Dissipative mean-field theory of IBM utility experiment

In spite of remarkable recent advances, quantum computers have not yet found any useful applications. A promising direction for such utility is offered by the simulation of the dynamics of many-body quantum systems, which cannot be efficiently computed classically. Recently, IBM used a superconducting quantum computer to simulate a kicked quantum Ising model for large numbers of qubits and time steps. By employing powerful error mitigation techniques, they were able to obtain an excellent agreement with the exact solution of the model. This result is very surprising, considering that the total error accumulated by the circuit is prohibitively large. In this letter, we address this paradox by introducing a dissipative mean-field approximation based on Kraus operators. Our effective theory reproduces the many-body unitary dynamics and matches quantitatively local and non-local observables. These findings demonstrate that the observed dynamics is equivalent to a single qubit undergoing rotations and dephasing. Our emergent description can explain the success of the quantum computer in solving this specific problem.Comment: 4 pages, 2 figure

Acid catalyzed synthesis of dimethyl isosorbide via dimethyl carbonate chemistry

Dimethyl isosorbide (DMI) is a bio-based solvent that can be used as green alternative for conventional dipolar media (dimethyl sulfoxide, dimethylformamide, and dimethylacetamide). The main synthetic procedures to DMI reported in the literature are based on the methylation of isosorbide employing different alkylating agents including toxic halogen compounds such as alkyl halides. A more sustainable alternative would be to employ dimethyl carbonate (DMC), a well-known green reagent and solvent, considered one of the most promising methylating agents for its good biodegradability and low toxicity. Indeed, in recent years, DMC-promoted methylation of isosorbide has been extensively exploited although mostly in the presence of a base or an amphoteric catalyst. In this work, we report for the first time a comprehensive investigation on the synthesis of DMI via DMC chemistry promoted by heterogeneous acid catalyst (Amberlyst-36 and Purolite CT275DR). Re- action conditions were optimized and then applied for the methylation of isosorbide and its epimers, isoidide and isomannide. Considerations on the related reaction mechanism were reported highlighting the difference in the preferred reaction pathways among this new synthetic approach and the previously reported base-catalyzed procedures

Dissipative Preparation of Spin Squeezed Atomic Ensembles in a Steady State

We present and analyze a new approach for the generation of atomic spin squeezed states. Our method involves the collective coupling of an atomic ensemble to a decaying mode of an open optical cavity. We demonstrate the existence of a collective atomic dark-state, decoupled from the radiation field. By explicitly constructing this state we find that it can feature spin squeezing bounded only by the Heisenberg limit. We show that such dark states can be deterministically prepared via dissipative means, thus turning dissipation into a resource for entanglement. The scaling of the phase sensitivity taking realistic imperfections into account is discussed.Comment: 5 pages, 4 figure

The interaction of aluminum with catecholamine-based neurotransmitters: Can the formation of these species be considered a potential risk factor for neurodegenerative diseases?

The potential neurotoxic role of Al(iii) and its proposed link with the insurgence of Alzheimer's Disease (AD) have attracted increasing interest towards the determination of the nature of bioligands that are propitious to interact with aluminum. Among them, catecholamine-based neurotransmitters have been proposed to be sensitive to the presence of this non-essential metal ion in the brain. In the present work, we characterize several aluminum-catecholamine complexes in various stoichiometries, determining their structure and thermodynamics of formation. For this purpose, we apply a recently validated computational protocol with results that show a remarkably good agreement with the available experimental data. In particular, we employ Density Functional Theory (DFT) in conjunction with continuum solvation models to calculate complexation energies of aluminum for a set of four important catecholamines: l-DOPA, dopamine, noradrenaline and adrenaline. In addition, by means of the Quantum Theory of Atoms in Molecules (QTAIM) and Energy Decomposition Analysis (EDA) we assessed the nature of the Al-ligand interactions, finding mainly ionic bonds with an important degree of covalent character. Our results point at the possibility of the formation of aluminum-catecholamine complexes with favorable formation energies, even when proton/aluminum competition is taken into account. Indeed, we found that these catecholamines are better aluminum binders than catechol at physiological pH, because of the electron withdrawing effect of the positively-charged amine that decreases their deprotonation penalty with respect to catechol. However, overall, our results show that, in an open biological environment, the formation of Al-catecholamine complexes is not thermodynamically competitive when compared with the formation of other aluminum species in solution such as Al-hydroxide, or when considering other endogenous/exogenous Al(iii) ligands such as citrate, deferiprone and EDTA. In summary, we rule out the possibility, suggested by some authors, that the formation of Al-catecholamine complexes in solution might be behind some of the toxic roles attributed to aluminum in the brain. An up-to-date view of the catecholamine biosynthesis pathway with sites of aluminum interference (according to the current literature) is presented. Alternative mechanisms that might explain the deleterious effects of this metal on the catecholamine route are thoroughly discussed, and new hypotheses that should be investigated in future are proposed

RHIP, a Radio-controlled High-Voltage Insulated Picoammeter and its usage in studying ion backflow in MPGD-based photon detectors

A picoammeter system has been developed and engineering. It consists in a current-voltage converter, based on an operational amplifier with very low input current, a high precision ADC, a radio controlled data acquisition unit and the computer-based control, visualization and storage. The precision is of the order of a tenth of picoampers and it can measure currents between electrodes at potentials up to 8 kV. The system is battery powered and a number of strategies have been implemented to limit the power consumption. The system is designed for multichannel applications, up to 256 parallel channels. The overall implementation is cost-effective to make the availability of multichannel setups easily affordable. The design, implementation and performance of the picoammeter system are described in detail as well as a an application: the measurement of ion backflow in MPGD-based photon detectors.Comment: 5th International Conference on Micro-Pattern Gas Detectors (MPGD2017), presentation by Silvia Dalla Torr

Study of MicroPattern Gaseous detectors with novel nanodiamond based photocathodes for single photon detection in EIC RICH

Identification of high momentum hadrons at the future EIC is crucial, gaseous RICH detectors are therefore viable option. Compact collider setups impose to construct RICHes with small radiator length, hence significantly limiting the number of detected photons. More photons can be detected in the far UV region, using a windowless RICH approach. QE of CsI degrades under strong irradiation and air contamination. Nanodiamond based photocathodes (PCs) are being developed as an alternative to CsI. Recent development of layers of hydrogenated nanodiamond powders as an alternative photosensitive material and their performance, when coupled to the THick Gaseous Electron Multipliers (THGEM)-based detectors, are the objects of an ongoing R\&D. We report about the initial phase of our studies.Comment: 3 pages, 5 figures, RICH2018 conference proceedin

Introduction to the Dicke model : from equilibrium to nonequilibrium, and vice versa

P.K. acknowledges support from EPSRC (EP/M010910/1) and the Austrian Academy of Sciences (ÖAW). P.K. and J.K. acknowledge support from EPSRC program “Hybrid Polaritonics” (EP/M025330/1).The Dicke model describes the coupling between a quantized cavity field and a large ensemble of two-level atoms. When the number of atoms tends to infinity, this model can undergo a transition to a superradiant phase, belonging to the mean-field Ising universality class. The superradiant transition was first predicted for atoms in thermal equilibrium, but its experimental realizations required driven-dissipative systems. In this Progress Report, we offer an introduction to some theoretical concepts relevant to the Dicke model, reviewing the critical properties of the superradiant phase transition, and the distinction between equilibrium and nonequilibrium conditions. In addition, we explain the fundamental difference between the superradiant phase transition and the more common lasing transition. Our report mostly focuses on the steady states of single-mode optical cavities, but we also mention some aspects of real-time dynamics, as well as applications to multimode cavities, superconducting circuits, and trapped ions.PostprintPeer reviewe

Rise and fall of hidden string order of lattice bosons

We investigate the ground state properties of a newly discovered phase of one dimensional lattice bosons with extended interactions (see E. G. Dalla Torre et al., Phys. Rev. Lett. \textbf{97}, 260401 (2006)). The new phase, termed the Haldane Insulator (HI) in analogy with the gapped phase of spin-1 chains, is characterized by a non local order parameter, which can only be written as an infinite string in terms of the bosonic densities. We show that the string order can nevertheless be probed with physical fields that couple locally, via the effect those fields have on the quantum phase transitions separating the exotic phase from the conventional Mott and density wave phases. Using a field theoretical analysis we show that a perturbation which breaks lattice inversion symmetry gaps the critical point separating the Mott and Haldane phases and eliminates the sharp distinction between them. This is remarkable given that neither of these phases involves broken inversion symmetry. We also investigate the evolution of the phase diagram with the tunable coupling between parallel chains in an optical lattice setup. We find that inter-chain tunneling destroys the direct phase transition between the Mott and Haldane insulators by establishing an intermediate superfluid phase. On the other hand coupling the chains only by weak repulsive interactions does not modify the structure of the phase diagram. The theoretical predictions are confirmed with numerical calculations using the Density Matrix Renormalization Group (DMRG).Comment: 15 pages, 8 figures. Minor corrections, published versio