The HIFI instrument on board the Herschel Space Observatory has been used to observe interstellar nitrogen hydrides along the sight-line towards
G10.6−0.4 in order to improve our understanding of the interstellar chemistry of nitrogen. We report observations of absorption in NH N = 1 ← 0,
J = 2 ← 1 and ortho-NH_2 1_(1,1) ← 0_(0,0). We also observed ortho-NH_3 1_0 ← 0_0, and 2_0 ← 1_0, para-NH_3 2_1 ← 1_1, and searched unsuccessfully for
NH^+. All detections show emission and absorption associated directly with the hot-core source itself as well as absorption by foreground material
over a wide range of velocities. All spectra show similar, non-saturated, absorption features, which we attribute to diffuse molecular gas. Total
column densities over the velocity range 11−54 km s^(−1) are estimated. The similar profiles suggest fairly uniform abundances relative to hydrogen,
approximately 6 × 10^(−9), 3 × 10^(−9), and 3 × 10^(−9) for NH, NH_2, and NH_3, respectively. These abundances are discussed with reference to models of
gas-phase and surface chemistry
