Optical probe of carrier doping by X-ray irradiation in organic dimer Mott insulator κ\kappa-(BEDT-TTF)2_{2}Cu[N(CN)2]_{2}]Cl

We investigated the infrared optical spectra of an organic dimer Mott insulator $\kappa$-(BEDT-TTF)$_{2}$Cu[N(CN)$_{2}$]Cl, which was irradiated with X-rays. We observed that the irradiation caused a large spectral weight transfer from the mid-infrared region, where interband transitions in the dimer and Mott-Hubbard bands take place, to a Drude part in a low-energy region; this caused the Mott gap to collapse. The increase of the Drude part indicates a carrier doping into the Mott insulator due to irradiation defects. The strong redistribution of the spectral weight demonstrates that the organic Mott insulator is very close to the phase border of the bandwidth-controlled Mott transition.Comment: 4 pages, 4 figure

Cross-correlation between the 21-cm signal and [OIII] emitters during early cosmic reionization

We study statistics of the 21-cm signal from the epoch of reionization. We propose to use [OIII] line emitting galaxies to cross-correlate with the 21-cm signal from $z = 7 - 10$. To this aim, we employ simulations of reionization obtained post-processing the high-resolution cosmological hydrodynamic simulation Massive Black-II with the three-dimensional (3D) radiative transfer code CRASH to follow the propagation of ionizing photons from a variety of sources. We show that, during the early phases of reionization, the 21-cm signal is positively correlated with the spatial distribution of the [OIII] emitters on large scales $(k < 1h~\rm cMpc^{-1})$. This positive correlation is generated by the temperature-galaxy correlation and it is a few times larger than when we assume that the heating is saturated. As the reionized regions expand, the correlation changes its sign to negative from $z = 10$ to 8. The signals at this epoch can be detected by combining the Square Kilometre Array (SKA) and a wide-field [OIII] emitter survey. We also calculate the cross-power spectrum with a 3D [OIII] intensity field, aiming at exploiting future intensity mapping observations. We conclude that high-redshift [OIII] line emitters can be used to probe the reionization process when the intergalactic medium is largely neutral.Comment: 7 pages, 5 figures, published in MNRA

Electrospray ionization mass spectrometric observation of ligand exchange of zinc pyrithione with amino acids

ArticleRAPID COMMUNICATIONS IN MASS SPECTROMETRY. 23(14):2161-2166 (2009)journal articl

Raman tensor analysis of hexagonal polyoxymethylene and its application to study the molecular arrangement in highly crystalline electrospun nanofibers

The orientation dependence in space of Raman-active vibrations in the hexagonal structure of polyoxymethylene (POM) is discussed in terms of Raman tensor elements as intrinsic physical parameters of the lattice. The variation of polarized intensity for the A1 and the E1 vibrational modes with respect to the POM molecular orientation is systematically studied, from both theoretical and experimental viewpoints, according to the symmetry assignments of each vibrational mode. A set of working equations including the Raman selection rules associated with the A1 and the E1 modes and the orientation distribution function are explicitly formulated and validated by means of a least-square fitting procedure on experimental data. In addition, an approach based on the introduction of orientation distribution functions is applied to quantitatively assess and compare on a statistical base the molecular orientation of two different types of electrospun POM nanofibers. Copyright (c) 2012 John Wiley &amp; Sons, Ltd

Stability conditions and positivity of invariants of fibrations

We study three methods that prove the positivity of a natural numerical invariant associated to $1-$parameter families of polarized varieties. All these methods involve different stability conditions. In dimension 2 we prove that there is a natural connection between them, related to a yet another stability condition, the linear stability. Finally we make some speculations and prove new results in higher dimension.Comment: Final version, to appear in the Springer volume dedicated to Klaus Hulek on the occasion of his 60-th birthda