Changes in hydrodynamic, structural and geochemical properties in carbonate rock samples due to reactive transport

Reactive transport plays an important role in the development of a wide range of both anthropic and natural processes affecting geological media. To predict the consequences of reactive transport processes on structural and hydrodynamic properties of a porous media at large time and spatial scales, numerical modeling is a powerful tool. Nevertheless, such models, to be realistic, need geochemical, structural and hydrodynamic data inputs representative of the studied reservoir or material. Here, we present an experimental study coupling traditional laboratory measurements and percolation experiments in order to obtain the parameters that define rock heterogeneity, which can be altered during the percolation of a reactive fluid. In order to validate the experimental methodology and identify the role of the initial heterogeneities on the localization of the reactive transport processes, we used three different limestones with different petrophysical characteristics. We tracked the changes of geochemical, structural and hydrodynamic parameters in these samples induced by the percolation of an acid fluid by measuring, before and after the percolation experiment, petrophysical and hydrodynamic properties of the rocks.Peer ReviewedPostprint (published version

Permeability evolution in sandstone due to injection of CO2-saturated brine or supercritical CO2 at reservoir conditions

We measured the change in permeability of two selected sandstones (Berea, Fonteinebleau) due to injection of CO2-saturated (“live”) brine, unsaturated (“dead”) brine or supercritical (sc) CO2 at reservoir conditions. We found that the permeability did not significantly change in a clean sandstone consisting of pure quartz (Fonteinemebleau) due to live or dead brine injection, although permeability changed due to scCO2 injection by ~23%. The permeability in the Berea sandstone, however, changed due to live or dead brine injection, by up to 35%; this permeability reduction in Berea sandstone was likely caused by fines release and subsequent pore throat plugging as the damage was more significant at higher injection rates. We expect that this phenomenon – i.e. rock permeability reduction due to CO2 injection into the formation – can have a significant and detrimental influence on CO2 injectivity, which would be reduced accordingly

Flow simulation of artificially induced microfractures using digital rock and lattice boltzmann methods

Microfractures have great significance in the study of reservoir development because they are an effective reserving space and main contributor to permeability in a large amount of reservoirs. Usually, microfractures are divided into natural microfractures and induced microfractures. Artificially induced rough microfractures are our research objects, the existence of which will affect the fluid-flow system (expand the production radius of production wells), and act as a flow path for the leakage of fluids injected to the wells, and even facilitate depletion in tight reservoirs. Therefore, the characteristic of the flow in artificially induced fractures is of great significance. The Lattice Boltzmann Method (LBM) was used to calculate the equivalent permeability of artificially induced three-dimensional (3D) fractures. The 3D box fractal dimensions and porosity of artificially induced fractures in Berea sandstone were calculated based on the fractal theory and image-segmentation method, respectively. The geometrical parameters (surface roughness, minimum fracture aperture, and mean fracture aperture), were also calculated on the base of digital cores of fractures. According to the results, the permeability lies between 0.071–3.759 (dimensionless LB units) in artificially induced fractures. The wide range of permeability indicates that artificially induced fractures have complex structures and connectivity. It was also found that 3D fractal dimensions of artificially induced fractures in Berea sandstone are between 2.247 and 2.367, which shows that the artificially induced fractures have the characteristics of self-similarity. Finally, the following relations were studied: (a) exponentially increasing permeability with increasing 3D box fractal dimension, (b) linearly increasing permeability with increasing square of mean fracture aperture, (c) indistinct relationship between permeability and surface roughness, and (d) linearly increasing 3D box fractal dimension with increasing porosity

Time-lapse cross-hole electrical resistivity tomography (CHERT) for monitoring seawater intrusion dynamics in a Mediterranean aquifer

Surface electrical resistivity tomography (ERT) is a widely used tool to study seawater intrusion (SWI). It is noninvasive and offers a high spatial coverage at a low cost, but its imaging capabilities are strongly affected by decreasing resolution with depth. We conjecture that the use of CHERT (cross-hole ERT) can partly overcome these resolution limitations since the electrodes are placed at depth, which implies that the model resolution does not decrease at the depths of interest. The objective of this study is to test the CHERT for imaging the SWI and monitoring its dynamics at the Argentona site, a well-instrumented field site of a coastal alluvial aquifer located 40¿km NE of Barcelona. To do so, we installed permanent electrodes around boreholes attached to the PVC pipes to perform time-lapse monitoring of the SWI on a transect perpendicular to the coastline. After 2 years of monitoring, we observe variability of SWI at different timescales: (1) natural seasonal variations and aquifer salinization that we attribute to long-term drought and (2) short-term fluctuations due to sea storms or flooding in the nearby stream during heavy rain events. The spatial imaging of bulk electrical conductivity allows us to explain non-monotonic salinity profiles in open boreholes (step-wise profiles really reflect the presence of freshwater at depth). By comparing CHERT results with traditional in situ measurements such as electrical conductivity of water samples and bulk electrical conductivity from induction logs, we conclude that CHERT is a reliable and cost-effective imaging tool for monitoring SWI dynamics.This work was funded by the project CGL2016-77122-C2-1-R/2-R of the Spanish Government. This project also received funding from the European Commission, Horizon 2020 research and innovation programme (Marie Sklodowska-Curie (grant no. 722028)). The author Albert Folch is a Serra Húnter Fellow.Peer ReviewedPostprint (published version

Time-lapse cross-hole electrical resistivity tomography (CHERT) for monitoring seawater intrusion dynamics in a Mediterranean aquifer

Surface electrical resistivity tomography (ERT) is a widely used tool to study seawater intrusion (SWI). It is noninvasive and offers a high spatial coverage at a low cost, but its imaging capabilities are strongly affected by decreasing resolution with depth. We conjecture that the use of CHERT (cross-hole ERT) can partly overcome these resolution limitations since the electrodes are placed at depth, which implies that the model resolution does not decrease at the depths of interest. The objective of this study is to test the CHERT for imaging the SWI and monitoring its dynamics at the Argentona site, a well-instrumented field site of a coastal alluvial aquifer located 40 km NE of Barcelona. To do so, we installed permanent electrodes around boreholes attached to the PVC pipes to perform time-lapse monitoring of the SWI on a transect perpendicular to the coastline. After 2 years of monitoring, we observe variability of SWI at different timescales: (1) natural seasonal variations and aquifer salinization that we attribute to long-term drought and (2) short-term fluctuations due to sea storms or flooding in the nearby stream during heavy rain events. The spatial imaging of bulk electrical conductivity allows us to explain non-monotonic salinity profiles in open boreholes (step-wise profiles really reflect the presence of freshwater at depth). By comparing CHERT results with traditional in situ measurements such as electrical conductivity of water samples and bulk electrical conductivity from induction logs, we conclude that CHERT is a reliable and cost-effective imaging tool for monitoring SWI dynamics