7,956 research outputs found
Fluctuations and stability in front propagation
Propagating fronts arising from bistable reaction-diffusion equations are a
purely deterministic effect. Stochastic reaction-diffusion processes also show
front propagation which coincides with the deterministic effect in the limit of
small fluctuations (usually, large populations). However, for larger
fluctuations propagation can be affected. We give an example, based on the
classic spruce-budworm model, where the direction of wave propagation, i.e.,
the relative stability of two phases, can be reversed by fluctuations.Comment: 5 pages, 5 figure
Measurement of the electron electric dipole moment using YbF molecules
The most sensitive measurements of the electron electric dipole moment d_e
have previously been made using heavy atoms. Heavy polar molecules offer a
greater sensitivity to d_e because the interaction energy to be measured is
typically 10^3 times larger than in a heavy atom. We report the first
measurement of this kind, for which we have used the molecule YbF. Together,
the large interaction energy and the strong tensor polarizability of the
molecule make our experiment essentially free of the systematic errors that
currently limit d_e measurements in atoms. Our first result d_e = (- 0.2 \pm
3.2) x 10^-26 e.cm is less sensitive than the best atom measurement, but is
limited only by counting statistics and demonstrates the power of the method.Comment: 4 pages, 4 figures. v2. Minor corrections and clarifications made in
response to referee comment
Catalyst screening and reaction kinetics of liquid phase DME synthesis under reactive distillation conditions
The ideal gas as an urn model: derivation of the entropy formula
The approach of an ideal gas to equilibrium is simulated through a
generalization of the Ehrenfest ball-and-box model. In the present model, the
interior of each box is discretized, {\it i.e.}, balls/particles live in cells
whose occupation can be either multiple or single. Moreover, particles
occasionally undergo random, but elastic, collisions between each other and
against the container walls. I show, both analitically and numerically, that
the number and energy of particles in a given box eventually evolve to an
equilibrium distribution which, depending on cell occupations, is binomial
or hypergeometric in the particle number and beta-like in the energy.
Furthermore, the long-run probability density of particle velocities is
Maxwellian, whereas the Boltzmann entropy exactly reproduces the
ideal-gas entropy. Besides its own interest, this exercise is also relevant for
pedagogical purposes since it provides, although in a simple case, an explicit
probabilistic foundation for the ergodic hypothesis and for the maximum-entropy
principle of thermodynamics. For this reason, its discussion can profitably be
included in a graduate course on statistical mechanics.Comment: 17 pages, 3 figure
Online occupational education in community colleges: Prevalence and contextual factors
This study examined the current state of online occupational programs in community colleges and explored issues related to institutional, economic, and social indicators that influence (a) the offering of online programs and (b) the programmatic connection to workforce development needs. This project is the first national study that categorizes and inventories specific types of online occupational programs in community colleges. The study included a national random sample of 321 institutions in the United States. Data were collected through institutional websites, statewide websites, follow-up emails, and phone inquiries to institutions. The following sections summarize key findings
Temporal and Spatial Aspects of Gas Release During the 2010 Apparition of Comet 103P/Hartley-2
We report measurements of eight primary volatiles (H2O, HCN, CH4, C2H6,
CH3OH, C2H2, H2CO, and NH3) and two product species (OH and NH2) in comet
103P/Hartley-2 using high dispersion infrared spectroscopy. We quantified the
long- and short-term behavior of volatile release over a three-month interval
that encompassed the comet's close approach to Earth, its perihelion passage,
and flyby of the comet by the Deep Impact spacecraft during the EPOXI mission.
We present production rates for individual species, their mixing ratios
relative to water, and their spatial distributions in the coma on multiple
dates. The production rates for water, ethane, HCN, and methanol vary in a
manner consistent with independent measures of nucleus rotation, but mixing
ratios for HCN, C2H6, & CH3OH are independent of rotational phase. Our results
demonstrate that the ensemble average composition of gas released from the
nucleus is well defined, and relatively constant over the three-month interval
(September 18 through December 17). If individual vents vary in composition,
enough diverse vents must be active simultaneously to approximate (in sum) the
bulk composition of the nucleus. The released primary volatiles exhibit diverse
spatial properties which favor the presence of separate polar and apolar ice
phases in the nucleus, establish dust and gas release from icy clumps (and
also, directly from the nucleus), and provide insights into the driver for the
cyanogen (CN) polar jet. The spatial distributions of C2H6 & HCN along the
near-polar jet (UT 19.5 October) and nearly orthogonal to it (UT 22.5 October)
are discussed relative to the origin of CN. The ortho-para ratio (OPR) of water
was 2.85 \pm 0.20; the lower bound (2.65) defines Tspin > 32 K. These values
are consistent with results returned from ISO in 1997.Comment: 18 pages, 3 figures, to be published in: Astrophysical Journal
Letter
Slowing heavy, ground-state molecules using an alternating gradient decelerator
Cold supersonic beams of molecules can be slowed down using a switched
sequence of electrostatic field gradients. The energy to be removed is
proportional to the mass of the molecules. Here we report deceleration of YbF,
which is 7 times heavier than any molecule previously decelerated. We use an
alternating gradient structure to decelerate and focus the molecules in their
ground state. We show that the decelerator exhibits the axial and transverse
stability required to bring these molecules to rest. Our work significantly
extends the range of molecules amenable to this powerful method of cooling and
trapping.Comment: 4 pages, 5 figure
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