Dust grains in cold circumstellar regions and dark-cloud interiors at 10-20 K
are covered by ice mantles. A nonthermal desorption mechanism is invoked to
explain the presence of gas-phase molecules in these environments, such as the
photodesorption induced by irradiation of ice due to secondary ultraviolet
photons. To quantify the effects of ice photoprocessing, an estimate of the
photon absorption in ice mantles is required. In a recent work, we reported the
vacuum-ultraviolet (VUV) absorption cross sections of nonpolar molecules in the
solid phase. The aim was to estimate the VUV-absorption cross sections of
nonpolar molecular ice components, including CH4, CO2, N2, and O2. The column
densities of the ice samples deposited at 8 K were measured in situ by infrared
spectroscopy in transmittance. VUV spectra of the ice samples were collected in
the 120-160 nm (10.33-7.74 eV) range using a commercial microwave-discharged
hydrogen flow lamp. We found that, as expected, solid N2 has the lowest
VUV-absorption cross section, which about three orders of magnitude lower than
that of other species such as O2, which is also homonuclear. Methane (CH4) ice
presents a high absorption near Ly-alpha (121.6 nm) and does not absorb below
148 nm. Estimating the ice absorption cross sections is essential for models of
ice photoprocessing and allows estimating the ice photodesorption rates as the
number of photodesorbed molecules per absorbed photon in the ice.Comment: 9 pages, 6 figures, 7 table
