Complexion-mediated martensitic phase transformation in Titanium

The most efficient way to tune microstructures and mechanical properties of metallic alloys lies in designing and using athermal phase transformations. Examples are shape memory alloys and high strength steels, which together stand for 1,500 million tons annual production. In these materials, martensite formation and mechanical twinning are tuned via composition adjustment for realizing complex microstructures and beneficial mechanical properties. Here we report a new phase transformation that has the potential to widen the application window of Ti alloys, the most important structural material in aerospace design, by nanostructuring them via complexion-mediated transformation. This is a reversible martensitic transformation mechanism that leads to a final nanolaminate structure of α″ (orthorhombic) martensite bounded with planar complexions of athermal ω (a–ω, hexagonal). Both phases are crystallographically related to the parent β (BCC) matrix. As expected from a planar complexion, the a–ω is stable only at the hetero-interface

Comparación de isómeros geométricos de ácidos grasos insaturados en aceites refinados comerciales seleccionados

Four different commercially refined vegetable oils were analyzed by capillary gas-liquid chromatography for their trans fatty acid contents. The results obtained showed that the total trans FA contents in refined sunflower, corn, soybean, and hazelnut oils were 0.68 ± 0.41, 0.51 ± 0.24, 1.27 ± 0.57, and 0.26 ± 0.07% of total FA, respectively. The total trans FA comprised isomers of the C18:1, C18:2 and C18:3 FA. Meanwhile, five brands of the refined sunflower oil and two brands of hazelnut oil contained no measurable amounts of total trans C18:3 acids. The total trans C18:2 acid was the predominant trans FA found in the refined sunflower and corn oils, while trans polyunsaturated FAs for the refined soybean oils were found at high levels. However, total trans C18:1 acid was the major trans FA for refined hazelnut oils. The commercially refined vegetable oils with a relatively high total polyunsaturated FA contained considerable amounts of trans polyunsaturated isomers. This study indicates that it is necessary to optimize industrial deodorization, especially the time and temperature, for each different FA composition of oil used.Cuatro aceites vegetales refinados comerciales diferentes fueron analizados por cromatografía de gases para determinar el contenido en ácidos grasos trans. Los resultados obtenidos mostraron que el contenido total de los FA trans de aceites refinados de girasol, maíz, soja y avellana fueron 0.68 ± 0.41, 0.51 ± 0.24, 1.27 ± 0.57, y 0.26 ± 0.07% de FA totales, respetivamente. Los ácidos grasos totales trans comprenden a isómeros de FA C18:1, C18:2 y C18:3. Cinco marcas de aceites de girasol refinado y dos marcas de aceite de avellana contenían cantidades no medibles de ácidos trans C18:3 totales. Los ácidos C18:2 trans totales fueron los FA trans predominantes en el aceite de girasol y maíz refinado, mientras los FA poliinsaturados trans fueron encontrados a niveles altos en el aceite de soja refinado. Sin embargo, los ácidos trans C18:1 totales fueron los principales FA trans en el aceite de avellana refinado. Los aceites vegetales refinados comerciales con un contenido relativamente alto de FA poliinsaturado total contenían cantidades considerable de isómeros poliinsaturados trans. Este estudio indica que es necesario optimizar la industria de desodorización, especialmente el tiempo y la temperatura, para cada composición diferente de FA del aceite usado

Governing urban diversity: Multi-scalar representations, local contexts, dissonant narratives

In recent academic and urban policy writings the term urban diversity is usually understood, or discussed within the context of, increasing ‘socio-cultural’ diversity in cities or is explicitly connected to debates over immigration and demographic change. Although policy agendas follow certain common trends ‘to deal with’ the consequences of diversity, there is a lack of evidence-based research on how representations of diversity are mobilised and implemented by institutions of governance operating at multiple scales and how these narratives relate to each other. Policy-makers are faced with new dilemmas over how to govern and manage cities that are becoming increasingly diverse, on the one hand, and increasingly ‘sensitive’ to certain channels of flows of people (such as refugees), on the other. In some cases, city authorities promote the idea of inclusive diversity as a mark of modernisation and tolerance. In others, its recognition may be seen as a threat to an imagined social order and is perceived to be fuelling neo-assimilationist policies in many European Union cities. This special issue aims to fill this gap by providing evidence-based research outcomes that tackle different dimensions of the governance of diversity in cities. The principal aim of the research project, named DIVERCITIES, that underpins this collection was to critically assess evidence concerning the range of socio-economic outcomes that may emerge from the presence of greater urban diversity. DIVERCITIES has shown that city policy agendas across Europe are often more ‘positive’ towards diversity than national policies and media reports. Moreover, local policy initiatives, mostly formed at the bottom-up scale, sometimes as a cooperation between state and civic actors and sometimes as purely private or even individual arrangements, address the actual needs of certain population groups by acting as bridge-builders between public authorities and target groups. This collection aims to provide a clear understanding of how diversity is understood, operationalised and dealt with at different scales of policy-making. In focusing on European examples, it provides an important addition to a literature that has become Anglo-American focused, both in terms of the concepts and policy interventions

Complexion-mediated martensitic phase transformation in Titanium

The most efficient way to tune microstructures and mechanical properties of metallic alloys lies in designing and using athermal phase transformations. Examples are shape memory alloys and high strength steels, which together stand for 1,500 million tons annual production. In these materials, martensite formation and mechanical twinning are tuned via composition adjustment for realizing complex microstructures and beneficial mechanical properties. Here we report a new phase transformation that has the potential to widen the application window of Ti alloys, the most important structural material in aerospace design, by nanostructuring them via complexion-mediated transformation. This is a reversible martensitic transformation mechanism that leads to a final nanolaminate structure of α″ (orthorhombic) martensite bounded with planar complexions of athermal ω (a–ω, hexagonal). Both phases are crystallographically related to the parent β (BCC) matrix. As expected from a planar complexion, the a–ω is stable only at the hetero-interface.European Commission. Framework Programme for Research and Innovation (FP7/2007–2013))/ERC Grant agreement 290998 'SmartMet’)Innovative Research Team in University (IRT13034)National Basic Research Program of China (973 Program) (2014CB644003)China. Ministry of Science and Technology. National Key Research and Development Program (2016YFB0701302)National Natural Science Foundation of China (51501145)National Natural Science Foundation of China (51320105014)National Natural Science Foundation of China (51621063

Integrated experimental and simulation analysis of stress and strain partitioning in dual phase steel

The mechanical behavior of multiphase steels is governed by the microscopic strain and stress partitioning behavior among microstructural constituents [1-3]. However, due to limitations in the characterization of the partitioning that takes place at the submicron scale, microstructure optimization of such alloys is typically based on evaluating the averaged response, referring to, for example, macroscopic stress–strain curves. Here, a coupled experimental–numerical methodology is presented and discussed to strengthen the integrated understanding of the microstructure and mechanical properties of complex alloys, enabling joint analyses of deformation-induced evolution of the microstructure, and the strain and stress distribution therein, down to submicron resolution. From the experiments, deformation-induced evolution of (i) the microstructure, and (ii) the local strain distribution are concurrently captured, employing in situ secondary electron imaging and electron backscatter diffraction (EBSD) (for the former), and microscopic-digital image correlation (for the latter) [3,4]. From the simulations, local strain as well as stress distributions are revealed, through full-field crystal plasticity (CP) simulations conducted with the advanced DAMASK spectral solver suitable for heterogeneous materials [5,6]. The simulated model is designed directly from the initial EBSD measurements, and the phase properties are obtained by additional inverse CP simulations of nanoindentation experiments carried out on the original microstructure. The experiments and simulations demonstrate good correlation in the proof-of-principle study conducted here on a martensite–ferrite dual-phase steel, and deviations are discussed in terms of opportunities and limitations of the techniques involved. C.C. Tasan et al. Strain localization and damage in dual phase steels investigated by coupled in-situ deformation experiments and crystal plasticity simulations, International Journal of Plasticity,63,198-210,2014 C.C. Tasan et al. An overview of dual-phase steels: advances in microstructure-oriented processing and micromechanically guided design, Annual Review of Materials Research,45,391-431,2015 D. Yan et al. High resolution in situ mapping of microstrain and microstructure evolution reveals damage resistance criteria in dual phase steels,Acta Materialia,96,399-409,2015 C.C. Tasan et al. Integrated experimental–simulation analysis of stress and strain partitioning in multiphase alloys,Acta Materialia,81,,386-400,2014 F. Roters, et al. 2012, DAMASK: The Düsseldorf Advanced Material Simulation Kit for studying crystal plasticity using an FE based or a spectral numerical solver, in Procedia IUTAM, Vol. III, pp. 3–10, Elsevier, Amsterdam. https://damask.mpie.d

Retardation of plastic instability via damage-enabled microstrain delocalization

Multi-phase microstructures with high mechanical contrast phases are prone to microscopic damage mechanisms. For ferrite-martensite dual-phase steel, for example, damage mechanisms such as martensite cracking or martensite-ferrite decohesion are activated with deformation, and discussed often in literature in relation to their detrimental role in triggering early failure in specific dual-phase steel grades. However, both the micromechanical processes involved and their direct influence on the macroscopic behavior are quite complex, and a deeper understanding thereof requires systematic analyses. To this end, an experimental-theoretical approach is employed here, focusing on three model dual-phase steel microstructures each deformed in three different strain paths. The micromechanical role of the observed damage mechanisms is investigated in detail by in-situ scanning electron microscopy tests, quantitative damage analyses, and finite element simulations. The comparative analysis reveals the unforeseen conclusion that damage nucleation may have a beneficial mechanical effect in ideally designed dual-phase steel microstructures (with effective crack-arrest mechanisms) through microscopic strain delocalization

Replication timing maintains the global epigenetic state in human cells

ACKNOWLEDGMENTS We thank R. Didier and B. Alexander of the FSU Flow Cytometry and Confocal Microscopy Facilities for their help with flow cytometry and fluorescence-activated cell sorting for this project. Thanks to A. Brown of the FSU Biological Science Core Labs and to Y. Yang and C. Vied of the FSU Translational Labs. Thanks to S. R. Westermann of SCIGRAPHIX for generating the model figure. Thanks to B. van Steensel, J. Phillips-Cremins, and P. Fraser for critical reading of the manuscript. Funding: This work was supported by NIH grant GM083337 to D.M.G., GM035463 to V.G.C., and GM085354 to D.M.G., S.D., and V.G.C. D.L. is supported by the Hong Kong Research Grant Council (ECS 26104216). T.B. is supported by the William C. and Joyce C. O’Neil Charitable Trust, Memorial Sloan Kettering Single Cell Sequencing InitiativePeer reviewedPostprin