9,107 research outputs found
Sulfur loss from subducted altered oceanic crust and implications for mantle oxidation
© The Author(s), [year]. This article is distributed under the terms of the Creative Commons Attribution License. The definitive version was published in Walters, J. B., Cruz-Uribe, A. M., & Marschall, H. R. Sulfur loss from subducted altered oceanic crust and implications for mantle oxidation. Geochemical Perspectives Letters, 13, (2020): 36-41, doi:10.7185/geochemlet.2011.Oxygen fugacity (fO2) is a controlling factor of the physics of Earth’s mantle; however, the mechanisms driving spatial and secular changes in fO2 associated with convergent margins are highly debated. We present new thermodynamic models and petrographic observations to predict that oxidised sulfur species are produced during the subduction of altered oceanic crust. Sulfur loss from the subducting slab is a function of the protolith Fe3+/ΣFe ratio and subduction zone thermal structure, with elevated sulfur fluxes predicted for oxidised slabs in cold subduction zones. We also predict bi-modal release of sulfur-bearing fluids, with a low volume shallow flux of reduced sulfur followed by an enhanced deep flux of sulfate and sulfite species, consistent with oxidised arc magmas and associated copper porphyry deposits. The variable SOx release predicted by our models both across and among active margins may introduce fO2 heterogeneity to the upper mantle.We thank James Connolly for modelling support and Peter van Keken for providing updated P–T paths for the Syracuse et al. (2010) models. The manuscript benefited from the editorial handling by Helen Williams and from constructive reviews of Maryjo Brounce, Katy Evans, and an anonymous reviewer. JBW acknowledges Fulbright and Chase Distinguished Research fellowships. This work was supported by NSF grant EAR1725301 awarded to AMC
Quantum dynamics of the avian compass
The ability of migratory birds to orient relative to the Earth's magnetic
field is believed to involve a coherent superposition of two spin states of a
radical electron pair. However, the mechanism by which this coherence can be
maintained in the face of strong interactions with the cellular environment has
remained unclear. This Letter addresses the problem of decoherence between two
electron spins due to hyperfine interaction with a bath of spin 1/2 nuclei.
Dynamics of the radical pair density matrix are derived and shown to yield a
simple mechanism for sensing magnetic field orientation. Rates of dephasing and
decoherence are calculated ab initio and found to yield millisecond coherence
times, consistent with behavioral experiments
Sounds From The Ringing Rocks
https://digitalcommons.library.umaine.edu/mmb-ps/1881/thumbnail.jp
High Harmonic Generation in SF: Raman-excited Vibrational Quantum Beats
In a recent experiment (N. Wagner et al., PNAS v103, p13279) on SF, a
high-harmonic generating laser pulse is preceded by a pump pulse which
stimulates Raman-active modes in the molecule. Varying the time delay between
the two pulses modulates high harmonic intensity, with frequencies equal to the
vibration frequencies of the Raman-active modes. We propose an explanation of
this modulation as a quantum interference between competing pathways that occur
via adjacent vibrational states of the molecule. The Raman and high harmonic
processes act as beamsplitters, producing vibrational quantum beats among the
Raman-active vibrational modes that are excited by the first pulse. We
introduce a rigorous treatment of the electron-ion recombination process and
the effect of the ionic Coulomb field in the electron propagation outside the
molecule, improving over the widely-used three-step model.Comment: submitted to PR
The effect of bedrest on various parameters of physiological function. part v- dietary requirements
Effect of bedrest on various parameters of physiological function - nutritional requiremen
Extended Timed Up and Go assessment as a clinical indicator of cognitive state in Parkinson\u27s disease
Objective: To evaluate a modified extended Timed Up and Go (extended-TUG) assessment against a panel of validated clinical assessments, as an indicator of Parkinson’s disease (PD) severity and cognitive impairment.
Methods: Eighty-seven participants with idiopathic PD were sequentially recruited from a Movement Disorders Clinic. An extended-TUG assessment was employed which required participants to stand from a seated position, walk in a straight line for 7 metres, turn 180 degrees and then return to the start, in a seated position. The extended-TUG assessment duration was correlated to a panel of clinical assessments, including the Unified Parkinson’s Disease Rating Scale (MDS-UPDRS), Quality of Life (PDQ-39), Scales for Outcomes in Parkinson’s disease (SCOPA-Cog), revised Addenbrooke’s Cognitive Index (ACE-R) and Barratt’s Impulsivity Scale 11 (BIS-11).
Results: Extended-TUG time was significantly correlated to MDS-UPDRS III score and to SCOPA-Cog, ACE-R (p\u3c0.001) and PDQ-39 scores (p\u3c0.01). Generalized linear models determined the extended-TUG to be a sole variable in predicting ACE-R or SCOPA-Cog scores. Patients in the fastest extended-TUG tertile were predicted to perform 8.3 and 13.4 points better in the SCOPA-Cog and ACE-R assessments, respectively, than the slowest group. Patients who exceeded the dementia cut-off scores with these instruments exhibited significantly longer extended-TUG times.
Conclusions: Extended-TUG performance appears to be a useful indicator of cognition as well as motor function and quality of life in PD, and warrants further evaluation as a first line assessment tool to monitor disease severity and response to treatment. Poor extended-TUG performance may identify patients without overt cognitive impairment form whom cognitive assessment is needed
Forbidden ordinal patterns in higher dimensional dynamics
Forbidden ordinal patterns are ordinal patterns (or `rank blocks') that
cannot appear in the orbits generated by a map taking values on a linearly
ordered space, in which case we say that the map has forbidden patterns. Once a
map has a forbidden pattern of a given length , it has forbidden
patterns of any length and their number grows superexponentially
with . Using recent results on topological permutation entropy, we study in
this paper the existence and some basic properties of forbidden ordinal
patterns for self maps on n-dimensional intervals. Our most applicable
conclusion is that expansive interval maps with finite topological entropy have
necessarily forbidden patterns, although we conjecture that this is also the
case under more general conditions. The theoretical results are nicely
illustrated for n=2 both using the naive counting estimator for forbidden
patterns and Chao's estimator for the number of classes in a population. The
robustness of forbidden ordinal patterns against observational white noise is
also illustrated.Comment: 19 pages, 6 figure
Towards an ecological network for the Carpathians
The Carpathian Biodiversity Information System (CBIS) and the proposal for an ecological network for the eastern part of the Carpathians are the two main outcomes of the project funded by the BBI Matra program of the Dutch government. This brochure presents information on how the CBIS was designed, and how the data stored can be retrieved and used. It also clarifies how the CBIS data were used to design the ecological network and, last but not least, it offers recommendations for the use of the proposed ecological network in supporting sustainable developmentin the Carpathians. Due to funding restrictions, the project focused on three east Carpathian countries: Romania, Serbia and Ukraine, which together host the largest area of the Carpathians (Fig. 2). Geographically, the Eastern Carpathians also include parts of the Carpathians located in Poland and Slovakia. Data collection in the Western Carpathians (Czech Republic, Poland, Slovakia and Hungary) will be completed by 2010 and is funded by a parallel project
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