1,244 research outputs found
A Herschel/HIFI Legacy Survey of HF and H2O in the Galaxy: Probing Diffuse Molecular Cloud Chemistry
We combine Herschel observations of a total of 12 sources to construct the
most uniform survey of HF and H2O in our Galactic disk. Both molecules are
detected in absorption along all sight lines. The high spectral resolution of
the Heterodyne Instrument for the Far-Infrared (HIFI) allows us to compare the
HF and H2O distributions in 47 diffuse cloud components sampling the disk. We
find that the HF and H2O velocity distributions follow each other almost
perfectly and establish that HF and H2O probe the same gas-phase volume. Our
observations corroborate theoretical predictions that HF is a sensitive tracer
of H2 in diffuse clouds, down to molecular fractions of only a few percent.
Using HF to trace H2 in our sample, we find that the N(H2O)-to-N(HF) ratio
shows a narrow distribution with a median value of 1.51. Our results further
suggest that H2O might be used as a tracer of H2 -within a factor 2.5- in the
diffuse interstellar medium. We show that the measured factor of ~2.5 variation
around the median is driven by true local variations in the H2O abundance
relative to H2 throughout the disk. The latter variability allows us to test
our theoretical understanding of the chemistry of oxygen-bearing molecules in
the diffuse gas. We show that both gas-phase and grain-surface chemistry are
required to reproduce our H2O observations. This survey thus confirms that
grain surface reactions can play a significant role in the chemistry occurring
in the diffuse interstellar medium n_H < 1000 cm^-3.Comment: 53 pages; 12 figures, accepted for publication in ApJ main journa
Lo que se ha de notar en los que combaten como forma castellana de El vencedor y el vencido.
Sin resume
Polanyi Evaluation of Adsorptive Capacities of Commercial Activated Carbons
Commercial activated carbons from Calgon (207C and OVC) and Cabot Norit (RB2 and GCA 48) were evaluated for use in spacecraft trace contaminant control filters. The Polanyi potential plots of the activated carbons were compared using to those of Barnebey-Cheney Type BD, an untreated activated carbon with similar properties as the acid-treated Barnebey-Sutcliffe Type 3032 utilized in the TCCS. Their adsorptive capacities under dry conditions were measured in a closed loop system and the sorbents were ranked for their ability to remove common VOCs found in spacecraft cabin air. This comparison suggests that these sorbents can be ranked as GCA 48 207C, OVC RB2 for the compounds evaluated
Interstellar CH absorption in the diffuse interstellar medium along the sight-lines to G10.6–0.4 (W31C), W49N, and W51
We report the detection of the ground state N, J = 1, 3/2 → 1, 1/2 doublet of the methylidyne radical CH at ~532 GHz and ~536 GHz with
the Herschel/HIFI instrument along the sight-line to the massive star-forming regions G10.6–0.4 (W31C), W49N, and W51. While the molecular
cores associated with these massive star-forming regions show emission lines, clouds in the diffuse interstellar medium are detected in absorption
against the strong submillimeter background. The combination of hyperfine structure with emission and absorption results in complex profiles,
with overlap of the different hyperfine components. The opacities of most of the CH absorption features are linearly correlated with those of CCH,
CN, and HCO^+ in the same velocity intervals. In specific narrow velocity intervals, the opacities of CN and HCO^+ deviate from the mean trends,
giving rise to more opaque absorption features. We propose that CCH can be used as another tracer of the molecular gas in the absence of better
tracers, with [CCH]/[H_2] ~3.2 ± 1.1 × 10^(−8). The observed [CN]/[CH], [CCH]/[CH] abundance ratios suggest that the bulk of the diffuse matter
along the lines of sight has gas densities n_H = n(H) + 2n(H_2) ranging between 100 and 1000 cm^(−3)
Nitrogen hydrides in interstellar gas: Herschel/HIFI observations towards G10.6-0.4 (W31C)
The HIFI instrument on board the Herschel Space Observatory has been used to observe interstellar nitrogen hydrides along the sight-line towards
G10.6−0.4 in order to improve our understanding of the interstellar chemistry of nitrogen. We report observations of absorption in NH N = 1 ← 0,
J = 2 ← 1 and ortho-NH_2 1_(1,1) ← 0_(0,0). We also observed ortho-NH_3 1_0 ← 0_0, and 2_0 ← 1_0, para-NH_3 2_1 ← 1_1, and searched unsuccessfully for
NH^+. All detections show emission and absorption associated directly with the hot-core source itself as well as absorption by foreground material
over a wide range of velocities. All spectra show similar, non-saturated, absorption features, which we attribute to diffuse molecular gas. Total
column densities over the velocity range 11−54 km s^(−1) are estimated. The similar profiles suggest fairly uniform abundances relative to hydrogen,
approximately 6 × 10^(−9), 3 × 10^(−9), and 3 × 10^(−9) for NH, NH_2, and NH_3, respectively. These abundances are discussed with reference to models of
gas-phase and surface chemistry
Plant Science in Reduced Gravity: Lessons Learned
The effect of gravity on the growth and development of plants has been the subject of scientific investigation for over a century. The results obtained in space to test specific hypotheses on gravitropism, gene expression, seed formation, or growth rate are affected by both the primary effect of the microgravity and secondary effects of the spaceflight environment. The secondary effects of the spaceflight environment include physical effects arising from physical changes, such as the absence of buoyancy driven convective mixing, altered behavior of liquids and gases, and the environmental conditions in the spacecraft atmosphere. Thus, the design of biological experiments (e.g. cells, plants, animals, etc.) conducted in microgravity must account for changes in the physical forces, as well as the environmental conditions, imposed by the specific spaceflight vehicle and experimental hardware. In addition, researchers must become familiar with other aspects of spaceflight experiments: payload integration with hardware developers, safety documentation and crew procedures, and the logistics of conducting flight and ground controls. This report reviews the physical and environmental factors that directly and indirectly affect the results of plant science experiments in microgravity and is intended to serve as a guide in the design and implementation plant experiments in space
Ammonia Offgassing from SA9T
NH3 is a degradation product of SA9T, a solid-amine sorbent developed by Hamilton Sundstrand, that is continually emitted into the gas stream being conditioned by this sorbent. NH3 offgassing rates were measured using FTIR spectroscopy using a packed bed at similar contact times as offgassing tests conducted at Hamilton Sundstrand and at the Ames Research Center. The bed was challenged with moist air at several flow rates and humidities and NH3 concentration of the effluent was measured for several hours. The NH3 offgassing rates in open-loop testing were calculated from the steady state outlet NH3 concentration and flow rate. NH3 offgassing rates from SA9T were found to be influenced by the contact time with the adsorbent (flow rate) and by the humidity of the inlet gas stream, which are consistent with previous studies. Closed-loop vacuum-swing adsorption cycling rates verified that NH3 offgassing continues when a constant source of water vapor is present
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