12,998 research outputs found
Water adsorption on vanadium oxide thin films in ambient relative humidity.
In this work, ambient pressure x-ray photoelectron spectroscopy (APXPS) is used to study the initial stages of water adsorption on vanadium oxide surfaces. V 2p, O 1s, C 1s, and valence band XPS spectra were collected as a function of relative humidity in a series of isotherm and isobar experiments. Experiments were carried out on two VO2 thin films on TiO2 (100) substrates, prepared with different surface cleaning procedures. Hydroxyl and molecular water surface species were identified, with up to 0.5 ML hydroxide present at the minimum relative humidity, and a consistent molecular water adsorption onset occurring around 0.01% relative humidity. The work function was found to increase with increasing relative humidity, suggesting that surface water and hydroxyl species are oriented with the hydrogen atoms directed away from the surface. Changes in the valence band were also observed as a function of relative humidity. The results were similar to those observed in APXPS experiments on other transition metal oxide surfaces, suggesting that H2O-OH and H2O-H2O surface complex formation plays an important role in the oxide wetting process and water dissociation. Compared to polycrystalline vanadium metal, these vanadium oxide films generate less hydroxide and appear to be more favorable for molecular water adsorption
Octet Baryon Magnetic Moments in the Chiral Quark Model with Configuration Mixing
The Coleman-Glashow sum-rule for magnetic moments is always fulfilled in the
chiral quark model, independently of SU(3) symmetry breaking. This is due to
the structure of the wave functions, coming from the non-relativistic quark
model. Experimentally, the Coleman-Glashow sum-rule is violated by about ten
standard deviations. To overcome this problem, two models of wave functions
with configuration mixing are studied. One of these models violates the
Coleman-Glashow sum-rule to the right degree and also reproduces the octet
baryon magnetic moments rather accurately.Comment: 22 pages, RevTe
Thermal Conversion of Guanylurea Dicyanamide into Graphitic Carbon Nitride via Prototype CNx Precursors
Guanylurea dicyanamide, [(H2N)C(-O)NHC(NH2)2][N(CN)2], has been synthesized by ion exchange reaction in aqueous solution and structurally characterized by single-crystal X-ray diffraction (C2/c, a = 2249.0(5) pm, b = 483.9(1) pm, c = 1382.4(3) pm, β = 99.49(3)°, V = 1483.8(5) × 106 pm3, T = 130 K). The thermal behavior of the molecular salt has been studied by thermal analysis, temperature-programmed X-ray powder diffraction, FTIR spectroscopy, and mass spectrometry between room temperature and 823 K. The results were interpreted on a molecular level in terms of a sequence of thermally induced addition, cyclization, and elimination reactions. As a consequence, melamine (2,4,6-triamino-1,3,5-triazine) is formed with concomitant loss of HNCO. Further condensation of melamine yields the prototypic CNx precursor melem (2,6,10-triamino-s-heptazine, C6N7(NH2)3), which alongside varying amounts of directly formed CNxHy material transforms into layered CNxHy phases without significant integration of oxygen into the core framework owing to the evaporation of HNCO. Thus, further evidence can be added to melamine and its condensation product melem acting as “key intermediates” in the synthetic pathway toward graphitic CNxHy materials, whose exact constitution is still a point at issue. Due to the characteristic formation process and hydrogen content a close relationship with the polymer melon is evident. In particular, the thermal transformation of guanylurea dicyanamide clearly demonstrates that the formation of volatile compounds such as HNCO during thermal decomposition may render a large variety of previously not considered molecular compounds suitable CNx precursors despite the presence of oxygen in the starting material
The Mid-Infrared Instrument for the James Webb Space Telescope, VIII: The MIRI Focal Plane System
We describe the layout and unique features of the focal plane system for
MIRI. We begin with the detector array and its readout integrated circuit
(combining the amplifier unit cells and the multiplexer), the electronics, and
the steps by which the data collection is controlled and the output signals are
digitized and delivered to the JWST spacecraft electronics system. We then
discuss the operation of this MIRI data system, including detector readout
patterns, operation of subarrays, and data formats. Finally, we summarize the
performance of the system, including remaining anomalies that need to be
corrected in the data pipeline
Elusive vector glueball
If the vector glueball exists in the mass range that theory suggests, its
resonance production cross section can be seen in e+e- annihilation only if the
decay width is very narrow (< a few MeV). Otherwise it willbe observed only
indirectly through its mixing with psi(2S). A few tests of the glueball-psi'
mixing are proposed for future charm factories.Comment: One misleading short sentence delete
Sea Contributions and Nucleon Structure
We suggest a general formalism to treat a baryon as a composite system of
three quarks and a `sea'. In this formalism, the sea is a cluster which can
consists of gluons and quark-antiquark pairs. The hadron wave function with a
sea component is given. The magnetic moments, related sum rules and axial weak
coupling constants are obtained. The data seems to favor a vector sea rather
than a scalar sea. The quark spin distributions in the nucleon are also
discussed.Comment: 24 page
Radio-frequency discharges in Oxygen. Part 1: Modeling
In this series of three papers we present results from a combined
experimental and theoretical effort to quantitatively describe capacitively
coupled radio-frequency discharges in oxygen. The particle-in-cell Monte-Carlo
model on which the theoretical description is based will be described in the
present paper. It treats space charge fields and transport processes on an
equal footing with the most important plasma-chemical reactions. For given
external voltage and pressure, the model determines the electric potential
within the discharge and the distribution functions for electrons, negatively
charged atomic oxygen, and positively charged molecular oxygen. Previously used
scattering and reaction cross section data are critically assessed and in some
cases modified. To validate our model, we compare the densities in the bulk of
the discharge with experimental data and find good agreement, indicating that
essential aspects of an oxygen discharge are captured.Comment: 11 pages, 10 figure
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