1,996 research outputs found

    The order-disorder transition of the (3x3)Sn/Ge(111) phase

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    Growing attention has been drawn in the past years to the \alpha-phase (1/3 monolayer) of Sn on Ge(111), which undergoes a transition from the low temperature (3x3) phase to the room temperature (\sqrt3 x \sqrt3)R30 one. On the basis of scanning tunnelling microscopy experiments, this transition was claimed to be the manifestation of a surface charge density wave (SCDW), i.e. a periodic redistribution of charge, possibly accompanied by a periodic lattice distortion, which determines a change of the surface symmetry. As further experiments with different techniques were being performed, increasing doubts were cast about the SCDW model. We have measured by He scattering the long range order of the 1/3 monolayer phase of Sn on the Ge(111) surface throughout the phase transition. The transition has been found of the order-disorder type with a critical temperature Tc=220 K. The expected 3-State Potts critical exponents are shown to be consistent with the observed power law dependence of the (3x3) order parameter and its correlation length close to Tc, thus excluding a charge density wave driven phase transition.Comment: 6 pages with 4 figures; updated reference

    Crystal structure of the yellow 1:2 molecular complex lumiflavin–bisnaphthalene-2,3-diol

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    In the first molecular complex of the physiologically active neutral form of isoalloxazine studied, lumiflavin–bisnaphthalene-2,3-diol, each flavin is sandwiched between two naphthalenediol molecules with extensive overlap but a moderately large (3·44 Å) spacing, indicating at most weak charge-transfer interaction and in agreement with the yellow colour of the complex, nearly the same as that of the parent lumiflavin

    Kainate Receptor-Mediated Modulation of Hippocampal Fast Spiking Interneurons in a Rat Model of Schizophrenia

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    Kainate receptor (KAR) subunits are believed to be involved in abnormal GABAergic neurotransmission in the hippocampus (HIPP) in schizophrenia (SZ) and bipolar disorder. Postmortem studies have shown changes in the expression of the GluR5/6 subunits of KARs in the stratum oriens (SO) of sectors CA2/3, where the basolateral amygdala (BLA) sends a robust projection. Previous work using a rat model of SZ demonstrated that BLA activation leads to electrophysiological changes in fast-spiking interneurons in SO of CA2/3. The present study explores KAR modulation of interneurons in CA2/3 in response to BLA activation. Intrinsic firing properties of these interneurons through KAR-mediated activity were measured with patch-clamp recordings from rats that received 15 days of picrotoxin infusion into the BLA. Chronic BLA activation induced changes in the firing properties of CA2/3 interneurons associated with modifications in the function of KARs. Specifically, the responsiveness of these interneurons to activation of KARs was diminished in picrotoxin-treated rats, while the after-hyperpolarization (AHP) amplitude was increased. In addition, we tested blockers of KAR subunits which have been shown to have altered gene expression in SO sector CA2/3 of SZ subjects. The GluR5 antagonist UBP296 further decreased AP frequency and increased AHP amplitude in picrotoxin-treated rats. Application of the GluR6/7 antagonist NS102 suggested that activation of GluR6/7 KARs may be required to maintain the high firing rates in SO interneurons in the presence of KA. Moreover, the GluR6/7 KAR-mediated signaling may be suppressed in PICRO-treated rats. Our findings indicate that glutamatergic activity from the BLA may modulate the firing properties of CA2/3 interneurons through GluR5 and GluR6/7 KARs. These receptors are expressed in GABAergic interneurons and play a key role in the synchronization of gamma oscillations. Modulation of interneuronal activity through KARs in response to amygdala activation may lead to abnormal oscillatory rhythms reported in SZ subjects

    Psychology and the Church: An Exemplar of Psychologist-Clergy Collaboration

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    Despite the increasing attention being given to clergy-psychologist collaboration, many psychologists may wonder what clergy-psychologist collaboration looks like in actual practice. The authors describe an example of clergy-psychologist collaboration involving a careful needs-assessment phase followed by the development of a wide spectrum of preventive, consultative, and direct services. Current challenges include funding, establishment of trust, and the integration of psychology and spirituality. Implications for professional psychologists are discussed

    Highly permeable and mechanically robust silicon carbide hollow fiber membranes

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    Silicon carbide (SiC) membranes have shown large potential for applications in water treatment. Being able to make these membranes in a hollow fiber geometry allows for higher surface-to-volume ratios. In this study, we present a thermal treatment procedure that is tuned to produce porous silicon carbide hollow fiber membranes with sufficient mechanical strength. Thermal treatments up to 1500 °C in either nitrogen or argon resulted in relatively strong fibers, that were still contaminated with residual carbon from the polymer binder. After treatment at a higher temperature of 1790 °C, the mechanical strength had decreased as a result of carbon removal, but after treatments at even higher temperature of 2075 °C the SiC-particles sinter together, resulting in fibers with mechanical strengths of 30–40 MPa and exceptionally high water permeabilities of 50,000 L m−2 h−1 bar−1. Combined with the unique chemical and thermal resistance of silicon carbide, these properties make the fibers suitable microfiltration membranes or as a membrane support for application under demanding condition

    How Prosecutors and Defense Attorneys Differ in Their Use of Neuroscience Evidence

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    Much of the public debate surrounding the intersection of neuroscience and criminal law is based on assumptions about how prosecutors and defense attorneys differ in their use of neuroscience evidence. For example, according to some commentators, the defense’s use of neuroscience evidence will abdicate criminals of all responsibility for their offenses. In contrast, the prosecution’s use of that same evidence will unfairly punish the most vulnerable defendants as unfixable future dangers to society. This “double- edged sword” view of neuroscience evidence is important for flagging concerns about the law’s construction of criminal responsibility and punishment: it demonstrates that the same information about the defendant can either be mitigating or aggravating depending on who is raising it. Yet empirical assessments of legal decisions reveal a far more nuanced reality, showing that public beliefs about the impact of neuroscience on the criminal law can often be wrong. This Article takes an evidence-based and multidisciplinary approach to examining how courts respond to neuroscience evidence in capital cases when the defense presents it to argue that the defendant’s mental state at the time of the crime was below the given legal requisite due to some neurologic or cognitive deficiency
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