Air mass origin and its influence over the aerosol size distribution: a study in SE Spain

International audienceA k-means cluster analysis of 96 hour trajectories arriving in Southeast (SE) Spain at 3000, 1500 and 500 m for the 7-year period 2000?2006 has been performed to identify and describe the main flows arriving at the study area. The dependence of the aerosol size distribution on the air mass origin has been studied by using non-parametric statistics. There are statistically significant differences on aerosol size distribution and meteorological variables at surface level according to the identified clusters

Contributions to the study of porosity in fly ash-based geopolymers. Relationship between degree of reaction, porosity and compressive strength

The main contribution of this paper relates to the development of a systematic study involving a set of parameters which could potentially have an impact on geopolymer properties: curing temperature, type of activating solution, alkali metal in solution, incorporation of slag (Ca source) and type of slag used. The microstructures, degrees of reaction, porosities and compressive strengths of geopolymers have been evaluated. Geopolymers prepared with soluble silicate presented a more compacted and closed structure, a larger amount of gel, lower porosity and greater compressive strength than those prepared with hydroxides. On the other hand, Na-geopolymers were more porous but more resistant than K-geopolymers. Although there is an inverse relation between degree of reaction and porosity, between compressive strength and porosity it is not always inversely proportional and could, in some cases, be masked by changes produced in other influencing parameters.Contribuciones al estudio de la porosidad de geopolímeros basados en cenizas volantes. Relación entre grado de reacción, porosidad y resistencia a compresión. La principal contribución de este documento es el desarrollo de un estudio sistemático implicando una serie de parámetros que podrían afectar a las propiedades de los geopolímeros: temperatura de curado, solución activadora, metal alcalino de la solución, incorporación de escorias (fuente de calcio) y tipo de escorias. Se han evaluado: microestructura, grado de reacción, porosidad y resistencia a compresión. Los geopolímeros preparados con silicatos presentaron un microestructura más densa y compacta, una mayor cantidad del gel geopolimérico, menor porosidad y mejores propiedades mecánicas que los preparados con hidróxidos. Los geopolímeros preparados con sales de sodio fueron más porosos pero más resistentes que los preparados con sales potasio. Aunque existe una relación inversa entre el grado de reacción y la porosidad, en algunos casos, la relación entre resistencia y porosidad es inexistente ya que puede estar enmascarada por cambios producidos por otros parámetros que afecten a la reacción.Ministerio de Ciencia y Tecnología CTM2010-1991

Efficient plot-based floristic assessment of tropical forests

The tropical flora remains chronically understudied and the lack of floristic understanding hampers ecological research and its application for large-scale conservation planning. Given scarce resources and the scale of the challenge there is a need to maximize the efficiency of both sampling strategies and sampling units, yet there is little information on the relative efficiency of different approaches to floristic assessment in tropical forests. This paper is the first attempt to address this gap. We repeatedly sampled forests in two regions of Amazonia using the two most widely used plot-based protocols of floristic sampling, and compared their performance in terms of the quantity of floristic knowledge and ecological insight gained scaled to the field effort required. Specifically, the methods are assessed first in terms of the number of person-days required to complete each sample (‘effort’), secondly by the total gain in the quantity of floristic information that each unit of effort provides (‘crude inventory efficiency’), and thirdly in terms of the floristic information gained as a proportion of the target species pool (‘proportional inventory efficiency’). Finally, we compare the methods in terms of their efficiency in identifying different ecological patterns within the data (‘ecological efficiency’) while controlling for effort. There are large and consistent differences in the performance of the two methods. The disparity is maintained even after accounting for regional and site-level variation in forest species richness, tree density and the number of field assistants. We interpret our results in the context of selecting the appropriate method for particular research purposes

Application of an Exhausted Fermentation Broth Obtained from Biohydrogen Production in an Apple Orchard: Assessment of Fruit Quality

About 95% of global hydrogen production is made by fossil fuels using different technologies which are all characterized by high energy consumption and high carbon emissions. Alternatively, more sustainable production methods, such as biological fermentation processes, are under study. Dark fermentation, also called acidogenesis, entails the transformation of a great variety of organic substances into a mixture of organic and inorganic products, as well as gases (H-2 and CO2). In this study we tested an exhausted fermentation broth, derived after Clostridium fermentation for H-2 production, as a biostimulant via foliar application in an intensive apple orchard. Two different doses were applied upon dilution of the broth in water (100 mL L-1 and 10 mL L-1), evaluating the main fruit quality parameters (fresh weight, fruit diameter, dry matter, firmness, soluble solid content, color lightness, DA index) in addition to macro- and micro-nutrients and heavy metals concentrations. Chemical characterization of the broth showed a high amount of low-MW polypeptides (Trp-Glu-Lys, Ile-Pro-Ile, Phe-Pro-Lys, His-Pro) and organic acids (formic acid, butyric acid, butanedioic acid); moreover, quantitative analyses of inorganic ions showed no heavy metal detection but high concentrations of nitrogen, phosphorus and potassium, compatible with use in agriculture. The fruit quality parameters showed significantly higher mean fruit weight compared to the untreated trees, as well as higher dry matter. No statistical differences were recorded among the treatments for fruit firmness, diameter and yield. Soluble solids content in both treatments were significantly lower than the controls, whereas the DA index mean values were higher in both treatments compared to the controls, indicating a delay in fruit ripening probably due to the high nitrogen broth concentration. Regarding the chemical analyses of fruits, no particular differences were found among the treatments, except for Fe, which showed a significantly higher amount upon treatment with the lower dose. As concerns leaves, no phytotoxic symptoms were detected in both treatments, making the described exhausted broth a candidate for its use as a plant biostimulant. Additional studies are needed to evaluate the ideal application dose, identify further action targets and implement appropriate strategies to concentrate the biostimulant active compounds

A possible cyclotron resonance scattering feature near 0.7 keV in X1822-371

We analyse all available X-ray observations of X1822-371 made with XMM-Newton, Chandra, Suzaku and INTEGRAL satellites. The observations were not simultaneous. The Suzaku and INTEGRAL broad band energy coverage allows us to constrain the spectral shape of the continuum emission well. We use the model already proposed for this source, consisting of a Comptonised component absorbed by interstellar matter and partially absorbed by local neutral matter, and we added a Gaussian feature in absorption at $\sim 0.7$ keV. This addition significantly improves the fit and flattens the residuals between 0.6 and 0.8 keV. We interpret the Gaussian feature in absorption as a cyclotron resonant scattering feature (CRSF) produced close to the neutron star surface and derive the magnetic field strength at the surface of the neutron star, $(8.8 \pm 0.3) \times 10^{10}$ G for a radius of 10 km. We derive the pulse period in the EPIC-pn data to be 0.5928850(6) s and estimate that the spin period derivative of X1822-371 is $(-2.55 \pm 0.03) \times 10^{-12}$ s/s using all available pulse period measurements. Assuming that the intrinsic luminosity of X1822-371is at the Eddington limit and using the values of spin period and spin period derivative of the source, we constrain the neutron star and companion star masses. We find the neutron star and the companion star masses to be $1.69 \pm 0.13$ M$_{\odot}$ and $0.46 \pm 0.02$ M$_{\odot}$, respectively, for a neutron star radius of 10 km.In a self-consistent scenario in which X1822-371 is spinning-up and accretes at the Eddington limit, we estimate that the magnetic field of the neutron star is $(8.8 \pm 0.3) \times 10^{10}$ G for a neutron star radius of 10 km. If our interpretation is correct, the Gaussian absorption feature near 0.7 keV is the very first detection of a CRSF below 1 keV in a LMXB. (abridged)Comment: 14 pages, 12 figures, accepted for publication in A&

Signature of the presence of a third body orbiting around XB 1916-053

The ultra-compact dipping source \object{XB 1916-053} has an orbital period of close to 50 min and a companion star with a very low mass (less than 0.1 M$_{\odot}$). The orbital period derivative of the source was estimated to be $1.5(3) \times 10^{-11}$ s/s through analysing the delays associated with the dip arrival times obtained from observations spanning 25 years, from 1978 to 2002. The known orbital period derivative is extremely large and can be explained by invoking an extreme, non-conservative mass transfer rate that is not easily justifiable. We extended the analysed data from 1978 to 2014, by spanning 37 years, to verify whether a larger sample of data can be fitted with a quadratic term or a different scenario has to be considered. We obtained 27 delays associated with the dip arrival times from data covering 37 years and used different models to fit the time delays with respect to a constant period model.We find that the quadratic form alone does not fit the data. The data are well fitted using a sinusoidal term plus a quadratic function or, alternatively, with a series of sinusoidal terms that can be associated with a modulation of the dip arrival times due to the presence of a third body that has an elliptical orbit. We infer that for a conservative mass transfer scenario the modulation of the delays can be explained by invoking the presence of a third body with mass between 0.10-0.14 M$_{\odot}$, orbital period around the X-ray binary system of close to 51 yr and an eccentricity of $0.28 \pm 0.15$. In a non-conservative mass transfer scenario we estimate that the fraction of matter yielded by the degenerate companion star and accreted onto the neutron star is $\beta = 0.08$, the neutron star mass is $\ge 2.2$ M$_{\odot}$, and the companion star mass is 0.028 M$_{\odot}$. (Abridged)Comment: 13 pages, 9 figures. Accepted for publication in A&