11,120 research outputs found
Exotic magnetism in the alkali sesquoxides Rb4O6 and Cs4O6
Among the various alkali oxides the sesquioxides Rb4O6 and Cs4O6 are of
special interest. Electronic structure calculations using the local
spin-density approximation predicted that Rb4O6 should be a half-metallic
ferromagnet, which was later contradicted when an experimental investigation of
the temperature dependent magnetization of Rb4O6 showed a low-temperature
magnetic transition and differences between zero-field-cooled (ZFC) and
field-cooled (FC) measurements. Such behavior is known from spin glasses and
frustrated systems. Rb4O6 and Cs4O6 comprise two different types of dioxygen
anions, the hyperoxide and the peroxide anions. The nonmagnetic peroxide anions
do not contain unpaired electrons while the hyperoxide anions contain unpaired
electrons in antibonding pi*-orbitals. High electron localization (narrow
bands) suggests that electronic correlations are of major importance in these
open shell p-electron systems. Correlations and charge ordering due to the
mixed valency render p-electron-based anionogenic magnetic order possible in
the sesquioxides. In this work we present an experimental comparison of Rb4O6
and the related Cs4O6. The crystal structures are verified using powder x-ray
diffraction. The mixed valency of both compounds is confirmed using Raman
spectroscopy, and time-dependent magnetization experiments indicate that both
compounds show magnetic frustration, a feature only previously known from d-
and f-electron systems
Bond breaking in vibrationally excited methane on transition metal catalysts
The role of vibrational excitation of a single mode in the scattering of
methane is studied by wave packet simulations of oriented CH4 and CD4 molecules
from a flat surface. All nine internal vibrations are included. In the
translational energy range from 32 up to 128 kJ/mol we find that initial
vibrational excitations enhance the transfer of translational energy towards
vibrational energy and increase the accessibility of the entrance channel for
dissociation. Our simulations predict that initial vibrational excitations of
the asymmetrical stretch (nu_3) and especially the symmetrical stretch (nu_1)
modes will give the highest enhancement of the dissociation probability of
methane.Comment: 4 pages REVTeX, 2 figures (eps), to be published in Phys. Rev. B.
(See also arXiv:physics.chem-ph/0003031). Journal version at
http://publish.aps.org/abstract/PRB/v61/p1565
Structural and Magnetic Properties of Trigonal Iron
First principles calculations of the electronic structure of trigonal iron
were performed using density function theory. The results are used to predict
lattice spacings, magnetic moments and elastic properties; these are in good
agreement with experiment for both the bcc and fcc structures. We find however,
that in extracting these quantities great care must be taken in interpreting
numerical fits to the calculated total energies. In addition, the results for
bulk iron give insight into the properties of thin iron films. Thin films grown
on substrates with mismatched lattice constants often have non-cubic symmetry.
If they are thicker than a few monolayers their electronic structure is similar
to a bulk material with an appropriately distorted geometry, as in our trigonal
calculations. We recast our bulk results in terms of an iron film grown on the
(111) surface of an fcc substrate, and find the predicted strain energies and
moments accurately reflect the trends for iron growth on a variety of
substrates.Comment: 11 pages, RevTeX,4 tar'd,compressed, uuencoded Postscript figure
Twisted mass fermions: neutral pion masses from disconnected contributions
Twisted mass fermions allow light quarks to be explored but with the
consequence that there are mass splittings, such as between the neutral and
charged pion. Using a direct calculation of the connected neutral pion
correlator and stochastic methods to evaluate the disconnected correlations, we
determine the neutral pion mass. We explore the dependence on lattice spacing
and quark mass in quenched QCD. For dynamical QCD, we determine the sign of the
splitting which is linked, via chiral PT, to the nature of the phase transition
at small quark mass.Comment: 6 pages, poster (hadron spectrum and quark masses) at Lattice
2005,Dublin, July 25-3
Direct simulation of ion beam induced stressing and amorphization of silicon
Using molecular dynamics (MD) simulation, we investigate the mechanical
response of silicon to high dose ion-irradiation. We employ a realistic and
efficient model to directly simulate ion beam induced amorphization. Structural
properties of the amorphized sample are compared with experimental data and
results of other simulation studies. We find the behavior of the irradiated
material is related to the rate at which it can relax. Depending upon the
ability to deform, we observe either the generation of a high compressive
stress and subsequent expansion of the material, or generation of tensile
stress and densification. We note that statistical material properties, such as
radial distribution functions are not sufficient to differentiate between
different densities of amorphous samples. For any reasonable deformation rate,
we observe an expansion of the target upon amorphization in agreement with
experimental observations. This is in contrast to simulations of quenching
which usually result in denser structures relative to crystalline Si. We
conclude that although there is substantial agreement between experimental
measurements and most simulation results, the amorphous structures being
investigated may have fundamental differences; the difference in density can be
attributed to local defects within the amorphous network. Finally we show that
annealing simulations of our amorphized samples can lead to a reduction of high
energy local defects without a large scale rearrangement of the amorphous
network. This supports the proposal that defects in amorphous silicon are
analogous to those in crystalline silicon.Comment: 13 pages, 12 figure
Envelope structure of deeply embedded young stellar objects in the Serpens Molecular Cloud
Aperture synthesis and single-dish (sub) millimeter molecular lines and
continuum observations reveal in great detail the envelope structure of deeply
embedded young stellar objects (SMM1, SMM2, SMM3, SMM4) in the densely
star-forming Serpens Molecular Cloud. Resolved millimeter continuum emission
constrains the density structure to a radial power law with index -2.0 +/- 0.5,
and envelope masses of 8.7, 3.0, and 5.3 M_sol for SMM1, SMM3, and SMM4. The
core SMM2 does not seem to have a central condensation and may not have formed
a star yet. The molecular line observations can be described by the same
envelope model, if an additional, small amount of warm (100 K) material is
included. This probably corresponds to the inner few hundred AU of the envelope
were the temperature is high. In the interferometer beam, the molecular lines
reveal the inner regions of the envelopes, as well as interaction of the
outflow with the surrounding envelope. Bright HCO+ and HCN emission outlines
the cavities, while SiO and SO trace the direct impact of the outflow on
ambient gas. Taken together, these observations provide a first comprehensive
view of the physical and chemical structure of the envelopes of deeply embedded
young stellar objects in a clustered environment on scales between 1000 and
10,000 AU.Comment: 46 pages, incl. 12 postscript figures, uses ApJ latex and psfig
macro
Lattice Gauge Theory -- Present Status
Lattice gauge theory is our primary tool for the study of non-perturbative
phenomena in hadronic physics. In addition to giving quantitative information
on confinement, the approach is yielding first principles calculations of
hadronic spectra and matrix elements. After years of confusion, there has been
significant recent progress in understanding issues of chiral symmetry on the
lattice. (Talk presented at HADRON 93, Como, Italy, June 1993.)Comment: 11 pages, BNL-4946
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