128 research outputs found

    Advances in stationary and portable fuel cell applications

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    The reliance on fossil fuels is one of the most challenging problems that need to be dealt with vigorously in recent times. This is because using them is not sustainable and leads to serious environmental issues, such as: air pollution and global warming. This condition affects economic security and development. An alternative to fossil fuel is highly possible which will be more environmentally friendly, sustainable and efficient as well. Among all the different technologies associated with renewable energy, fuel cell technologies represent one of the most promising technological advancement to curb the situation. In this paper, an overview of the technology and its advantages and disadvantages compared with competitive technologies was revealed. The application of different fuel cell types in the stationary and portable sectors was covered. Furthermore, recent challenges and promising developments of current fuel cell technologies in different studied applications were reviewed. Some possible solutions to the challenges were named in this paper for both the portable and stationary fuel cell applications. The paper further seeks to expose the world to the current progress made in the fuel cell industry up to date and possible areas that needs intensified research and modifications to make the fuel cell industry more vibrant and buoyant

    From "best practice" to "best fit": a framework for designing and analyzing pluralistic agricultural advisory services

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    "Agricultural advisory services play an important role in supporting the use of the agricultural sector as an engine of pro-poor growth and enabling small farmers to meet new challenges, such as accessing export markets, adopting environmentally sustainable production techniques, and coping with HIV/AIDS and other health challenges that affect agriculture...There is now renewed interest in agricultural advisory services in many countries.... The questions under debate include: What should be the roles of the public sector, private sector, and civil society? How can we ensure that agricultural advisory services are demand-driven and meet the diverse information needs of farmers? How can advisory services be made efficient and financially sustainable? How can we ensure that female farmers, the poor, and other marginalized groups have access to agricultural advisory services?" from Authors' SummaryAgricultural extension work, Pro-poor growth, Capacity strengthening,

    The effect of particle size on the in vivo degradation of poly(d,l-lactide-co-glycolide)/α-tricalcium phosphate micro- and nanocomposites.

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    UNLABELLED: This paper reports the effect of particle size within a resorbable composite on the in vivo degradation rate and host response. Resorbable composites based on poly(d,l-lactide-co-glycolide) (PLGA) reinforced with tricalcium phosphate (TCP) have shown suitable degradation, biological and mechanical properties for bone repair. Composites with nano-sized TCP particles degrade more homogenously in vitro than equivalent composites with micro-sized particles. In this study, PLGA and PLGA/TCP composites containing micro- or nano-sized α-TCP particles were implanted into an ovine distal femoral condyle defect and harvested at 6, 12, 18 and 24weeks. An intimate interface was observed between the new bone tissue and degrading implants. Visual scoring of histological images and semi-automated segmentation of X-ray images were used to quantify implant degradation and the growth of new bone tissue in the implant site. Bone growth into the implant site occurred at a similar rate for both composites and the PLGA control. However, the in vivo degradation rate of the nanocomposite was slower than that of the microcomposite and consequently more closely matched the rate of bone growth. For the first 6weeks, the rate of in vivo degradation matched that of in vitro degradation, but lagged significantly at longer time points. These results point to the potential use of ceramic particle size in controlling composite degradation whilst maintaining good bone formation. STATEMENT OF SIGNIFICANCE: This paper concerns degradable composites for orthopaedic application. The effect of particle size on implant degradation in vivo is not yet well characterised and these results give the first opportunity to directly compare in vitro and in vivo degradation rates for composites with micro- and nano-sized particles. This type of data is vital for the validation of models of composite degradation behaviour, which will lead to the design and manufacture of composites with a tailored, predictable degradation profile. The trainable segmentation tool can be used for future studies where X-rays of partially degraded implants (which have complicated greyscales and morphologies) need to be quantified without bias.The authors gratefully acknowledge funding from EPSRC grant: DT/E005233/1 (TP/5/REG/6/I/HO106A/DT/E006469/1). S M Bennett is grateful for sponsorship from Lucideon Ltd. and an EPSRC Doctoral Training Account grant. SW is grateful to Ms. Charlotte Fay von Karsa, for funding his Ph.D. studies. XCZ gratefully acknowledges funding from a Royal Society Industrial Fellowship. Dr RA Brooks gratefully acknowledges funding from the National Institute of Health Research.This is the final version of the article. It first appeared from Elsevier at http://dx.doi.org/10.1016/j.actbio.2016.08.046

    A Rasch analysis of the Person-Centred Climate Questionnaire – staff version

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    Background: Person-centred care is the bedrock of modern dementia services, yet the evidence-base to support its implementation is not firmly established. Research is hindered by a need for more robust measurement instruments. The 14-item Person-Centred Climate Questionnaire - Staff version (PCQ-S) is one of the most established scales and has promising measurement properties. However, its construction under classical test theory methods leaves question marks over its rigour and the need for evaluation under more modern testing procedures. Methods: The PCQ-S was self-completed by nurses and other care staff working across nursing homes in 35 Swedish municipalities in 2013/14. A Rasch analysis was undertaken in RUMM2030 using a partial credit model suited to the Likert-type items. Three subscales of the PCQ-S were evaluated against common thresholds for overall fit to the Rasch model; ordering of category thresholds; unidimensionality; local dependency; targeting; and Differential Item Functioning. Three subscales were evaluated separately as unidimensional models and then combined as subtests into a single measure. Due to large number of respondents (n = 4381), two random sub-samples were drawn, with a satisfactory model established in the first ('evaluation') and confirmed in the second ('validation'). Final item locations and a table converting raw scores to Rasch-transformed values were created using the full sample. Results: All three subscales had disordered thresholds for some items, which were resolved by collapsing categories. The three subscales fit the assumptions of the Rasch model after the removal of two items, except for subscale 3, where there was evidence of local dependence between two items. By forming subtests, the 3 subscales were combined into a single Rasch model which had satisfactory fit statistics. The Rasch form of the instrument (PCQ-S-R) had an adequate but modest Person Separation Index (< 0.80) and some evidence of mistargeting due to a low number of `difficult-to-endorse' items. Conclusions: The PCQ-S-R has 12 items and can be used as a unidimensional scale with interval level properties, using the nomogram presented within this paper. The scale is reliable but has some inefficiencies due to too few high-end thresholds inhibiting discrimination amongst populations who already perceive that person-centred care is very good in their environment

    Thermophysical properties of graphene-based nanofluids

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    Heat transfer operations are very common in the process industry to transfer a huge amount of thermal energy, i.e., heat, from one fluid to another for different purposes. Many fluids are used as heat transfer fluid (HTF), in which water is the most common HTF due to its high specific heat, availability, and affordability. However, conventional HTFs, including water, have a lower thermal conductivity, which is the most critical thermophysical property, hence decreased heat transfer efficiency. The addition of solid particles of highly thermally conductive material, specifically at nano-size, i.e., nanoparticles NPs, result in nanofluid NF, which has evolved over the last two decades as efficient HTF and have been investigated in a wide range of applications. Among NPs, graphene (Gr) based materials have shown very high potential as NF due to the very high thermal conductivity up to 5,000 W/m.K, hence higher thermal conductivity NF. This work aims to thoroughly discuss the thermophysical properties of Gr-based NFs, including thermal conductivity, heat capacity, density, and viscosity. The discussion focus on the thermophysical properties as it is the ultimate determinator of the heat transfer characteristics of the HTF, such as the convective and the overall heat transfer coefficient as well as the heat transfer capacity of the NF. The discussion expands to the relative enhancement in such thermophysical properties reaching up to a 40% increase in thermal conductivity, as the most critical thermophysical property. The discussion shows that Gr-based NF has a much higher thermal conductivity relative to widely studied metal oxide NF and at much lower content, and lower density and viscosity increase, which is critical for determining the pumping power requirements. Critical challenges facing the application of Gr-based NFs such as cost, stability, increased density and viscosity, and environmental impacts are thoroughly discussed with mitigation recommendations given

    Prospect of Post-Combustion Carbon Capture Technology and Its Impact on the Circular Economy

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    The sudden increase in the concentration of carbon dioxide (CO2) in the atmosphere due to the high dependency on fossil products has created the need for an urgent solution to mitigate this challenge. Global warming, which is a direct result of excessive CO2 emissions into the atmosphere, is one major issue that the world is trying to curb, especially in the 21st Century where most energy generation mediums operate using fossil products. This investigation considered a number of materials ideal for the capturing of CO2 in the post-combustion process. The application of aqueous ammonia, amine solutions, ionic liquids, and activated carbons is thoroughly discussed. Notable challenges are impeding their advancement, which are clearly expatiated in the report. Some merits and demerits of these technologies are also presented. Future research directions for each of these technologies are also analyzed and explained in detail. Furthermore, the impact of post-combustion CO2 capture on the circular economy is also presented
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