Evolution of crystalline electric field effects, superconductivity, and heavy fermion behavior in the specific heat of Pr(Os1−x_{1-x}Rux_x)4_4Sb12_{12}

Specific heat $C(T)$ measurements were made on single crystals of the superconducting filled skutterudite series Pr(Os$_{1-x}$Ru$_x$)$_4$Sb$_{12}$ down to 0.6 K. Crystalline electric field fits in the normal state produced parameters which were in agreement with previous measurements. Bulk superconductivity was observed for all values of the Ru concentration $x$ with transition temperatures consistent with previous experiments, confirming a minimum in $T_{c}$ at $x=0.6$. The $C(T)$ data below $T_{c}$ appear to be more consistent with power law behavior for $x=0$ (PrOs$_4$Sb$_{12}$), and with exponential behavior for $0.05 \leq x \leq 0.2$. An enhanced electronic specific heat coefficient $\gamma$ was observed for $x \leq 0.4$, further supporting $x \simeq 0.6$ as a critical concentration where the physical properties abruptly change. Significant enhancement of $\Delta C/T_{c}$ above the weak coupling value was only observed for $x=0$ and $x=0.05$.Comment: 16 pages, 5 figures, submitted to Physical Review B. v2: text added and figures modifie

Microprocessor Controller in Closed Loop Angular Position Servo System P.

Integrated command, control and copmunication systems are based on the use of computers for digital data processing. The weapon system platforms like missile launchers are given input command for accurate and quick positioning in azimuth and elevation. The technologies of sensors, signal conditioning and associated solid state electronics have moved from analog to digital. Therefore, a position controller has to be designed around a microprocessor in embedded form for usage in such servo control systems. This paper highlights the basic approach for such design and problems which need to be tackled during actual implementation

Reflection confocal nanoscopy using a super-oscillatory lens

A Superoscillatory lens (SOL) is known to produce a sub-diffraction hotspot which is useful for high-resolution imaging. However, high-energy rings called sidelobes coexist with the central hotspot. Additionally, SOLs have not yet been directly used to image reflective objects due to low efficiency and poor imaging properties. We propose a novel reflection confocal nanoscope which mitigates these issues by relaying the SOL intensity pattern onto the object and use conventional optics for detection. We experimentally demonstrate super-resolution by imaging double bars with 330 nm separation using a 632.8 nm excitation and a 0.95 NA objective. We also discuss the enhanced contrast properties of the SOL nanoscope against a laser confocal microscope, and the degradation of performance while imaging large objects.Comment: 17 pages, 15 figures, supplementary include

Was the Cosmic Web of Protogalactic Material Permeated by Lobes of Radio Galaxies During the Quasar Era?

Evidence for extended active lifetimes (> 10^8 yr) for radio galaxies implies that many large radio lobes were produced during the `quasar era', 1.5 < z < 3, when the comoving density of radio sources was 2 -- 3 dex higher than the present level. However, inverse Compton losses against the intense microwave background substantially reduce the ages and numbers of sources that are detected in flux-limited surveys. The realization that the galaxy forming material in those epochs was concentrated in filaments occupying a small fraction of the total volume then leads to the conclusion that radio lobes permeated much of the volume occupied by the protogalactic material during that era. The sustained overpressure in these extended lobes is likely to have played an important role in triggering the high inferred rate of galaxy formation at z > 1.5 and in the magnetization of the cosmic network of filaments.Comment: 5 pages, 0 figures, submitted to ApJ Letters; uses emulateapj

A NEW VALIDATED THIRD ORDER DERIVATIVE SPECTROSCOPIC METHOD FOR SIMULTANEOUS ESTIMATION OF METOPROLOL SUCCINATE AND RAMIPRIL IN TABLET DOSAGE FORM

Objective: The objective of the present work is to develop and validate a new UV derivative spectrophotometric method for simultaneous estimation of metoprolol succinate and ramipril in methanol: water (50:50v/v). Methods: “Zero crossing technique” was chosen for quantitative determination. The zero-crossing points (ZCP’s) were found to be 209 nm where metoprolol succinate was quantified and 211 nm where ramipril was quantified. This method was then subjected to accuracy, linearity, sensitivity and reproducibility according to ICH guidelines to ensure and confirm its validity. Results: The method was found to be obeying Beer’s law in the range of 10-50 µg/ml and 5-25 µg/ml for metoprolol succinate and ramipril, respectively. The % recoveries were observed between the range of 99.2-100.2 for metoprolol succinate and 99.57-99.86 for ramipril. The intra-day and inter-day results showed reproducibility. Conclusion: It can be concluded that the developed third-order UV derivative spectroscopic method for the simultaneous determination of metoprolol succinate and ramiprilcan be recommended for routine quantitative analysis

Understanding BL Lac objects Structural & kinematic mode changes in the BL Lac object PKS 0735+178

Context. We present evidence that parsec-scale jets in BL Lac objects may be significantly distinct in kinematics from their counterparts in quasars. We argued this previously for the BL lac sources 1803+784 and 0716+714, report here a similar pattern for another well-known BL Lac object, PKS 0735+178, whose nuclear jet is found to exhibit kinematics atypical of quasars. Aims. A detailed study of the jet components' motion reveals that the standard AGN paradigm of apparent superluminal motion does not always describe the kinematics in BL Lac objects. We study 0735+178 here to augment and improve the understanding of the peculiar motions in the jets of BL Lac objects as a class. Methods. We analyzed 15 GHz VLBA (Very Long Baseline Array) observations (2cm/MOJAVE survey) performed at 23 epochs between 1995.27 and 2008.91. Results. We found a drastic structural mode change in the VLBI jet of 0735+178, between 2000.4 and 2001.8 when its twice sharply bent trajectory turned into a linear shape.We further found that this jet had undergone a similar transition sometime between December 1981 and June 1983. A mode change, occurring in the reverse direction (between mid-1992 and mid-1995) has already been reported in the literature. These structural mode changes are found to be reflected in changed kinematical behavior of the nuclear jet, manifested as an apparent superluminal motion and stationarity of the radio knots. In addition, we found the individual mode changes to correlate in time with the maxima in the optical light curve. The last two transitions occurred before a (modest) radio flare. The behavior of this pc-scale jet appears to favor a scenario involving non-ballistic motions of the radio knots, produced by the precession of a continuous jet within the ambient medium.Comment: Accepted for publication in A&A (Abstract reduced for astro-ph

Lipid-dependent conformational landscape of the ErbB2 growth factor receptor dimers

Altered lipid metabolism has been linked to cancer development and progression. Several roles have been attributed to the increased saturation and length of lipid acyl tails observed in tumors, but its effect on signaling receptors is still emerging. In this work, we have analyzed the lipid dependence of the ErbB2 growth factor receptor dimerization that plays an important role in the pathogenesis of breast cancer. We have performed coarse-grain ensemble molecular dynamics simulations to comprehensively sample the ErbB2 monomer-dimer association. Our results indicate a dynamic dimer state with a complex conformational landscape that is modulated with increasing lipid tail length. We resolve the native N-terminal "active" and C-terminal "inactive" conformations in all membrane compositions. However, the relative population of the N-terminal and C-terminal conformers is dependent on length of the saturated lipid tails. In short-tail membranes, additional non-specific dimers are observed which are reduced or absent in long-tailed bilayers. Our results indicate that the relative population as well as the structure of the dimer state is modulated by membrane composition. We have correlated these differences to local perturbations of the membrane around the receptor. Our work is an important step in characterizing ErbB dimers in healthy and diseased states and emphasize the importance of sampling lipid dynamics in understanding receptor association

Chemical Stabilisation of Sand Part IX: Orthophthalate type Unsaturated Polyester Resin for Inducing Fast setting Behaviour and High Strength

Polymer concrete composites have been made from orthophthalate-type unsaturated polyester resin, methyl ethyl ketone peroxide as initiator, cobalt naphthenate as accelerator and desert sand as filler. Composites preferred using resin (10-25 per cent), initiator (4 per cent) and accelerator (2 per cent) with representative desert sand samples of different particle sizes (0.2-0.02 mm, 2-0.2 mm and 4-2 mm) as filler recorded unconfined compression strength ranging from 4 to 442 kg/cm/sup 2/ after curing at 50 degree centigrade in an oven for 0.5-24 h. Using coarse and fine sand samples with 10 and 15 per cent resin systems the maximum strength of 391 and 326 kg/cm/sup 2/ respectively was attained after 2 h of curing at 50 degree centigrade. The fast setting resin system with strength in this range is quite adequate for the construction of chemically stabilised surfaces, which withstand trafficability of vehicles, operation of helicopters and aircraft's requiring a maximum strength up to 275 kg/cm/sup 2/. These composites may prove useful for rapid repair of roads, helipads and runways damaged during operational activities. A mathematical model has been developed for predicting resin percentage needed for obtaining composite material of requisite strength. The observed and model predicted values have been found to show close agreement

Ferromagnetic Ordering in CeIr2B2: Transport, magnetization, specific heat and NMR studies

We present a complete characterization of ferromagnetic system CeIr2B2 using powder x-ray diffraction XRD, magnetic susceptibility chi(T), isothermal magnetization M(H), specific heat C(T), electrical resistivity rho(T,H), and thermoelectric power S(T) measurements. Furthermore 11B NMR study was performed to probe the magnetism on a microscopic scale. The chi(T), C(T) and rho(T) data confirm bulk ferromagnetic ordering with Tc = 5.1 K. Ce ions in CeIr2B2 are in stable trivalent state. Our low-temperature C(T) data measured down to 0.4 K yield Sommerfeld coefficient gamma = 73(4) mJ/molK2 which is much smaller than the previously reported value of gamma = 180 mJ/molK2 deduced from the specific heat measurement down to 2.5 K. For LaIr2B2 gamma = 6(1) mJ/molK2 which implies the density of states at the Fermi level D(EF) = 2.54 states/(eV f.u.) for both spin directions. The renormalization factor for quasi-particle density of states and hence for quasi-particle mass due to 4f correlations in CeIr2B2 is 12. The Kondo temperature TK ~ 4 K is estimated from the jump in specific heat of CeIr2B2 at Tc. Both C(T) and rho(T) data exhibit gapped-magnon behavior in magnetically ordered state with an energy gap Eg ~ 3.5 K. The rho data as a function of magnetic field H indicate a large negative magnetoresistance (MR) which is highest for T = 5 K.While at 5 K the negative MR keeps on increasing up to 10 T, at 2 K an upturn is observed near H = 3.5 T. On the other hand, the thermoelectric power data have small absolute values (S ~ 7 {\mu}V/K) indicating a weak Kondo interaction. A shoulder in S(T) at about 30 K followed by a minimum at ~ 10 K is attributed to crystal electric field (CEF) effects and the onset of magnetic ordering. 11B NMR line broadening provides strong evidence of ferromagnetic correlations below 40 K.Comment: 10 pages, 11 figure