Structural Studies of Nonionic Dodecanol Ethoxylates at the Oil–Water Interface: Effect of Increasing Head Group Size

The conformation of charged surfactants at the oil-water interface was recently reported. With the aim to assess the role of the head group size on the conformation of the adsorbed layer, we have extended these studies to a series of non-ionic dodecanol ethoxylate surfactants (C12En, ethylene oxide units n from 6 to 12). The study was performed using neutron reflectometry to enable maximum sensitivity to buried interfaces. Similarly to charged surfactants, the interface was found to be broader and rougher compared to the air-water interface. Irrespectively of the head group size, the tail group region was found to assume a staggered conformation. The conformations of the head group were found to be significantly different compared to the air-water interface, moving from a globular to an almost fully extended conformation at the oil-water interface. The stretching of the head groups is attributed to the presence of some hexadecane oil molecules, which may penetrate all the way to this region. It is proposed here that the presence of the oil, which can efficiently solvate the surfactant tail groups, plays a key role in the conformation of the adsorbed layer and is responsible for the broadening of the interface

Planting on Rural School Grounds

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Development of novel multiplex microsatellite polymerase chain reactions to enable high-throughput population genetic studies of Schistosoma haematobium

© 2015 Webster et al. Open Access This article is distributed under the terms of the Creative Commons Attribution 4.0 International License (http://creativecommons.org/licenses/by/4.0/), which permits unrestricted use, distribution, and reproduction in any medium, provided you give appropriate credit to the original author(s) and the source, provide a link to the Creative Commons license, and indicate if changes were made. The Creative Commons Public Domain Dedication waiver (http://creativecommons.org/publicdomain/zero/1.0/) applies to the data made available in this article, unless otherwise stated. The attached file is the published version of the article

Quasar-galaxy associations

There is controversy about the measurement of statistical associations between bright quasars and faint, presumably foreground galaxies. We look at the distribution of galaxies around an unbiased sample of 63 bright, moderate redshift quasars using a new statistic based on the separation of the quasar and its nearest neighbour galaxy. We find a significant excess of close neighbours at separations less than about 10 arcsec which we attribute to the magnification by gravitational lensing of quasars which would otherwise be too faint to be included in our sample. About one quarter to one third of the quasars are so affected although the allowed error in this fraction is large.Comment: uuencoded Postscript file (including figures and tables), SUSSEX-AST 94/8-

Surfactant mixtures at the oil–water interface

NOTICE: this is the author’s version of a work that was accepted for publication in Journal of Colloid and Interface Science. Changes resulting from the publishing process, such as peer review, editing, corrections, structural formatting, and other quality control mechanisms may not be reflected in this document. Changes may have been made to this work since it was submitted for publication. A definitive version was subsequently published in JOURNAL OF COLLOID AND INTERFACE SCIENCE, VOL 398, (2013) DOI 10.1016/j.jcis.2013.01.06

Scalable simultaneous multi-qubit readout with 99.99% single-shot fidelity

We describe single-shot readout of a trapped-ion multi-qubit register using space and time-resolved camera detection. For a single qubit we measure 0.9(3)x10^{-4} readout error in 400us exposure time, limited by the qubit's decay lifetime. For a four-qubit register (a "qunybble") we measure an additional error of only 0.1(1)x10^{-4} per qubit, despite the presence of 4% optical cross-talk between neighbouring qubits. A study of the cross-talk indicates that the method would scale with negligible loss of fidelity to ~10000 qubits at a density <~1 qubit/um^2, with a readout time ~1us/qubit.Comment: 4 pages, 3 figures; simulations added to fig.3, with some further text and figure revisions. Main results unchanged