336 research outputs found
The air pressure effect on the homogeneous nucleation of carbon dioxide by molecular simulation
Vapour-liquid equilibria (VLE) and the influence of an inert carrier gas on
homogeneous vapour to liquid nucleation are investigated by molecular
simulation for quaternary mixtures of carbon dioxide, nitrogen, oxygen, and
argon. Canonical ensemble molecular dynamics simulation using the
Yasuoka-Matsumoto method is applied to nucleation in supersaturated vapours
that contain more carbon dioxide than in the saturated state at the dew line.
Established molecular models are employed that are known to accurately
reproduce the VLE of the pure fluids as well as their binary and ternary
mixtures. On the basis of these models, also the quaternary VLE properties of
the bulk fluid are determined with the Grand Equilibrium method.
Simulation results for the carrier gas influence on the nucleation rate are
compared with the classical nucleation theory (CNT) considering the "pressure
effect" [Phys. Rev. Lett. 101: 125703 (2008)]. It is found that the presence of
air as a carrier gas decreases the nucleation rate only slightly and, in
particular, to a significantly lower extent than predicted by CNT. The
nucleation rate of carbon dioxide is generally underestimated by CNT, leading
to a deviation between one and two orders of magnitude for pure carbon dioxide
in the vicinity of the spinodal line and up to three orders of magnitude in
presence of air as a carrier gas. Furthermore, CNT predicts a temperature
dependence of the nucleation rate in the spinodal limit, which cannot be
confirmed by molecular simulation
Intertwining operator for Calogero-Moser-Sutherland system
We consider generalised Calogero-Moser-Sutherland quantum Hamiltonian
associated with a configuration of vectors on the plane which is a union
of and root systems. The Hamiltonian depends on one parameter.
We find an intertwining operator between and the Calogero-Moser-Sutherland
Hamiltonian for the root system . This gives a quantum integral for of
order 6 in an explicit form thus establishing integrability of .Comment: 24 page
Influence of inherited geometry and fault history on the seismogenic activity and potential of strike-slip fault systems in NW Slovenia: the case study of the Ravne Fault
La zona di faglia Ravne è situata in un area di interazione fra due sistemi regionali di faglie con differente cinematica, entrambi collegati alla convergenza fra Adria e Eurasia: le faglie dinariche orientate NW-SE e le faglie del Sud-alpino orientate E-W. L’analisi di dati di geologia strutturale e di due sequenze sismiche recenti che hanno colpito l’area, ci permette di proporre un modello sismotettonico per la faglia di Ravne, che è stata interessata da diverse fasi tettoniche. La geometria originale e la storia evolutiva della zona di faglia svolgono un ruolo cruciale nella distribuzione recente dell’attività sismica e del potenziale sismogenetico dell’intera struttura. Infatti, la configurazione attuale della faglia Ravne, caratterizzata da fagliazione trascorrente su piani ad alto angolo a profondità crostali, è il risultato dell’iniziale geometria di un thrust orientato NW-SE e avente immersione verso NE, e della sua interazione con i piani di thrust diretti essenzialmente E-W. Partendo dai dati raccolti e tenendo in considerazione sia il quadro geodinamico che le relazioni empiriche, proponiamo tre possibili scenari con relativi potenziali sismogenetici per la possibile futura attività della faglia di Ravne
Grand canonical steady-state simulation of nucleation
Grand canonical molecular dynamics (GCMD) is applied to the nucleation
process in a metastable phase near the spinodal, where nucleation occurs almost
instantaneously and is limited to a very short time interval. With a variant of
Maxwell's demon, proposed by McDonald [Am. J. Phys. 31: 31 (1963)], all nuclei
exceeding a specified size are removed. In such a steady-state simulation, the
nucleation process is sampled over an arbitrary timespan and all properties of
the metastable state, including the nucleation rate, can be obtained with an
increased precision.
As an example, a series of GCMD simulations with McDonald's demon is carried
out for homogeneous vapor to liquid nucleation of the truncated-shifted
Lennard-Jones (tsLJ) fluid, covering the entire relevant temperature range. The
results are in agreement with direct non-equilibrium MD simulation in the
canonical ensemble. It is confirmed for supersaturated vapors of the tsLJ fluid
that the classical nucleation theory underpredicts the nucleation rate by two
orders of magnitude
A classification of smooth embeddings of 3-manifolds in 6-space
We work in the smooth category. If there are knotted embeddings S^n\to R^m,
which often happens for 2m<3n+4, then no concrete complete description of
embeddings of n-manifolds into R^m up to isotopy was known, except for disjoint
unions of spheres. Let N be a closed connected orientable 3-manifold. Our main
result is the following description of the set Emb^6(N) of embeddings N\to R^6
up to isotopy.
The Whitney invariant W : Emb^6(N) \to H_1(N;Z) is surjective. For each u \in
H_1(N;Z) the Kreck invariant \eta_u : W^{-1}u \to Z_{d(u)} is bijective, where
d(u) is the divisibility of the projection of u to the free part of H_1(N;Z).
The group Emb^6(S^3) is isomorphic to Z (Haefliger). This group acts on
Emb^6(N) by embedded connected sum. It was proved that the orbit space of this
action maps under W bijectively to H_1(N;Z) (by Vrabec and Haefliger's
smoothing theory). The new part of our classification result is determination
of the orbits of the action. E. g. for N=RP^3 the action is free, while for
N=S^1\times S^2 we construct explicitly an embedding f : N \to R^6 such that
for each knot l:S^3\to R^6 the embedding f#l is isotopic to f.
Our proof uses new approaches involving the Kreck modified surgery theory or
the Boechat-Haefliger formula for smoothing obstruction.Comment: 32 pages, a link to http://www.springerlink.com added, to appear in
Math. Zei
Phase diversity restoration of sunspot images I. Relations between penumbral and photospheric features
We investigate the dynamics of and the relations between small-scale
penumbral and photospheric features near the outer penumbral boundary:
penumbral grains (PGs), dark penumbral fibrils, granules, and photospheric
G-band bright points. The analysis is based on a 2 h time sequence of a sunspot
close to disc center, taken simultaneously in the G-band and in the blue
continuum at 450.7 nm. Observations were performed at the Swedish Vacuum Solar
Telescope (La Palma) in July 1999. A total of 2564 images (46 arcsec x 75
arcsec) were corrected for telescope aberrations and turbulence perturbations
by applying the inversion method of phase diversity. Our findings can by
summarized as follows: (a) One third of the outward-moving PGs pass through the
outer penumbral boundary and then either continue moving as small bright
features or expand and develop into granules. (b) Former PGs and G-band bright
points next to the spot reveal a different nature. The latter have not been
identified as a continuation of PGs escaping from the penumbra. The G-band
bright points are mostly born close to dark penumbral fibrils where the
magnetic field is strong, whereas PGs stem from the less-magnetized penumbral
component and evolve presumably to non-magnetic granules or small bright
features.Comment: Accepted by A&A, 9 pages and 5 figure
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