Charged exctions in two-dimensional transition-metal dichalcogenides - semiclassical calculation of Berry-curvature effects

We theoretically study the role of the Berry curvature on neutral and charged excitons in two-dimensional transition-metal dichalcogenides. The Berry curvature arises due to a strong coupling between the conduction and valence bands in these materials that can to great extent be described within the model of massive Dirac fermions. The Berry curvature lifts the degeneracy of exciton states with opposite angular momentum. Using an electronic interaction that accounts for non-local screening effects, we find a Berry-curvature induced splitting of $\sim 17$ meV between the 2$p_{-}$ and 2$p_{+}$ exciton states in WS$_2$, consistent with experimental findings. Furthermore, we calculate the trion binding energies in WS$_2$ and WSe$_2$ for a large variety of screening lenghts and different dielectric constants for the environment. Our approach indicates the prominent role played by the Berry curvature along with non-local electronic interactions in the understanding of the energy spectra of neutral and charged excitons in transition-metal dichalcogenides and in the the interpretation of their optical properties.Comment: 11 pages, 3 figure

Polyamide from lactams by reactive rotational molding via anionic ring-opening polymerization: Optimization of processing parameters

A reactive rotational molding (RRM) process was developed to obtain a PA6 by activated anionic ring-opening polymerization of epsilon-caprolactam (APA6). Sodium caprolactamate (C10) and caprolactam magnesium bromide (C1) were employed as catalysts, and difunctional hexamethylene-1,6-dicarbamoylcaprolactam (C20) was used as an activator. The kinetics of the anionic polymerization of !-caprolactam into polyamide 6 was monitored through dynamic rheology and differential scanning calorimetry measurements. The effect of the processing parameters, such as the polymerization temperature, different catalyst/activator combinations and concentrations, on the kinetics of polymerization is discussed. A temperature of 150°C was demonstrated to be the most appropriate. It was also found that crystallization may occur during PA6 polymerization and that the combination C1/C20 was well suited as it permitted a suitable induction time. Isoviscosity curves were drawn in order to determine the available processing window for RRM. The properties of the obtained APA6 were compared with those of a conventionally rotomolded PA6. Results pointed at lower cycle times and increased tensile properties at weak deformation

KARAKTERISTIK FISIKOKIMIA GELATIN KULIT IKAN AYAM-AYAM ( Abaliste stellaris ) DENGAN PRA-PERLAKUAN KONSENTRASI ASAM SITRAT

Gelatin is a fibrous protein obtained by partial denaturation of collagen. Traditionally, gelatin derived  from mammals’ skins and bones, such as cow and pork. However, both mammals’ gelatin could risk for bovine spongiform encephalopathy (BSE) and foot mouth disease (FMD), besides, gelatin extracted from pork is prohibited in Islam rules. Therefore, fish processing waste is potential as a source of gelatin in terms of starry triggerfish (Abalistes stellaris) skin gelatin. The aims of this study is to characterize physichochemical of gelatin extracted from skin of starry triggerfish. The methods used in this research, experiment with completely randomized design (CDR) by soaking different concentrations of citric acid (0.2; 0.4; and 0.6 M). The results showed that the concentrations of citric acid  had significantly different (P0.05) on the yield, viscosity, gel strength, and fat content of starry triggerfish skin gelatin. On the other hand, the pH, melting point, galling point, protein, moisture, and ash value of starry triggerfish skin gelatin did not perform significantly different (P0.05). The most properties of starry triggerfish skin gelatin meet the commercial gelatin, and it is able to as a potential alternative of halal gelatin

Ectopic expression of PtaRHE1, encoding a poplar RING-H2 protein with E3 ligase activity, alters plant development and induces defence-related responses

RING (really interesting new gene)-H2 domain-containing proteins are widely represented in plants and play important roles in the regulation of many developmental processes as well as in plant–environment interactions. In the present report, experiments were performed to unravel the role of the poplar gene PtaRHE1, coding for a RING-H2 protein. In vitro ubiquitination assays indicate a functional E3 ligase activity for PtaRHE1 with the specific E2 ubiquitin-conjugating enzyme UbcH5a. The overexpression of PtaRHE1 in tobacco resulted in a pleiotropic phenotype characterized by a curling of the leaves, the formation of necrotic lesions on leaf blades, growth retardation, and a delay in floral transition. The plant gene expression response to PtaRHE1 overexpression provided evidence for the up-regulation of defence- and/or programmed cell death-related genes. Moreover, genes coding for WRKY transcription factors as well as for mitogen-activated protein kinases, such as wound-induced protein kinase (WIPK), were also found to be induced in the transgenic lines as compared with the wild type. In addition, histochemical β-glucuronidase staining showed that the PtaRHE1 promoter is induced by plant pathogens and by elicitors such as salicylic acid and cellulase. Taken together, these results suggest that the E3 ligase PtaRHE1 plays a role in the ubiquitination-mediated regulation of defence response, possibly by acting upstream of WIPK and/or in the activation of WRKY factors

Vibrational Enhancement of the Effective Donor - Acceptor Coupling

The paper deals with a simple three sites model for charge transfer phenomena in an one-dimensional donor (D) - bridge (B) - acceptor (A) system coupled with vibrational dynamics of the B site. It is found that in a certain range of parameters the vibrational coupling leads to an enhancement of the effective donor - acceptor electronic coupling as a result of the formation of the polaron on the B site. This enhancement of the charge transfer efficiency is maximum at the resonance, where the effective energy of the fluctuating B site coincides with the donor (acceptor) energy.Comment: 5 pages, 3 figure

DREAM: III.A helium survey in exoplanets on the edge of the hot Neptune desert with GIANO-B@TNG

The population of close-in exoplanets features a desert of hot Neptunes whose origin is uncertain. These planets may have lost their atmosphere, eroding into mini-Neptunes and super-Earths. Direct observations of evaporating atmospheres are essential to derive mass-loss estimates and constrain this scenario. The metastable 1083.3nm HeI triplet represents a powerful diagnostic of atmospheric evaporation since it traces the hot gas in extended exoplanet atmospheres, is observable from the ground, and is weakly affected by interstellar medium absorption. We conducted a uniform HeI transmission spectroscopy survey, focusing on 9 planets located at the edges of the Neptunian desert, aiming to gain insights into the role of photo-evaporation in its formation. We observed one transit per planet using the high-resolution, near-infrared spectrograph GIANO-B on the Telescopio Nazionale Galileo. We focused our analysis on the HeI triplet by computing high-resolution transmission spectra. We then employed the p-winds model to interpret the observed transmission spectra. We found no sign of planetary absorption in the HeI triplet in any of the investigated targets. We thus provided 3sigma upper-limit estimations on the thermosphere absorption, temperature, and mass loss, and combined them with past measurements to search for correlations with parameters thought to be drivers in the formation of the HeI triplet. Our results strengthen the importance of performing homogeneous surveys and analyses to bring clarification in the HeI detection and hence in the Neptunian desert origin. Our findings corroborate the literature expectations that the HeI absorption signal correlates with the stellar mass and the received XUV flux. However, these trends seem to disappear in terms of mass-loss rates; further studies are essential to shed light on this aspect and to understand better the photo-evaporation process.Comment: 23 pages, 13 figures, accepted for publication in A&A, after language editin

Analisis Kualitas Garam Hasil Produksi Prisma Rumah Kaca di Desa Sedayu Lawas, Kabupaten Lamongan, Jawa Timur

Desa Sedayu Lawas merupakan salah satu sentra produksi garam di Lamongan. Potensi tambak garam di desa ini cukup besar hanya saja produksi garam yang ada sebagian besar masih sangat tergantung kondisi cuaca. Salah satu inovasi dalam memproduksi garam rakyat untuk mengatasi masalah cuaca tersebut adalah dengan menggunakan teknologi Prisma Rumah Kaca.  Inovasi ini memanfaatkan rumah kaca dan plastik geomembran dalam proses kristalisasi garam. Tujuan dari penelitian ini adalah untuk menganalisis kualitas garam dari hasil produksi metode Prisma Rumah Kaca di desa Sedayu Lawas. Parameter yang diukur dalam penelitian ini adalah suhu, salinitas, kandungan Mg, kandungan Ca, kandungan NaCl dan kadar air. Hasil penelitian ini menunjukkan kalau kadar salinitas air pada kolam penampungan air muda adalah 23-24 ppt dan pada kolam penampungan air tua adalah 34-42 ppt. Nilai rata-rata NaCl, Mg dan Ca pada air muda secara berturut-turut adalah 115.000 mg/L, 313,6 mg/L dan 202,3 mg/L. Hasil pengujian air tua menunjukkan nilai rata-rata NaCl, Mg dan Ca secara berturut-turut adalah 129.333,3 mg/L, 313,6 mg/L dan 214,3 mg/L. Hasil uji kualitas garam menunjukkan kadar NaCl atas dasar berat basah (adbb) sebesar 87,56%, kadar Mg sebesar 2,15%, kadar Ca sebesar 3,45% dan kadar air sebesar 5,86%. Hasil penelitian ini mengindikasikan kalau kualitas garam yang dihasilkan melalui metode Prisma Rumah Kaca di desa Sedayu Lawas termasuk dalam kategori Kualitas K1 berdasarkan SNI 4435:2017

Dairy Consumption and the Incidence of Hyperglycemia and the Metabolic Syndrome: Results from a French prospective study, Data from the Epidemiological Study on the Insulin Resistance Syndrome (DESIR)

International audienceOBJECTIVE: In the French Data from the Epidemiological Study on the Insulin Resistance Syndrome (DESIR) cohort, cross-sectional analyses have shown that a higher consumption of dairy products and calcium are associated with a lower prevalence of the metabolic syndrome (MetS). We assess the influence of dairy products on 9-year incident MetS and on impaired fasting glycemia and/or type 2 diabetes (IFG/T2D). RESEARCH DESIGN AND METHODS: Men and women who completed a food frequency questionnaire at baseline and after 3 years were studied (n = 3,435). Logistic regression models were used to study associations between the average year 0 and year 3 consumption of milk and dairy products, cheese, dietary calcium density, and incident MetS and IFG/T2D after adjusting for 1) sex, age, alcohol, smoking, physical activity, fat intake and 2) additionally for BMI. Associations between dairy products and continuous variables were studied by repeated-measures ANCOVA, using the same covariates. RESULTS: Dairy products other than cheese, and dietary calcium density, were inversely associated with incident MetS and IFG/T2D; cheese was negatively associated with incident MetS. All three parameters were associated with lower diastolic blood pressure, and with a lower BMI gain. Higher cheese intake and calcium density were associated with a lower increase in waist circumference and lower triglyceride levels. Calcium density was also associated with a lower systolic blood pressure and a lower 9-year increase in plasma triglyceride levels. CONCLUSIONS: A higher consumption of dairy products and calcium was associated with a lower 9-year incidence of MetS and IFG/T2D in a large cohort drawn from the general population

ARES. III. Unveiling the Two Faces of KELT-7 b with HST WFC3*

We present the analysis of the hot-Jupiter KELT-7 b using transmission and emission spectroscopy from the Hubble Space Telescope, both taken with the Wide Field Camera 3. Our study uncovers a rich transmission spectrum that is consistent with a cloud-free atmosphere and suggests the presence of H_{2}O and H^{−}. In contrast, the extracted emission spectrum does not contain strong absorption features and, although it is not consistent with a simple blackbody, it can be explained by a varying temperature–pressure profile, collision induced absorption, and H^{-}. KELT-7 b had also been studied with other space-based instruments and we explore the effects of introducing these additional data sets. Further observations with Hubble, or the next generation of space-based telescopes, are needed to allow for the optical opacity source in transmission to be confirmed and for molecular features to be disentangled in emission