First direct evidence of N-heterocyclic carbene in BMIm acetate ionic liquid. An electrochemical and chemical study on the role of temperature

Cyclic voltammetry provides the first direct evidence of N-­heterocyclic carbene (NHC) presence in neat 1-‐butyl-­3-­methylimidazolium acetate ionic liquid (BMImAcO) at 120°C. The NHC existence, proved by its oxidation current in cyclic voltammetry, was confirmed by the formation of a PhCHO-­NHC adduct in pure ionic liquid. The role of the temperature was considered

Baseline design of the filters for the LAD detector on board LOFT

The Large Observatory for X-ray Timing (LOFT) was one of the M3 missions selected for the phase A study in the ESA's Cosmic Vision program. LOFT is designed to perform high-time-resolution X-ray observations of black holes and neutron stars. The main instrument on the LOFT payload is the Large Area Detector (LAD), a collimated experiment with a nominal effective area of ~10 m 2 @ 8 keV, and a spectral resolution of ~240 eV in the energy band 2-30 keV. These performances are achieved covering a large collecting area with more than 2000 large-area Silicon Drift Detectors (SDDs) each one coupled to a collimator based on lead-glass micro-channel plates. In order to reduce the thermal load onto the detectors, which are open to Sky, and to protect them from out of band radiation, optical-thermal filter will be mounted in front of the SDDs. Different options have been considered for the LAD filters for best compromise between high quantum efficiency and high mechanical robustness. We present the baseline design of the optical-thermal filters, show the nominal performances, and present preliminary test results performed during the phase A study.Comment: Proc. SPIE 9144, Space Telescopes and Instrumentation 2014: Ultraviolet to Gamma Ray, 91446

Comparative study of the two large flares from SGR1900+14 with the BeppoSAX Gamma-Ray Burst Monitor

We report on spectral and temporal results of the 40-700 keV observations, obtained with the Gamma-Ray Burst Monitor (GRBM) on board BeppoSAX, of the two large flares from the Soft Gamma-ray Repeater SGR1900+14 occurred on August 27, 1998 and April 18, 2001. From their intensity, fluence and duration, the first one was classified as "giant" and the second as "intermediate". The spectral results have been obtained with an improved response function of the GRBM. We find that the two events have similar spectral properties, but different temporal properties. The major difference concerns the time profiles of the light curves, whereas the lack of evidence in the 2001 flare for the erratic time variability found at high frequencies (10-1000 Hz) in the 1998 flare could be ascribed to lower counting statistics. We discuss these results in the light of the magnetar model proposed for SGR sources.Comment: 15 pages, 20 figures, accepted for publication in A&

The complex time behaviour of the microquasar GRS 1915+105 in the \rho-class observed with BeppoSAX. III: The hard X-ray delay and limit cycle mapping

The microquasar GRS1915+105 was observed by BeppoSAX in October 2000 for about ten days while the source was in \rho-mode, which is characterized by a quasi-regular type I bursting activity. This paper presents a systematic analysis of the delay of the hard and soft X-ray emission at the burst peaks. The lag, also apparent from the comparison of the [1.7-3.4] keV light curves with those in the [6.8-10.2] keV range, is evaluated and studied as a function of time, spectral parameters, and flux. We apply the limit cycle mapping technique, using as independent variables the count rate and the mean photon rate. The results using this technique were also cross-checked using a more standard approach with the cross-correlation methods. Data are organized in runs, each relative to a continuous observation interval. The detected hard-soft delay changes in the course of the pointing from about 3 s to about 10 s and presents a clear correlation with the baseline count rate.Comment: accepted for publication in A&

Supernovae, Pulsars and Gamma-Ray Bursts: A Unified Picture

A scenario is proposed that explains both the observed high pulsar velocities and extragalactic gamma-ray bursts (GRBs). The model involves an ultra- relativistic jet from a supernova (SN), that produces a GRB and its afterglow, whose characteristics are similar to an isotropic fireball GRB perhaps with some differences at late times in the afterglow once some significant transverse diffusion has occurred. The time scales and many other properties of GRBs and their afterglows in this model are consistent with observations. GRBs in this model have special intrinsic properties, that can either falsify or prove this model unambiguously by observations. The most direct proof is the detection of a SN about the same time as the luminous GRB event. Most GRBs and SNe are expected occur at moderate redshift ($z\sim 1-3$), if they follow the observed universal star formation history, as implied in this model. Searching for GRB/SN associations is a challenge, because majority of the SNe will be faint. Some additional, dramatic observable consequences are predicted, which can also be utilized to test the model.Comment: ApJ Letters in press, 4 emulateapj page

A Robust Filter for the BeppoSAX Gamma Ray Burst Monitor Triggers

The BeppoSAX Gamma Ray Burst Monitor (GRBM) is triggered any time a statistically significant counting excess is simultaneously revealed by at least two of its four independent detectors. Several spurious effects, including highly ionizing particles crossing two detectors, are recorded as onboard triggers. In fact, a large number of false triggers is detected, in the order of 10/day. A software code, based on an heuristic algorithm, was written to discriminate between real and false triggers. We present the results of the analysis on an homogeneous sample of GRBM triggers, thus providing an estimate of the efficiency of the GRB detection system consisting of the GRBM and the software.Comment: Proc. 5th Huntsville GRB Symposiu

An innovative strategy for electrochemically-promoted addition reactions

A new strategy based on the catalytic release of the supporting electrolyte agent in the electrolysis medium proved to be effective for the direct electroactivation of suitable C–H acid-containing compounds vs. catalytic addition processes, under solvent-free conditions