SYMMETRIC BLOCK COPOLYMERS TEMPLATES FOR NANO-LITHOGRAPHIC APPLICATIONS

Nanofabrication has been long characterized by a top-down approach for the definition of small features starting from large pieces of material. In this contest the process of size scaling in microelectronics devices is based on photolithography that is an advanced top-down technology. In order to design integrated circuits with small features with characteristic dimension below 20 nm, a new kind of approach is needed such as the bottom-up one of self-assembly systems. Indeed symmetric block copolymers are able to spontaneously phase separate into ordered nanoscale lamellar pattern, which can be fruitfully implemented into the fabrication of next generation of microelectronics devices. This thesis offers a systematic study of the thermodynamics and kinetics of the self-assembly process of lamellae forming block copolymers in view of their possible exploitation as lithographic materials

Rare earth doped ceria: The complex connection between structure and properties

The need for high efficiency energy production, conversion, storage and transport is serving as a robust guide for the development of new materials. Materials with physical-chemical properties matching specific functions in devices are produced by suitably tuning the crystallographic- defect- and micro-structure of the involved phases. In this review, we discuss the case of Rare Earth doped Ceria. Due to their high oxygen diffusion coefficient at temperatures higher than ~500\ub0C, they are very promising materials for several applications such as electrolytes for Solid Oxide Fuel and Electrolytic Cells (SOFC and SOEC, respectively). Defects are integral part of the conduction process, hence of the final application. As the fluorite structure of ceria is capable of accommodating a high concentration of lattice defects, the characterization and comprehension of such complex and highly defective materials involve expertise spanning from computational chemistry, physical chemistry, catalysis, electrochemistry, microscopy, spectroscopy, and crystallography. Results coming from different experimental and computational techniques will be reviewed, showing that structure determination (at different scale length) plays a pivotal role bridging theoretical calculation and physical properties of these complex materials

NMR and NQR parameters of ethanol crystal

Electric field gradients and chemical shielding tensors of the stable monoclinic crystal phase of ethanol are computed. The projector-augmented wave (PAW) and gauge-including projector-augmented wave (GIPAW) models in the periodic plane-wave density functional theory are used. The crystal data from X-ray measurements, as well as the structures where either all atomic, or only hydrogen atom positions are optimized in the density functional theory are analyzed. These structural models are also studied by including the semi-empirical Van der Waals correction to the density functional theory. Infrared spectra of these five crystal models are calculated

WSES classification and guidelines for liver trauma

The severity of liver injuries has been universally classified according to the American Association for the Surgery of Trauma (AAST) grading scale. In determining the optimal treatment strategy, however, the haemodynamic status and associated injuries should be considered. Thus the management of liver trauma is ultimately based on the anatomy of the injury and the physiology of the patient. This paper presents the World Society of Emergency Surgery (WSES) classification of liver trauma and the management Guidelines

Dynamic effective anisotropy: Asymptotics, simulations, and microwave experiments with dielectric fibers

International audienceWe investigate dynamic effective anisotropy in photonic crystals (PCs) through a combination of an effective medium theory, which is a high-frequency homogenization (HFH) method explicitly developed to operate for short waves, as well as through numerical simulations and microwave experiments. The HFH yields accurate predictions of the effective anisotropic properties of periodic structures when the wavelength is of comparable order to the pitch of the array; specifically, we investigate a square array of pitch 2 cm consisting of dielectric rods of radius 0.5 cm and refractive index n=6√ within an air matrix. This behaves as an effective medium, with strong artificial anisotropy, at a frequency corresponding to a flat band emerging from a Dirac-like point in transverse magnetic (TM) polarization. At this frequency, highly directive emission is predicted for an electric source placed inside this PC, and this artificial anisotropy can be shown to coincide with a change of character of the underlying effective equation from isotropic to unidirective, with coefficients of markedly different magnitudes appearing in the effective equation tensor. In transverse electric (TE) polarization, we note a second radical change of character of the underlying effective equation, this time from elliptic to hyperbolic, near a frequency at which a saddle point occurs in the corresponding dispersion curves. Delicate microwave experiments are performed in both polarizations for such a PC consisting of 80 rods, and we demonstrate that a directive emission in the form of a + (respectively, an X) is indeed seen experimentally at the predicted frequency 9.5 GHz in TM polarization (respectively, 5.9 GHz in TE polarization). These are clearly dynamic effects since in the quasistatic regime the PC just behaves as an isotropic medium

Charging Induced Emission of Neutral Atoms from NaCl Nanocube Corners

Detachment of neutral cations/anions from solid alkali halides can in principle be provoked by donating/subtracting electrons to the surface of alkali halide crystals, but generally constitutes a very endothermic process. However, the amount of energy required for emission is smaller for atoms located in less favorable positions, such as surface steps and kinks. For a corner ion in an alkali halide cube the binding is the weakest, so it should be easier to remove that atom, once it is neutralized. We carried out first principles density functional calculations and simulations of neutral and charged NaCl nanocubes, to establish the energetics of extraction of neutralized corner ions. Following hole donation (electron removal) we find that detachment of neutral Cl corner atoms will require a limited energy of about 0.8 eV. Conversely, following the donation of an excess electron to the cube, a neutral Na atom is extractable from the corner at the lower cost of about 0.6 eV. Since the cube electron affinity level (close to that a NaCl(100) surface state, which we also determine) is estimated to lie about 1.8 eV below vacuum, the overall energy balance upon donation to the nanocube of a zero energy electron from vacuum will be exothermic. The atomic and electronic structure of the NaCl(100) surface, and of the nanocube Na and Cl corner vacancies are obtained and analyzed as a byproduct.Comment: 16 pages, 2 table, 7 figure

Timing of Early Cholecystectomy for Acute Calculous Cholecystitis: A Multicentric Prospective Observational Study

The definition of Early Cholecystectomy (EC) is still debatable. This paper aims to find whether the timing of EC affects outcomes. The article reports a multicentric prospective observational study including patients with acute calculous cholecystitis (ACC) who had cholecystectomy within ten days from the onset of symptoms. Kruskall-Wallis test, Fisher’s Exact test, and Spearman rank correlation were used for statistical analysis. The patients were divided into three groups depending on the timing of the operation: 0–3 days, 4–7 days, or 8–10 days from the onset of symptoms. 1117 patients were studied over a year. The time from the onset of symptoms to EC did not affect the post-operative complications and mortality, the conversion, and the reintervention rate. The time represented a significant risk factor for intraoperative complications (0–3 days, 2.8%; 4–7 days, 5.6%; 8–10 days, 7.9%; p = 0.01) and subtotal cholecystectomies (0–3 days, 2.7%; 4–7 days, 5.6%; 8–10 days, 10.9%; p < 0.001). ACC is an evolutive inflammatory process and, as the days go by, the local and systemic inflammation increases, making surgery more complex and difficult with a higher risk of intraoperative complications. We recommend performing EC for ACC as soon as possible, within the first ten days of the onset of symptoms