41 research outputs found

    Effect of differences in proton and neutron density distributions on fission barriers

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    The neutron and proton density distributions obtained in constrained Hartree-Fock-Bogolyubov calculations with the Gogny force along the fission paths of 232Th, 236U, 238U and 240Pu are analyzed. Significant differences in the multipole deformations of neutron and proton densities are found. The effect on potential energy surfaces and on barrier heights of an additional constraint imposing similar spatial distributions to neutrons and protons, as assumed in macroscopic-microscopic models, is studied.Comment: 5 pages in Latex, 4 figures in ep

    Size exclusion chromatography for analyses of fibroin in silk : optimization of sampling and separation conditions

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    A direct goal of this paper was to improve the methods of sample preparation and separation for analyses of fibroin polypeptide with the use of size exclusion chromatography (SEC). The motivation for the study arises from our interest in natural polymers included in historic textile and paper artifacts, and is a logical response to the urgent need for developing rationale-based methods for materials conservation. The first step is to develop a reli- able analytical tool which would give insight into fibroin structure and its changes caused by both natural and arti- ficial ageing. To investigate the influence of preparation conditions, two sets of artificially aged samples were pre- pared (with and without NaCl in sample solution) and measured by the means of SEC with multi angle laser light scattering detector. It was shown that dialysis of fibroin dissolved in LiBr solution allows removal of the salt which destroys stacks chromatographic columns and prevents reproducible analyses. Salt rich (NaCl) water solutions of fibroin improved the quality of chromatograms

    Ground state properties of the β\beta stable nuclei in various mean field theories

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    The separation energies of neutrons and protons, binding energies, mean square charge radii, electric quadrupole moments and deformation parameters of the proton and neutron distributions are evaluated for β\beta stable even-even nuclei with 16A25616 \leq A \leq 256. We compare the theoretical estimates obtained within the Hartree-Fock plus BCS model with a few sets of Skyrme forces, relativistic mean-field theory and frequently used Saxon-Woods and Nilsson potentials with experimental data.Comment: 15 pages, latex, 3 tables, 14 figures in thr eps format include

    La conservazione preventiva del patrimonio librario come possibile alternativa al restauro tradizionale

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    The present paper focuses on the close relation between library collections and their preservation environment, aiming, in particular, at highlighting the importance of promoting and sustaining the monitoring. The paper proposes some simple and ready-to-use technologies – smart monitoring – to prevent future damages

    Acid-catalysed degradation

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    Towards determination of absolute molar mass of cellulose polymer by size exclusion chromatography with mulitple angle laser light scattering detection

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    The study focuses on determination of a set of crucial parameters for molar mass calculation of cellulose from the results of size exclusion chromatography coupled with multiple angle laser light scattering (MALLS) and differential refractive index (DRI) detectors. In the present work, cellulose has been derivatised to obtain cellulose tricarbanilate (CTC) soluble in tetrahydrofuran (THF). The parameters of Rayleigh scattering in the MALLS detector: refractive index increment (dn/dc) and second virial coefficient (A2) of CTC in THF were determined for laser wavelength 658 nm. In order to avoid errors resulting from cellulose derivatisation by-products present in the CTC solution, the so called “on-line” method of measuring dn/dc and A2 was applied. Based on the A2 determination, its influence on cellulose molar mass calculations and cellulose molecular dimensions were critically assessed. The latter includes evaluation of artificially aged cellulose towards conceivable branching by conformation plot analysis
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