8,463 research outputs found
Thermal behavior of radiation damage cascades via the binary collision approximation: Comparison with molecular dynamics results
Based on the profile of the energy deposition obtained using the binary collision model, we follow the diffusion of energy by solving a simplified version of the heat equation. An estimation of the molten zone compares very well with the molecular dynamics prediction for the same event. We discuss the reasons for this agreement and the relevance of such simplified procedure in terms of present-day computer limitations to simulate high energy cascades using molecular dynamic
Investigation of HNCO isomers formation in ice mantles by UV and thermal processing: an experimental approach
Current gas phase models do not account for the abundances of HNCO isomers
detected in various environments, suggesting a formation in icy grain mantles.
We attempted to study a formation channel of HNCO and its possible isomers by
vacuum-UV photoprocessing of interstellar ice analogues containing HO,
NH, CO, HCN, CHOH, CH, and N followed by warm-up, under
astrophysically relevant conditions. Only the HO:NH:CO and HO:HCN
ice mixtures led to the production of HNCO species. The possible isomerization
of HNCO to its higher energy tautomers following irradiation or due to ice
warm-up has been scrutinized. The photochemistry and thermal chemistry of
HO:NH:CO and HO:HCN ices was simulated using the Interstellar
Astrochemistry Chamber (ISAC), a state-of-the-art ultra-high-vacuum setup. The
ice was monitored in situ by Fourier transform mid-infrared spectroscopy in
transmittance. A quadrupole mass spectrometer (QMS) detected the desorption of
the molecules in the gas phase. UV-photoprocessing of
HO:NH:CO/HO:HCN ices lead to the formation of OCN as main
product in the solid state and a minor amount of HNCO. The second isomer HOCN
has been tentatively identified. Despite its low efficiency, the formation of
HNCO and the HOCN isomers by UV-photoprocessing of realistic simulated ice
mantles, might explain the observed abundances of these species in PDRs, hot
cores, and dark clouds
Influence of the irradiation temperature on the intracascade ion mixing
We present a description of the thermal behavior of cascades in Cu and Ag over a large energy range and irradiation temperatures. For this purpose the binary collision approximation, which gives the profile of the energy deposition, is coupled to a simplified version of the heat equation. In the present calculations, the original liquid drop model [M. Alurralde, A. Caro, and M. Victoria, J. Nucl. Mater. 183, 33 (1991)] has been extended to the case where the lattice is at finite temperatures. The resulting evolution of the liquid cascade is analyzed for PKA energies up to 1 MeV, and the results are compared to experimental observations of mixing rates. We obtain a temperature dependence that adds to the traditional Radiation Enhanced Diffusion, RED, in very good qualitative agreement with experiments on materials showing thermal spike
Typing Quantum Superpositions and Measurement
We propose a way to unify two approaches of non-cloning in quantum lambda-calculi. The first approach is to forbid duplicating variables, while the second is to consider all lambda-terms as algebraic-linear functions. We illustrate this idea by defining a quantum extension of first-order simply-typed lambda-calculus, where the type is linear on superposition, while allows cloning base vectors. In addition, we provide an interpretation of the calculus where superposed types are interpreted as vector spaces and non-superposed types as their basis.Fil: Díaz Caro, Alejandro. Universidad Nacional de Quilmes. Departamento de Ciencia y Tecnología; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas; ArgentinaFil: Dowek, Gilles. Institut National de Recherche en Informatique et en Automatique; Franci
Vacuum-UV spectroscopy of interstellar ice analogs. II. Absorption cross-sections of nonpolar ice molecules
Dust grains in cold circumstellar regions and dark-cloud interiors at 10-20 K
are covered by ice mantles. A nonthermal desorption mechanism is invoked to
explain the presence of gas-phase molecules in these environments, such as the
photodesorption induced by irradiation of ice due to secondary ultraviolet
photons. To quantify the effects of ice photoprocessing, an estimate of the
photon absorption in ice mantles is required. In a recent work, we reported the
vacuum-ultraviolet (VUV) absorption cross sections of nonpolar molecules in the
solid phase. The aim was to estimate the VUV-absorption cross sections of
nonpolar molecular ice components, including CH4, CO2, N2, and O2. The column
densities of the ice samples deposited at 8 K were measured in situ by infrared
spectroscopy in transmittance. VUV spectra of the ice samples were collected in
the 120-160 nm (10.33-7.74 eV) range using a commercial microwave-discharged
hydrogen flow lamp. We found that, as expected, solid N2 has the lowest
VUV-absorption cross section, which about three orders of magnitude lower than
that of other species such as O2, which is also homonuclear. Methane (CH4) ice
presents a high absorption near Ly-alpha (121.6 nm) and does not absorb below
148 nm. Estimating the ice absorption cross sections is essential for models of
ice photoprocessing and allows estimating the ice photodesorption rates as the
number of photodesorbed molecules per absorbed photon in the ice.Comment: 9 pages, 6 figures, 7 table
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