5,318 research outputs found
Mapping the structural diversity of C60 carbon clusters and their infrared spectra
The current debate about the nature of the carbonaceous material carrying the
infrared (IR) emission spectra of planetary and proto-planetary nebulae,
including the broad plateaus, calls for further studies on the interplay
between structure and spectroscopy of carbon-based compounds of astrophysical
interest. The recent observation of C60 buckminsterfullerene in space suggests
that carbon clusters of similar size may also be relevant. In the present work,
broad statistical samples of C60 isomers were computationally determined
without any bias using a reactive force field, their IR spectra being
subsequently obtained following local optimization with the
density-functional-based tight-binding theory. Structural analysis reveals four
main structural families identified as cages, planar polycyclic aromatics,
pretzels, and branched. Comparison with available astronomical spectra
indicates that only the cage family could contribute to the plateau observed in
the 6-9 micron region. The present framework shows great promise to explore and
relate structural and spectroscopic features in more diverse and possibly
hydrogenated carbonaceous compounds, in relation with astronomical
observations
The Ljapunov-Schmidt reduction for some critical problems
This is a survey about the application of the Ljapunov-Schmidt reduction for
some critical problems
Magnetic Field Effects on the Head Structure of Protostellar Jets
We present the results of 3-D SPMHD numerical simulations of
supermagnetosonic, overdense, radiatively cooling jets. Two initial magnetic
configurations are considered: (i) a helical and (ii) a longitudinal field. We
find that magnetic fields have important effects on the dynamics and structure
of radiative cooling jets, especially at the head. The presence of a helical
field suppresses the formation of the clumpy structure which is found to
develop at the head of purely hydrodynamical jets. On the other hand, a cooling
jet embedded in a longitudinal magnetic field retains clumpy morphology at its
head. This fragmented structure resembles the knotty pattern commonly observed
in HH objects behind the bow shocks of HH jets. This suggests that a strong
(equipartition) helical magnetic field configuration is ruled out at the jet
head. Therefore, if strong magnetic fields are present, they are probably
predominantly longitudinal in those regions. In both magnetic configurations,
we find that the confining pressure of the cocoon is able to excite
short-wavelength MHD K-H pinch modes that drive low-amplitude internal shocks
along the beam. These shocks are not strong however, and it likely that they
could only play a secondary role in the formation of the bright knots observed
in HH jets.Comment: 14 pages, 2 Gif figures, uses aasms4.sty. Also available on the web
page http://www.iagusp.usp.br/preprints/preprint.html. To appear in The
Astrophysical Journal Letter
Size effect in the ionization energy of PAH clusters
We report the first experimental measurement of the near-threshold
photo-ionization spectra of polycyclic aromatic hydrocarbon clusters made of
pyrene C16H10 and coronene C24H12, obtained using imaging photoelectron
photoion coincidence spectrometry with a VUV synchrotron beamline. The
experimental results of the ionization energy are confronted to calculated ones
obtained from simulations using dedicated electronic structure treatment for
large ionized molecular clusters. Experiment and theory consistently find a
decrease of the ionization energy with cluster size. The inclusion of
temperature effects in the simulations leads to a lowering of this energy and
to a quantitative agreement with the experiment. In the case of pyrene, both
theory and experiment show a discontinuity in the IE trend for the hexamer
Mid-infrared signatures of hydroxyl containing water clusters: Infrared laser Stark spectroscopy of OHâH2O and OH(D2O)n (n = 1-3)
Small water clusters containing a single hydroxyl radical are synthesized in liquid helium droplets. The OHâH2O and OH(D2O)n clusters (n = 1-3) are probed with infrared laser spectroscopy in the vicinity of the hydroxyl radical OH stretch vibration. Experimental band origins are qualitatively consistent with ab initio calculations of the global minimum structures; however, frequency shifts from isolated OH are significantly over-predicted by both B3LYP and MP2 methods. An effective Hamiltonian that accounts for partial quenching of electronic angular momentum is used to analyze Stark spectra of the OHâH2O and OHâD2O binary complexes, revealing a 3.70(5) D permanent electric dipole moment. Computations of the dipole moment are in good agreement with experiment when large-amplitude vibrational averaging is taken into account. Polarization spectroscopy is employed to characterize two vibrational bands assigned to OH(D2O)2, revealing two nearly isoenergetic cyclic isomers that differ in the orientation of the non-hydrogen-bonded deuterium atoms relative to the plane of the three oxygen atoms. The dipole moments for these clusters are determined to be approximately 2.5 and 1.8 D for âup-upâ and âup-downâ structures, respectively. Hydroxyl stretching bands of larger clusters containing three or more D2O molecules are observed shifted approximately 300 cmâ1 to the red of the isolated OH radical. Pressure dependence studies and ab initio calculations imply the presence of multiple cyclic isomers of OH(D2O)3.Fil: HernĂĄndez, Federico Javier. Consejo Nacional de Investigaciones CientĂficas y TĂ©cnicas. Centro CientĂfico TecnolĂłgico Conicet - CĂłrdoba. Instituto de Investigaciones en FĂsico-quĂmica de CĂłrdoba. Universidad Nacional de CĂłrdoba. Facultad de Ciencias QuĂmicas. Instituto de Investigaciones en FĂsico-quĂmica de CĂłrdoba; Argentina. University of Georgia; Estados UnidosFil: Brice, Joseph T.. University of Georgia; Estados UnidosFil: Leavitt, Christopher M.. University of Georgia; Estados UnidosFil: Liang, Tao. University of Georgia; Estados UnidosFil: Raston, Paul L.. James Madison University. Department of Chemistry and Biochemistry; Estados UnidosFil: Pino, Gustavo Ariel. Consejo Nacional de Investigaciones CientĂficas y TĂ©cnicas. Centro CientĂfico TecnolĂłgico Conicet - CĂłrdoba. Instituto de Investigaciones en FĂsico-quĂmica de CĂłrdoba. Universidad Nacional de CĂłrdoba. Facultad de Ciencias QuĂmicas. Instituto de Investigaciones en FĂsico-quĂmica de CĂłrdoba; ArgentinaFil: Douberly, Gary E.. University of Georgia; Estados Unido
Bubble concentration on spheres for supercritical elliptic problems
We consider the supercritical Lane-Emden problem (P_\eps)\qquad
-\Delta v= |v|^{p_\eps-1} v \ \hbox{in}\ \mathcal{A} ,\quad u=0\ \hbox{on}\
\partial\mathcal{A}
where is an annulus in \rr^{2m}, and
p_\eps={(m+1)+2\over(m+1)-2}-\eps, \eps>0.
We prove the existence of positive and sign changing solutions of (P_\eps)
concentrating and blowing-up, as \eps\to0, on dimensional spheres.
Using a reduction method (see Ruf-Srikanth (2010) J. Eur. Math. Soc. and
Pacella-Srikanth (2012) arXiv:1210.0782)we transform problem (P_\eps) into a
nonhomogeneous problem in an annulus \mathcal D\subset \rr^{m+1} which can be
solved by a Ljapunov-Schmidt finite dimensional reduction
Evidence for a Very Large-Scale Fractal Structure in the Universe from Cobe Measurements
In this work, we analyse the temperature fluctuations of the cosmic microwave
background radiation observed by COBE and show that the distribution can be
fitted by a fractal distribution with a fractal dimension .
This value is in close agreement with the fractal dimension obtained by Coleman
and Pietronero (1992) and Luo and Schramm (1992) from galaxy-galaxy and
cluster-cluster correlations up to . The fact that the
observed temperature fluctuations correspond to scales much larger than and are signatures of the primordial density fluctuations at the
recombination layer suggests that the structure of the matter at the early
universe was already fractal and thus non-homogeneous on those scales. This
result may have important consequences for the theoretical framework that
describes the universe.Comment: 11 pages, postscript file, 2 figures available upon request. To
appear in ApJ Letter
Deflection of ultra high energy cosmic rays by the galactic magnetic field: from the sources to the detector
We report the results of 3D simulations of the trajectories of ultra-high
energy protons and Fe nuclei (with energies and ) propagating through the galactic magnetic field from the
sources to the detector. A uniform distribution of anti-particles is
backtracked from the detector, at the Earth, to the halo of the Galaxy. We
assume an axisymmetric, large scale spiral magnetic field permeating both the
disc and the halo. A normal field component to the galactic plane () is
also included in part of the simulations. We find that the presence of a large
scale galactic magnetic field does not generally affect the arrival directions
of the protons, although the inclusion of a component may cause
significant deflection of the lower energy protons (
eV). Error boxes larger than or equal to are most expected in
this case. On the other hand, in the case of heavy nuclei, the arrival
direction of the particles is strongly dependent on the coordinates of the
particle source. The deflection may be high enough () as to make
extremely difficult any identification of the sources unless the real magnetic
field configuration is accurately determined. Moreover, not every incoming
particle direction is allowed between a given source and the detector. This
generates sky patches which are virtually unobservable from the Earth. In the
particular case of the UHE events of Yakutsk, Fly's Eye, and Akeno, they come
from locations for which the deflection caused by the assumed magnetic field is
not significant.Comment: LaTeX + 2 postscript figures - Color versions of both figures (highly
recommended) available via anonymous ftp at
ftp://capc07.ast.cam.ac.uk/pub/uhecr_gmf as fig*.g
Non-radial sign-changing solutions for the Schroedinger-Poisson problem in the semiclassical limit
We study the existence of nonradial sign-changing solutions to the
Schroedinger-Poisson system in dimension N>=3. We construct nonradial
sign-changing multi-peak solutions whose peaks are displaced in suitable
symmetric configurations and collapse to the same point. The proof is based on
the Lyapunov-Schmidt reduction
Three-dimensional MHD simulations of Radiatively cooling, Pulsed Jets
(Abridged) We here investigate, by means of fully 3-D Smoothed Particle
Magnetohydrodynamic numerical simulations, the effects of magnetic fields on
overdense, radiatively cooling, pulsed jets, using different initial magnetic
field topologies and strengths (G-0). The relative
differences that have been previously detected in 2-D simulations involving
distinct magnetic field configurations are diminished in the 3-D flows. While
the presence of toroidal magnetic components can modify the morphology close to
the jet head inhibiting its fragmentation in the early jet evolution, as
previously reported in the literature, the impact of the pulsed-induced
internal knots causes the appearance of a complex morphology at the jet head
(as required by the observations of H-H jets) even in the MHD jet models with
toroidal components. The detailed structure and emission properties of the
internal working surfaces can be also significantly altered by the presence of
magnetic fields. The increase of the magnetic field strength improves the jet
collimation, and amplifies the density (by factors up to 1.4, and 4) and the
H\alpha\beta \simeq 1-0.1I_{[SII]}}/I_{H}\alpha}\beta \simeq 0.1$ case.Comment: 31 pages, 10 figures (see higher resolution figures in:
http://www.iagusp.usp.br/~dalpino/mhd-jets/apj0301.tar.gz), ApJ in pres
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