Water ice in the dark dune spots of Richardson crater on Mars

In this study we assess the presence, nature and properties of ices - in particular water ice - that occur within these spots using HIRISE and CRISM observations, as well as the LMD Global Climate Model. Our studies focus on Richardson crater (72{\deg}S, 179{\deg}E) and cover southern spring and summer (LS 175{\deg} - 17 341{\deg}). Three units have been identified of these spots: dark core, gray ring and bright halo. Each unit show characteristic changes as the season progress. In winter, the whole area is covered by CO2 ice with H2O ice contamination. Dark spots form during late winter and early spring. During spring, the dark spots are located in a 10 cm thick depression compared to the surrounding bright ice-rich layer. They are spectrally characterized by weak CO2 ice signatures that probably result from spatial mixing of CO2 ice rich and ice free regions within pixels, and from mixing of surface signatures due to aerosols scattering. The bright halo shaped by winds shows stronger CO2 absorptions than the average ice covered terrain, which is consistent with a formation process involving CO2 re-condensation. According to spectral, morphological and modeling considerations, the gray ring is composed of a thin layer of a few tens of {\mu}m of water ice. Two sources/processes could participate to the enrichment of water ice in the gray ring unit: (i) water ice condensation at the surface in early fall (prior to the condensation of a CO2 rich winter layer) or during winter time (due to cold trapping of the CO2 layer); (ii) ejection of dust grains surrounded by water ice by the geyser activity responsible for the dark spot. In any case, water ice remains longer in the gray ring unit after the complete sublimation of the CO2. Finally, we also looked for liquid water in the near-IR CRISM spectra using linear unmixing modeling but found no conclusive evidence for it

Oligomeric Status and Nucleotide Binding Properties of the Plastid ATP/ADP Transporter 1: Toward a Molecular Understanding of the Transport Mechanism

Background: Chloroplast ATP/ADP transporters are essential to energy homeostasis in plant cells. However, their molecular mechanism remains poorly understood, primarily due to the difficulty of producing and purifying functional recombinant forms of these transporters. Methodology/Principal Findings: In this work, we describe an expression and purification protocol providing good yields and efficient solubilization of NTT1 protein from Arabidopsis thaliana. By biochemical and biophysical analyses, we identified the best detergent for solubilization and purification of functional proteins, LAPAO. Purified NTT1 was found to accumulate as two independent pools of well folded, stable monomers and dimers. ATP and ADP binding properties were determined, and Pi, a co-substrate of ADP, was confirmed to be essential for nucleotide steady-state transport. Nucleotide binding studies and analysis of NTT1 mutants lead us to suggest the existence of two distinct and probably inter-dependent binding sites. Finally, fusion and deletion experiments demonstrated that the C-terminus of NTT1 is not essential for multimerization, but probably plays a regulatory role, controlling the nucleotide exchange rate. Conclusions/Significance: Taken together, these data provide a comprehensive molecular characterization of a chloroplas

LEDs based on conjugated PPV block copolymers

A way to control the bandgap in semi-conducting polymers is by preparing polymers with a partially conjugated backbone. In our laboratory, three conjugated copolymers containing PPV trimers as light emitting chromophores have been synthesized, which emit in the blue, green and orange wavelength region. The copolymers have a well defined conjugated backbone consisting of regularly alternating terphenylene and p-phenylene-vinylene blocks. The desired control of conjugation length is achieved through steric interaction induced by the side-chains in the terphenyl blocks of the copolymer. In this paper we evaluate the electrical and optical properties of LED devices based on these conjugated PPV block copolymers