Compositional data analysis as a potential tool to study the (paleo)ecology of calcareous nannoplankton from the central portuguese submarine canyons (W off Portugal)

Submarine canyons are deep and steep incisions on the continental margins. The physical forcing mechanisms linked with these marine systems, such as the enhancement of upwelling and bottom sediment resuspension, are expected to provide a nutrient source that will increase phytoplankton density (Hickey, 1995, Kampf,2006). Coccolithophores are the predominant phytoplanktonic group within the calcareous nannoplankton and their sensitivity to a variety of surface water environmental parameters makes them important markers of oceanographic processes and proxies of sea surface water masses and temperatures, productivity and past climate changes (e.g. Ziveri et al., 2004; Silva et al., 2008). In the present work we propose to test compositional analysis (Buccianti & Esposito, 2004; Pawlowsky-Glahn & Egozcue, 2006) as a tool to: a) achieve a clearer distinction between opportunistic coastal-neritic species (r-strategists) and typical oceanic species (k-strategists) in the central Portuguese margin, and b) to identify a coccolith assemblage that might reflect favorable environmental conditions found in the vicinity of the canyon that promotes the productivity of calcareous nannoplankton. Our main difficulty will be in distinguishing the ecological signal from the effects of other environmental factors mentioned before (i.e. advection, dissolution, bottom resuspension). One way to infer the species’ ecological inter-relationships is by determining species relative percentages. The main concern is how the closure problem and the inconsistency of percentage determinations will affect our results. Compositional analysis was designed to provide more reliable and thus representative results, since the inference made on the coccolith assemblage features from which the data are drawn is correctly performed from a theoretical point of view (Buccianti & Esposito, 2004). Here, we present the first insights from applying compositional data analysis to coccolith assemblages from 85 surface sediment samples collected from the central Portuguese margin

Effects of external nutrient sources and extreme weather events on the nutrient budget of a Southern European coastal lagoon

The seasonal and annual nitrogen (N), phosphorus (P), and carbon (C) budgets of the mesotidal Ria Formosa lagoon, southern Portugal, were estimated to reveal the main inputs and outputs, the seasonal patterns, and how they may influence the ecological functioning of the system. The effects of extreme weather events such as long-lasting strong winds causing upwelling and strong rainfall were assessed. External nutrient inputs were quantified; ocean exchange was assessed in 24-h sampling campaigns, and final calculations were made using a hydrodynamic model of the lagoon. Rain and stream inputs were the main freshwater sources to the lagoon. However, wastewater treatment plant and groundwater discharges dominated nutrient input, together accounting for 98, 96, and 88 % of total C, N, and P input, respectively. Organic matter and nutrients were continuously exported to the ocean. This pattern was reversed following extreme events, such as strong winds in early summer that caused upwelling and after a period of heavy rainfall in late autumn. A principal component analysis (PCA) revealed that ammonium and organic N and C exchange were positively associated with temperature as opposed to pH and nitrate. These variables reflected mostly the benthic lagoon metabolism, whereas particulate P exchange was correlated to Chl a, indicating that this was more related to phytoplankton dynamics. The increase of stochastic events, as expected in climate change scenarios, may have strong effects on the ecological functioning of coastal lagoons, altering the C and nutrient budgets.Portuguese Science and Technology Foundation (FCT) [POCI/MAR/58427/2004, PPCDT/MAR/58427/2004]; Portuguese Science and Technology Foundation (FCT

Influence of diagenetic processes and terrestrial/anthropogenic sources in the REE contents of the Cascais submarine canyon (Iberian western coast)

ABSTRACT: Temporal variations of rare earth elements (REE) and their fractionation patterns, major elements, Pb and Hg were determined in two multicores collected at 445 and 2100 m water depth (mwd) in the Cascais submarine canyon (CSC). The PAAS-normalized REE patterns suggest mixing of Tagus estuarine and marine sediments, marked by MREE (Nd‐Dy series) enrichment and by positive Eu-anomaly, with marine sediments. The positive Eu/Eu* implies incorporation of detrital feldspar minerals derived from the estuary. Ce/Ce*, (La/Yb)PAAS and (Nd/Yb)PAAS show differences between the two cores. Core 252-35 from the shallower site is enriched in HREE (Ho‐Lu series) over LREE (La‐Pr series), a pattern also found in the Tagus estuary in the vicinity of an abandoned chemical complex, where the environment is affected by the legacy of massive-sulfide ores processing. There seems to be only limited down-canyon sediment transport to the deeper reaches where core 252-32 was collected. This deeper site shows Ce/Ce* peaks coinciding with low (La/Yb)PAAS values suggesting preferential diagenetic remobilization of LREE relative to HREE. Upcore Pb/Al and Hg/Corg trends observed in both cores indicate dispersion of the anthropogenic component from the estuary through the CSC, which is less obvious from the ∑REE/Al trends particularly in the deeper site. This may suggest the influence of diagenetic processes in the REE signal, associated with relatively low sediment accumulation rates.info:eu-repo/semantics/publishedVersio

Submarine Cascais Canyon as a sediment conduit to the deep sea : comparison with adjacent slopes

Submarine canyons are known to be important conduits that trap, accumulate and deliver both natural and anthropogenic sediments from the shelf to the deep sea. Ten multi-cores from the Cascais Canyon and from the neighbour slopes (off Estremadura and Sines) were dated by 21Opb methodologies and analyzed for texture, major and trace metals to evaluate the role of submarine canyons in the transport of anthropogenic metals to the abyssal plains. Higher accumulation mass rates were determined in the upper Cascais Canyon than in the lower canyon and slopes. Enrichment factors (EF) were used to evaluate the level of metal enrichment in the studied areas. EF values exceeding natural background concentrations were obtained for Pb suggesting an anthropogenic and/or diagenetic source for Pb enrichment in the Cascais Canyon, but also, to a lesser extent, in the Estremadura and Sines slopes. Studies of provenance based on the ratio of different stable Pb isotopes can help to determinethe origin of such metal in the sediments

Practical identifiability analysis of environmental models

Identifiability of a system model can be considered as the extent to which one can capture its parameter values from observational data and other prior knowledge of the system. Identifiability must be considered in context so that the objectives of the modelling must also be taken into account in its interpretation. A model may be identifiable for certain objective functions but not others; its identifiability may depend not just on the model structure but also on the level and type of noise, and may even not be identifiable when there is no noise on the observational data. Context also means that non-identifiability might not matter in some contexts, such as when representing pluralistic values among stakeholders, and may be very important in others, such as where it leads to intolerable uncertainties in model predictions. Uncertainty quantification of environmental systems is receiving increasing attention especially through the development of sophisticated methods, often statistically-based. This is partly driven by the desire of society and its decision makers to make more informed judgments as to how systems are better managed and associated resources efficiently allocated. Less attention seems to be given by modellers to understand the imperfections in their models and their implications. Practical methods of identifiability analysis can assist greatly here to assess if there is an identifiability problem so that one can proceed to decide if it matters, and if so how to go about modifying the model (transforming parameters, selecting specific data periods, changing model structure, using a more sophisticated objective function). A suite of relevant methods is available and the major useful ones are discussed here including sensitivity analysis, response surface methods, model emulation and the quantification of uncertainty. The paper also addresses various perspectives and concepts that warrant further development and use

Counterion adsorption on flexible polyelectrolytes: comparison of theories

Counterion adsorption on a flexible polyelectrolyte chain in a spherical cavity is considered by taking a "permuted" charge distribution on the chain so that the "adsorbed" counterions are allowed to move along the backbone. We compute the degree of ionization by using self-consistent field theory (SCFT) and compare with the previously developed variational theory. Analysis of various contributions to the free energy in both theories reveals that the equilibrium degree of ionization is attained mainly as an interplay of the adsorption energy of counterions on the backbone, the translational entropy of the small ions, and their correlated density fluctuations. Degree of ionization computed from SCFT is significantly lower than that from the variational formalism. The difference is entirely due to the density fluctuations of the small ions in the system, which are accounted for in the variational procedure. When these fluctuations are deliberately suppressed in the truncated variational procedure, there emerges a remarkable quantitative agreement in the various contributing factors to the equilibrium degree of ionization, in spite of the fundamental differences in the approximations and computational procedures used in these two schemes. Nevertheless, since the significant effects from density fluctuations of small ions are not captured by the SCFT, and due to the close agreement between SCFT and the other contributing factors in the more transparent variational procedure, the latter is a better computational tool for obtaining the degree of ionization

Alterações recentes nas razões isotópicas de Pb em sedimentos do Canhão Submarino de Cascais, Portugal

Temporal variations in lead concentrations and stable lead isotopic ratios in two sediment cores from the Cascais Canyon shows changes in sources of Pb during the last two centuries. The increase of total Pb contents wIth the evolution of Pb ratio recorded in both cores reveals the Increase of Pb from industrial sources. Nevertheless, this increase is lower in deeper core location (252-32) due to dilution and mixing with uncontaminated marine materials. An isotopic shift towards lower Pb/Pb in the shallower core (252-35) during the 1970s may reflect the increasing number of vehicles in the Lisboa area during that time

Демографічні фактори розвитку соціального капіталу

У статті проаналізовано тенденції змін основних демографічних показників в Україні й Донецькому регіоні зокрема, показано вплив цих факторів на розвиток соціального капіталу. Акцентовано, що дослідження демографічних факторів формування соціального капіталу на державному і регіональному рівнях дозволяє відповідним державним органам управління отримувати повну інформацію стосовно будь-яких змін демографічного розвитку та вживати заходів з оптимізації параметрів трудового та інтелектуального потенціалу населення.In the article the tendencies of changes of basic demographic indicators are analysed in Ukraine and Donetsk region in particular, influence of these factors is rotined on development of social capital. It is accented, that research of demographic factors of forming of social capital on state and regional levels allows the proper public organs of management to get complete information on any changes of demographic development and take measures from optimization of parameters of labour and intellectual potential of population

Cluster temporal de metales en un testigo corto de sedimento del Cañón Submarino de Cascais (Margen de Portugal)

The Cascais Canyon delivers contaminated sediments from the shelf to the deep marine environment. Multi-core PE252-32, located at 2100 m water depth in the canyon, records the latest 300 years of sedimentation. It was dated by 210Pb and analyzed texturally and geochemically for major elements and selected trace metals (Cu, Cr, Hg, Li, Ni, Pb and Zn). Cluster analysis performed on the down-core geochemical data identified four groups of variables related by grain-size, geochemical source and composition. Mercury, Pb and Zn were grouped in a cluster representing the anthropogenic component. Cluster analysis was applied again particularly to the latter cluster relatively to depth, in order to constrain the onset and temporal evolution of anthropogenic contamination. A second clustering, made on the basis of Hg, Pb and Zn, grouped samples by age and degree of anthropogenic contamination. One cluster contained relatively uncontaminated samples older than 1900 AD, and another cluster samples younger than 1900 AD with distinct metal enrichment. Maximum enrichments occurred during the early 1980s, followed by a slight recovery from the mid-1980s to the present. Mercury was the element with the highest enrichment factor (EFHg=5). Despite relatively low accumulation rates at this core location, our results show the importance of the Cascais Canyon as a transport route for contaminated sediments from the Tagus prodelta into the deep regions of the Portuguese Margin.El Cañón submarino de Cascais distribuye sedimentos contaminados de la plataforma continental al medio marino profundo. El testigo PE252-32, situado a 2100 metros de profundidad dentro del cañón, registra los últimos 300 años de su sedimentación. Se ha datado con 210Pb y ha sido analizada su granulometría, elementos mayoritarios y traza (cobre, cromo, mercurio, litio, níquel, plomo y zinc). Se ha llevado a cabo un análisis estadístico clúster, inicialmente aplicado a las series de datos geoquímicos en función de la profundidad, identificándose 4 grupos de variables, relacionados por la granulometría, procedencia y composición geoquímica. Los metales mercurio, plomo y zinc aparecen agrupados en un clúster que representa la componente antropogénica. A continuación el mismo análisis estadístico se aplicó específicamente a este grupo, en función de la profundidad, organizando las muestras según la edad de contaminación antropogénica. Como resultado las muestras quedan agrupadas en dos clústers principales, el de las muestras no contaminadas y más antiguas de 1900 AC, y el de las muestras más recientes de 1900 AC, marcando esta fecha el inicio de la contaminación por impacto de la actividad humana. Los máximos enriquecimientos ocurren durante el inicio de la década de los años ochenta, seguidos de un ligero descenso a partir de mediados de la misma década hasta la actualidad. De entre los demás, el mercurio es el elemento con el mayor grado de enriquecimiento (EFHg=5). Aunque la tasa de acumulación de sedimentos en este lugar es relativamente baja, los resultados obtenidos ponen en evidencia la importancia del Cañón submarino de Cascais como vía de transporte de sedimentos contaminados depositados en el pro-delta del Tajo a las regiones profundas del margen de Portugal