3,646 research outputs found

    Anxiety: An Adaptive Emotion

    Get PDF

    Estimating Gaps and Trends for the Chilean Economy

    Get PDF
    Trend GDP and the output gap are key inputs for policy evaluation and forecasting in standard models of monetary policy. However, the measurement of these variables is plagued with difficulties. In this paper we propose two different approaches. First, a data-based approach, that starts with the primal and dual estimates of total factor productivity (TFP) growth, and then uses a variety of procedures to filter the inputs. Second, a model-consistent framework that simultaneously estimates the macroeconomic dynamics and the underlying trends of the economy. We compare the difficulties in using each methodology, and we use them to construct measures of the output gap and potential growth for Chile

    Decision making and skill development In youth football players

    Full text link
    Este artículo presenta como se desarrolla la toma de decisiones y la habilidad técnica en jugadores con alto nivel de pericia desde los 6-7 a 13-14 años. El marco teórico está basado en la perspectiva de los sistemas dinámicos y la enseñanza comprensiva de los deportes. Se tomó como muestra a 57 jugadores del primer equipo de cada categoría de edad del Albacete Balompié: prebenjamín, benjamín, alevín e infantil. El instrumento usado fue la Herramienta de Evaluación del Rendimiento de Juego (HERJ), que mide la toma de decisiones y la ejecución, incluyendo el análisis ecológico atendiendo a principios tácticos (Bayer, 1992), comparando la situación en el juego con la decisión aplicada. Los resultados se basan en el análisis inferencial y correlacional. La evolución del rendimiento de juego se orienta desde el ataque hasta la defensa. Se han encontrado diferencias significativas en las variables entre las cuatro categorías de formación estudiadas, especialmente en el principio táctico de progresar hacia la portería contraria y en el desmarque, así como en el marcaje y la ayuda en defensa.This paper presents how decision-making and skills are developed in high level of expertise players from 6-7 to 13-14 years. The framework is based on the dynamical systems and teaching games for understanding approaches. Participants were 57 first team players of each age (n = 13 to 16) of Albacete Balompié: U-8, U-10, U-12 and U-14. The Game Performance Assessment Tool (GPET) was the instrument used for assessment, which measures decision-making and execution from an ecological view in relation to tactical principles (Bayer, 1992), comparing the game situation with the decision applied. The results are based on inferential and correlation analysis. The evolution of knowledge evolves attack to defensive. We have found significant differences in variables between the four age categories studied. These differences have been shown in attack: the progress toward goal tactical principle and shake off; on defence: marking and cover (off-ball defenders)

    Through the magnifying glass: ALMA acute viewing of the intricate nebular architecture of OH231.8+4.2

    Full text link
    We present continuum and molecular line emission ALMA observations of OH 231.8+4.2, a well studied bipolar nebula around an asymptotic giant branch (AGB) star. The high angular resolution (~0.2-0.3 arcsec) and sensitivity of our ALMA maps provide the most detailed and accurate description of the overall nebular structure and kinematics of this object to date. We have identified a number of outflow components previously unknown. Species studied in this work include 12CO, 13CO, CS, SO, SO2, OCS, SiO, SiS, H3O+, Na37Cl, and CH3OH. The molecules Na37Cl and CH3OH are first detections in OH 231.8+4.2, with CH3OH being also a first detection in an AGB star. Our ALMA maps bring to light the totally unexpected position of the mass-losing AGB star (QX Pup) relative to the large-scale outflow. QX Pup is enshrouded within a compact (<60 AU) parcel of dust and gas (clump S) in expansion (V~5-7 km/s) that is displaced by 0.6arcsec to the south of the dense equatorial region (or waist) where the bipolar lobes join. Our SiO maps disclose a compact bipolar outflow that emerges from QX Pup's vicinity. This outflow is oriented similarly to the large-scale nebula but the expansion velocities are about ten times lower (~35 km/s). We deduce short kinematical ages for the SiO outflow, ranging from ~50-80 yr, in regions within ~150 AU, to ~400-500 yr at the lobe tips (~3500 AU). Adjacent to the SiO outflow, we identify a small-scale hourglass-shaped structure (mini-hourglass) that is probably made of compressed ambient material formed as the SiO outflow penetrates the dense, central regions of the nebula. The lobes and the equatorial waist of the mini-hourglass are both radially expanding with a constant velocity gradient. The mini-waist is characterized by extremely low velocities, down to ~1 km/s at ~150 AU, which tentatively suggest the presence of a stable structure. (abridged

    Nonlinear waves in a chain of magnetically coupled pendula

    Get PDF
    A motivation for the study of reduced models like one-dimensional systems in Solid State Physics is the complexity of the full problem. In recent years our group has studied theoretically, numerically and experimentally wave propagation in lattices of nonlinearly coupled oscillators. Here, we present the dynamics of magnetically coupled pendula lattices. These macroscopic systems can model the dynamical processes of matter or layered systems. We report the results obtained for harmonic wave propagation in these media, and the different regimes of mode conversion into higher harmonics strongly influenced by dispersion and discreteness, including the phenomenon of acoustic dilatation of the chain, as well as some results on the propagation of localized waves i.e., solitons and kinks.Generalitat Valenciana APOSTD/2017/042Umiversitat Politècnica de València PAID-01-14Ministerio de Economía y Competitividad (MINECO), Spain FIS2015-65998-C2-2-PJunta de Andalucía 2017/FQM-28

    Borates or phosphates? That is the question

    Full text link
    [EN] Chemical nomenclature is perceived to be a closed topic. However, this work shows that the identification of polyanionic groups is still ambiguous and so is the nomenclature for some ternary compounds. Two examples, boron phosphate (BPO4) and boron arsenate (BAsO4), which were assigned to the large phosphate and arsenate families, respectively, nearly a century ago, are explored. The analyses show that these two compounds should be renamed phosphorus borate (PBO4) and arsenic borate (AsBO4). Beyond epistemology, this has pleasing consequences at several levels for the predictive character of chemistry. It paves the way for future work on the possible syntheses of SbBO4 and BiBO4, and it also renders previous structure field maps completely predictive, allowing us to foresee the structure and phase transitions of NbBO4 and TaBO4. Overall, this work demonstrates that quantum mechanics calculations can contribute to the improvement of current chemical nomenclature. Such revisitation is necessary to classify compounds and understand their properties, leading to the main final aim of a chemist: predicting new compounds, their structures and their transformations.This research was partially supported by Spanish MINECO (grant Nos. MAT2015-71070-REDC and MAT2016-75586-C4-2-P, and MALTA Consolider Team RED2018-102612-T) and Generalitat Valenciana (grant No. PROMETEO/2018/123-EFIMAT). J. Contreras-Garci ' a thanks CALSIMLAB (public grant No. ANR-11-LABX-0037-01), overseen by the French National Research Agency (ANR) as part of the Investissements d'Avenir program (grant No. ANR-11-IDEX-0004-02). M. Marque ' s acknowledges support from the ERC grant `Hecate' and computational resources provided by the UKCP consortium under EPSRC grant EP/P022561/1.Contreras-García, J.; Izquierdo-Ruiz, F.; Marqués, M.; Manjón, F. (2020). Borates or phosphates? That is the question. Acta Crystallographica Section A: Foundations and Advances. 76:197-205. https://doi.org/10.1107/S2053273319016826S19720576Abraham, R. H. & Marsden, J. E. (1994). Foundations of Mechanics. Reading: Addison Wesley.Alinger, N. L., Clark, T., Gasteiger, J., Kollman, P. A., Schaefer, H. F. III, Schreiner, P. R. & Schleyer, von R. (1998). Encyclopedia of Computational Chemistry, edited by R. F. W. Bader. Chichester: Wiley.Bader, R. F. W. (1990). Atoms in Molecules, a Quantum Theory. Oxford: Clarendon.Bader, R. F. W. (1994). Principle of stationary action and the definition of a proper open system. Physical Review B, 49(19), 13348-13356. doi:10.1103/physrevb.49.13348Bastide, J. P. (1987). Systématique simplifiée des composés ABX4 (X = O2−, F−) et evolution possible de leurs structures cristallines sous pression. Journal of Solid State Chemistry, 71(1), 115-120. doi:10.1016/0022-4596(87)90149-6Bayer, G. (1972). Thermal expansion of ABO4-compounds with zircon- and scheelite structures. Journal of the Less Common Metals, 26(2), 255-262. doi:10.1016/0022-5088(72)90045-8Blasse, G., & Van Den Heuvel, G. P. M. (1973). Some optical properties of tantalum borate (tabo4), a compound with unusual coordinations. Physica Status Solidi (a), 19(1), 111-117. doi:10.1002/pssa.2210190109Boyd, R. J. & Matta, C. F. (2007). Editors. The Quantum Theory of Atoms in Molecules. From Solid State to DNA and Drug Design. Weinheim: Wiley-VCH.Brill, R., & Debretteville, A. P. (1955). On the chemical bond type in AlPO4. Acta Crystallographica, 8(9), 567-570. doi:10.1107/s0365110x5500176xDachille, F., & Glasser, L. S. D. (1959). High pressure forms of BPO4 and BAsO4; quartz analogues. Acta Crystallographica, 12(10), 820-821. doi:10.1107/s0365110x59002365Dachille, F., & Roy, R. (1959). High-pressure region of the silica isotypes. Zeitschrift für Kristallographie, 111(1-6), 451-461. doi:10.1524/zkri.1959.111.1-6.451Demartin, F., Diella, V., Gramaccioli, C. M., & Pezzotta, F. (2001). Schiavinatoite, (Nb,Ta)BO4, the Nb analogue of behierite. European Journal of Mineralogy, 13(1), 159-165. doi:10.1127/0935-1221/01/0013-0159Depero, L. E., & Sangaletti, L. (1997). Cation Sublattice and Coordination Polyhedra inABO4Type of Structures. Journal of Solid State Chemistry, 129(1), 82-91. doi:10.1006/jssc.1996.7234Errandonea, D., & Manjón, F. J. (2008). Pressure effects on the structural and electronic properties of ABX4 scintillating crystals. Progress in Materials Science, 53(4), 711-773. doi:10.1016/j.pmatsci.2008.02.001Fukunaga, O., & Yamaoka, S. (1979). Phase transformations in ABO 4 type compounds under high pressure. Physics and Chemistry of Minerals, 5(2), 167-177. doi:10.1007/bf00307551Gázquez, J. L., & Ortiz, E. (1984). Electronegativities and hardnesses of open shell atoms. The Journal of Chemical Physics, 81(6), 2741-2748. doi:10.1063/1.447946Geerlings, P., De Proft, F., & Langenaeker, W. (2003). Conceptual Density Functional Theory. Chemical Reviews, 103(5), 1793-1874. doi:10.1021/cr990029pGenoni, A., Bučinský, L., Claiser, N., Contreras‐García, J., Dittrich, B., Dominiak, P. M., … Grabowsky, S. (2018). Quantum Crystallography: Current Developments and Future Perspectives. Chemistry – A European Journal, 24(43), 10881-10905. doi:10.1002/chem.201705952Gibbs, G. V., Cox, D. F., Boisen, M. B., Downs, R. T., & Ross, N. L. (2003). The electron localization function: a tool for locating favorable proton docking sites in the silica polymorphs. Physics and Chemistry of Minerals, 30(5), 305-316. doi:10.1007/s00269-003-0318-2Gramaccioli, C. M. (2000). Un nuovo minerale: la schiavinatoite. Rendiconti Lincei, 11(4), 197-199. doi:10.1007/bf02904665Haines, J., Chateau, C., Léger, J. M., Bogicevic, C., Hull, S., Klug, D. D., & Tse, J. S. (2003). Collapsing Cristobalitelike Structures in Silica Analogues at High Pressure. Physical Review Letters, 91(1). doi:10.1103/physrevlett.91.015503Hazen, R. M., & Finger, L. W. (1979). Bulk modulus-volume relationship for cation-anion polyhedra. Journal of Geophysical Research: Solid Earth, 84(B12), 6723-6728. doi:10.1029/jb084ib12p06723Hazen, R. M., Finger, L. W., & Mariathasan, J. W. E. (1985). High-pressure crystal chemistry of scheelite-type tungstates and molybdates. Journal of Physics and Chemistry of Solids, 46(2), 253-263. doi:10.1016/0022-3697(85)90039-3IUPAC (1970). Nomenclature of Inorganic Solids. Definitive Rules. 3rd ed. London: International Union of Pure and Applied Chemistry.Kniep, R., Gözel, G., Eisenmann, B., Röhr, C., Asbrand, M., & Kizilyalli, M. (1994). Borophosphates—A Neglected Class of Compounds: Crystal Structures of MII[BPO5](MII Ca, Sr) and Ba3[BP3O12]. Angewandte Chemie International Edition in English, 33(7), 749-751. doi:10.1002/anie.199407491Kresse, G., & Joubert, D. (1999). From ultrasoft pseudopotentials to the projector augmented-wave method. Physical Review B, 59(3), 1758-1775. doi:10.1103/physrevb.59.1758Lashin, V. E., Khritokhin, N. A., & Andreev, O. V. (2012). Structure maps of ABX4 inorganic compounds. Russian Journal of Inorganic Chemistry, 57(12), 1584-1587. doi:10.1134/s0036023612120133Léger, J. M., Haines, J., Chateau, C., Bocquillon, G., Schmidt, M. W., Hull, S., … Marchand, R. (2001). Phosphorus oxynitride PON, a silica analogue: structure and compression of the cristobalite-like phase; P  - T phase diagram. Physics and Chemistry of Minerals, 28(6), 388-398. doi:10.1007/s002690100161Liu, L. (1982). Phase transformations in MSiO4 compounds at high pressures and their geophysical implications. Earth and Planetary Science Letters, 57(1), 110-116. doi:10.1016/0012-821x(82)90177-7Martín Pendás, A., Costales, A., Blanco, M. A., Recio, J. M., & Luaña, V. (2000). Local compressibilities in crystals. Physical Review B, 62(21), 13970-13978. doi:10.1103/physrevb.62.13970Monkhorst, H. J., & Pack, J. D. (1976). Special points for Brillouin-zone integrations. Physical Review B, 13(12), 5188-5192. doi:10.1103/physrevb.13.5188Mori-Sánchez, P., Pendás, A. M., & Luaña, V. (2001). Polarity inversion in the electron density of BP crystal. Physical Review B, 63(12). doi:10.1103/physrevb.63.125103Muller, O., & Roy, R. (1973). Phase transitions among the ABX4compounds*,1. Zeitschrift für Kristallographie, 138(138), 237-253. doi:10.1524/zkri.1973.138.138.237O’Keeffe, M., & Hyde, B. G. (1976). Cristobalites and topologically-related structures. Acta Crystallographica Section B Structural Crystallography and Crystal Chemistry, 32(11), 2923-2936. doi:10.1107/s0567740876009308Otero-de-la-Roza, A., Blanco, M. A., Pendás, A. M., & Luaña, V. (2009). Critic: a new program for the topological analysis of solid-state electron densities. Computer Physics Communications, 180(1), 157-166. doi:10.1016/j.cpc.2008.07.018Otero-de-la-Roza, A., Johnson, E. R., & Contreras-García, J. (2012). Revealing non-covalent interactions in solids: NCI plots revisited. Physical Chemistry Chemical Physics, 14(35), 12165. doi:10.1039/c2cp41395gPauling, L. (1929). THE PRINCIPLES DETERMINING THE STRUCTURE OF COMPLEX IONIC CRYSTALS. Journal of the American Chemical Society, 51(4), 1010-1026. doi:10.1021/ja01379a006Pauling, L. (1960). The Nature of the Chemical Bond and the Structure of Molecules and Crystals: An Introduction to Modern Structural Chemistry, 3rd ed., pp. 543-562. Ithaca: Cornell University Press.Perdew, J. P., Burke, K., & Ernzerhof, M. (1996). Generalized Gradient Approximation Made Simple. Physical Review Letters, 77(18), 3865-3868. doi:10.1103/physrevlett.77.3865Rahm, M., Zeng, T., & Hoffmann, R. (2018). Electronegativity Seen as the Ground-State Average Valence Electron Binding Energy. Journal of the American Chemical Society, 141(1), 342-351. doi:10.1021/jacs.8b10246Range, K.-J., Wildenauer, M., & Heyns, A. M. (1988). Extremely Short Non-Bonding Oxygen?Oxygen Distances: The Crystal Structures of NbBO4, NaNb3O8, and NaTa3O8. Angewandte Chemie International Edition in English, 27(7), 969-971. doi:10.1002/anie.198809691Recio, J. M., Franco, R., Martín Pendás, A., Blanco, M. A., Pueyo, L., & Pandey, R. (2001). Theoretical explanation of the uniform compressibility behavior observed in oxide spinels. Physical Review B, 63(18). doi:10.1103/physrevb.63.184101Schulze, G. E. R. (1933). Die Kristallstruktur von BPO4 und BAsO4. Die Naturwissenschaften, 21(30), 562-562. doi:10.1007/bf01503856Scott, H. P., Williams, Q., & Knittle, E. (2001). Ultralow Compressibility Silicate without Highly Coordinated Silicon. Physical Review Letters, 88(1). doi:10.1103/physrevlett.88.015506Shannon, R. D. (1976). Revised effective ionic radii and systematic studies of interatomic distances in halides and chalcogenides. Acta Crystallographica Section A, 32(5), 751-767. doi:10.1107/s0567739476001551Stubican, V. S., & Roy, R. (1963). High-pressure scheelite-structure polymorphs of rare-earth vanadates and arsenates. Zeitschrift für Kristallographie, 119(1-2), 90-97. doi:10.1524/zkri.1963.119.1-2.90Vinet, P., Ferrante, J., Smith, J. R. & Rose, J. H. (1986). J. Phys. C: Solid State Phys. L, 19, 467.Vorres, K. S. (1962). Correlating ABO4 compound structures. Journal of Chemical Education, 39(11), 566. doi:10.1021/ed039p566Yang, W., Parr, R. G., & Uytterhoeven, L. (1987). New relation between hardness and compressibility of minerals. Physics and Chemistry of Minerals, 15(2), 191-195. doi:10.1007/bf00308783Zhang, J., Song, L., Sist, M., Tolborg, K., & Iversen, B. B. (2018). Chemical bonding origin of the unexpected isotropic physical properties in thermoelectric Mg3Sb2 and related materials. Nature Communications, 9(1). doi:10.1038/s41467-018-06980-
    corecore