partially covered absorbers in the path of X-ray emission region in the accretion stream.Comment: 34 pages, including 12 figures, Accepted for publication in Astronomical Journal, scheduled for January 2004 issue (vol. 127

Some Measurement on the Quantum Yield Temperature Coefficient of the Uranyl Oxalate Actinometer at 254 Mu1,2,3

Author Institution: Kenyon College, Gambier, OhioThis paper reports, for solutions of 0.001 M uranyl sulfate and 0.005 M oxalic acid, a 10-degree temperature coefficient, up to 85°C (using a base temperature of 25°) of 1.02±0.01 at 254 m/x. Measurements in more dilute solutions show a decrease to approximately unity at 0.00025 M uranyl sulfate0.00125 M oxalic acid, with indication that it may become less than unity on further dilution. Quantum yields measured (using uranyl oxalate as standard), by students under a National Science Foundation "pilot" undergraduate participation project, on actinometers at 254 rn.fi, were for (1) malachite green leucocyanide, 0.9; (2) monochloroacetic acid, 0.3; and (3) potassium ferrioxalate, 1.24 moles per einstein