Assessing Optical and Electrical Properties of Highly Active IrO_x Catalysts for the Electrochemical Oxygen Evolution Reaction via Spectroscopic Ellipsometry

Efficient water electrolysis requires highly active electrodes. The activity of corresponding catalytic coatings strongly depends on material properties such as film thickness, crystallinity, electrical conductivity, and chemical surface speciation. Measuring these properties with high accuracy in vacuum-free and non-destructive methods facilitates the elucidation of structure–activity relationships in realistic environments. Here, we report a novel approach to analyze the optical and electrical properties of highly active oxygen evolution reaction (OER) catalysts via spectroscopic ellipsometry (SE). Using a series of differently calcined, mesoporous, templated iridium oxide films as an example, we assess the film thickness, porosity, electrical resistivity, electron concentration, electron mobility, and interband and intraband transition energies by modeling of the optical spectra. Independently performed analyses using scanning electron microscopy, energy-dispersive X-ray spectroscopy, ellipsometric porosimetry, X-ray reflectometry, and absorption spectroscopy indicate a high accuracy of the deduced material properties. A comparison of the derived analytical data from SE, resonant photoemission spectroscopy, X-ray absorption spectroscopy, and X-ray photoelectron spectroscopy with activity measurements of the OER suggests that the intrinsic activity of iridium oxides scales with a shift of the Ir 5d t2g sub-level and an increase of p–d interband transition energies caused by a transition of μ1-OH to μ3-O species

The electronic structure of iridium oxide electrodes active in water splitting

Iridium oxide based electrodes are among the most promising candidates for electrocatalyzing the oxygen evolution reaction, making it imperative to understand their chemical/electronic structure. However, the complexity of iridium oxide's electronic structure makes it particularly difficult to experimentally determine the chemical state of the active surface species. To achieve an accurate understanding of the electronic structure of iridium oxide surfaces, we have combined synchrotron-based X-ray photoemission and absorption spectroscopies with ab initio calculations. Our investigation reveals a pre-edge feature in the O K-edge of highly catalytically active X-ray amorphous iridium oxides that we have identified as O 2p hole states forming in conjunction with IrIII. These electronic defects in the near-surface region of the anionic and cationic framework are likely critical for the enhanced activity of amorphous iridium oxides relative to their crystalline counterparts

Aircraft and technology for low noise short take-off and landing

This paper discusses characteristic multi-disciplinary issues related to quiet short take-off and landing for civil transport aircraft with a typical short to medium range mission. The work reported here is focussing on the noise aspects and is embedded in the collaborative research centre CRC880 in Braunschweig, Germany. This long term aircraft Research initiative focusses on a new transport aircraft segment for operation on airports with shorter runway length in commercial air transport. This calls for a community-friendly aircraft designed for operations much closer to the home of its passengers than today. This Scenario sets challenging, seemingly contradictory aircraft technology requirements, namely those for extreme lift augmentation at low noise. The Research Centre CRC880 has therefore devised a range of technology projects that aim at significant noise reductions and at the generation of e�cffient and flexible high lift. The research also addresses flight Dynamics of aircraft at takeoff and landing. It is envisaged that in general significant noise reduction -compared to a reference turbofan driven aircraft of year 2000 technology- necessarily requires component noise reduction in combination with a low noise a/c concept. Results are presented from all the acoustics related projects of CRC880 which cover the aeroacoustic simulation of the source noise reduction by flow permeable materials, the characterization, development, manufacturing and operation of (porous) materials especially tailored to aeroacoustics, new UHBR turbofan arrangements for minimum exterior noise due to acoustic shielding as well as the prediction of jet noise vibration excitation of cabin noise by UHBR engines compared to conventional turbofans at cruise