Bidentate N,O-prolinate ruthenium benzylidene catalyst highly active in RCM of disubstituted dienes

The synthesis of a bidentate N,O-prolinate ruthenium benzylidene from commercially available starting materials and its activity in ring-closing metathesis of functionalized disubstituted dienes at 30 °C is disclosed

A Salt Metathesis Route To Ruthenium Carbene Complex Isomers With Pyridine Dicarboxamide-Derived Chelate Pincer Ligands

Reaction of the doubly deprotonated pyridine 2,6-dicarboxamido ligand (1) with (PCy_3)_2Cl_2 Ru=CHPh (3a) in THF gave a mixture of (lig)(PCy_3)Ru=CHPh isomers (4). The pentane soluble N,N,O-4 isomer was isolated by extraction and characterized by X-ray diffraction. The O,N, O-4 isomer was identified in the residue. Single crystals of the closely related complex (lig)(NHC) Ru=CHPh, O,N,O-5, were obtained from the reaction of 1 with (NHC)(PCy_3)Cl_2Ru=CHPh (3b) and used for the X-ray crystal structure analysis of the system

Engineering design of the EURISOL multi-MW spallation target

The European Isotope Separation On-Line Radioactive Ion Beam project (EURISOL) is set to design the 'next-generation' European Isotope Separation On-Line (ISOL) Radioactive Ion Beam (RIB) facility. It will extend and amplify current research on nuclear physics, nuclear astrophysics and fundamental interactions beyond the year 2010. In EURISOL, four target stations are foreseen, three direct targets of approximately 100 kW of beam power and one multi-MW target assembly, all driven by a high-power particle accelerator. In this high power target station, high-intensity RIBs of neutron-rich isotopes will be obtained by inducing fission in several actinide targets surrounding a liquid metal spallation neutron source. This article summarises the work carried out within Task 2 of the EURISOL Design Study, with special attention to the coupled neutronics of the mercury proton-to-neutron converter and the fission targets. The overall performance of the facility, which will sustain fast neutron fluxes of the order of 1014 n/cm2/s, is evaluated, together with the production of radionuclides in the actinide targets, showing that the targeted 1015 fissions/s can be achieved. Some of the greatest challenges in the design of high power spallation sources are the high power densities, entailing large structural stresses, and the heat removal, requiring detailed thermo-hydraulic calculations. The use of a thin martensitic steel beam-window and a well-controlled mercury flow has been shown to reduce the von-Misses stress in the former below the 200 MPa limit, with reasonable maximum flow rates of ~6 m/s. Alternatively, a windowless target configuration has been proposed, based on a liquid mercury transverse film. With this design, higher power densities and fission rates may be achieved, avoiding the technical difficulties related to the beam window. Experimentally, several tests have been performed at IPUL (Riga, Latvia) in order to study the stability of the liquid metal flow and validate the mercury loop design

Localization of 102 exons to a 2.5 Mb region involved in Down syndrome

Exon amplification has been applied to a 2.5 Mb region of chromosome 21 that has been associated with some features of Down syndrome (DS). Identification of the majority of genes from this region will facilitate the correlation of the over-expression of particular genes with specific phenotypes of DS. Over 100 gene fragments have been isolated from this 2.5 Mb segment. The exons have been characterized by sequence analysis, comparison with public databases and expansion to cDNA clones. Localization of the exons to chromosome 21 has been determined by hybridization to genomic Southern blots and to YAC and cosmid clones representing the region. This has resulted in a higher resolution physical map with a marker approximately every 25 kb. This integrated physical and transcript map will be valuable for fine mapping of DNA from individuals with partial aneuploidy of chromosome 21 as well as for assessing and ultimately generating a complete gene map of this segment of the genom

Period changes in six contact binaries: WZ And, V803 Aql, DF Hya, PY Lyr, FZ Ori, and AH Tau

Six contact binaries lacking a period analysis have been chosen to search for the presence of a third body. The O-C diagrams of these binaries were analyzed with the least-squares method by using all available times of minima. Ten new minima times, obtained from our observations, were included in the present research. The Light-Time Effect was adopted for the first time as the main cause for the detailed description of the long-term period changes. Third bodies were found with orbital periods from 49 up to 100 years, and eccentricities from 0.0 to 0.56 for the selected binaries. In one case (WZ And), a fourth-body LITE variation was also applied. The mass functions and the minimal masses of such bodies were also calculated and a possible angular separation and magnitude differences were discussed for a prospective interferometric discovery of these bodies.Comment: 7 pages, 8 figures, 2009 New Astronomy 14, 12

Network models of soil porous structure

Soils sustain life on Earth. In times of increasing anthropogenic demands on soils [1] there is growing need to seek for novel approaches to understand the relationships between the soil porous structure and specific soil functions. Recently [2-4], soil pore structure was described as a complex network of pores using spatially embedded varying fitness network model [2] or heterogeneous preferential attachment scheme [3-4], both approaches revealing the apparent scale-free topology of soils. Here, we show, using a large set of soil images of structures obtained by X-ray computed tomography that both methods predict topological similar networks of soil pore structures. Furthermore, by analyzing the node-node link correlation properties of the obtained networks we suggest an approach to quantify the complexity of soil pore structur

Pseudo-single crystal electrochemistry on polycrystalline electrodes : visualizing activity at grains and grain boundaries on platinum for the Fe2+/Fe3+ redox reaction

The influence of electrode surface structure on electrochemical reaction rates and mechanisms is a major theme in electrochemical research, especially as electrodes with inherent structural heterogeneities are used ubiquitously. Yet, probing local electrochemistry and surface structure at complex surfaces is challenging. In this paper, high spatial resolution scanning electrochemical cell microscopy (SECCM) complemented with electron backscatter diffraction (EBSD) is demonstrated as a means of performing ‘pseudo-single-crystal’ electrochemical measurements at individual grains of a polycrystalline platinum electrode, while also allowing grain boundaries to be probed. Using the Fe2+/3+ couple as an illustrative case, a strong correlation is found between local surface structure and electrochemical activity. Variations in electrochemical activity for individual high index grains, visualized in a weakly adsorbing perchlorate medium, show that there is higher activity on grains with a significant (101) orientation contribution, compared to those with (001) and (111) contribution, consistent with findings on single-crystal electrodes. Interestingly, for Fe2+ oxidation in a sulfate medium a different pattern of activity emerges. Here, SECCM reveals only minor variations in activity between individual grains, again consistent with single-crystal studies, with a greatly enhanced activity at grain boundaries. This suggests that these sites may contribute significantly to the overall electrochemical behavior measured on the macroscale

Consequential life cycle assessment of kraft lignin recovery with chemical recycling

: The recovery of kraft lignin from black liquor allows an increasing of the pulp production of a kraft mill (marginal tonnage) and at the same time provide a valuable material that can be used as energy or chemical feedstock. However, because lignin precipitation is an energy- and material-consuming process, the environmental consequences from a life cycle perspective are under discourse. The aim of this study is to investigate, through the application of consequential life cycle assessment, the potential environmental benefits of kraft lignin recovery and its subsequent use as an energy or chemical feedstock. A newly developed chemical recovery strategy was assessed. The results revealed how the use of lignin as energy feedstock is not environmentally advantageous compared to producing energy directly from the pulp mill's recovery boiler. However, the best results were observed when lignin was used as a chemical feedstock in four applications to replace bitumen, carbon black, phenol, and bisphenol-A