Memristive Devices for Quantum Metrology

As a consequence of the redefinition of the International System of Units (SI), where units are defined in terms of fundamental physical constants, memristive devices represent a promising platform for quantum metrology. Coupling ionics with electronics, memristive devices can exhibit conductance levels quantized in multiples of the fundamental quantum of conductance G(0) = 2e(2)/h. Since the fundamental quantum of conductance G(0) is related only to physical constants that assume fixed value in the revised SI, memristive devices can be exploited for the practical realization of a quantum-based resistance standard that, differently from quantum-Hall based devices conventionally adopted as resistance standards, can operate in different ambient conditions (air, vacuum, harsh environment), in a wide range of temperatures and without the need of an applied magnetic field In this work, the possibility of using memristive devices for quantum metrology is critically discussed, based on recent experimental and theoretical advances on quantum conductance phenomena reported in literature. Thanks to the high operational speed, high scalability down to the nanometer scale, and CMOS compatibility, memristive devices allow on-chip implementation of a resistance standard required for the realization of self-calibrating electrical systems and equipment with zero-chain traceability in accordance with the revised SI

Liquid Phase Infiltration of Block Copolymers

Novel materials with defined composition and structures at the nanoscale are increasingly desired in several research fields spanning a wide range of applications. The development of new approaches of synthesis that provide such control is therefore required in order to relate the material properties to its functionalities. Self-assembling materials such as block copolymers (BCPs), in combination with liquid phase infiltration (LPI) processes, represent an ideal strategy for the synthesis of inorganic materials into even more complex and functional features. This review provides an overview of the mechanism involved in the LPI, outlining the role of the different polymer infiltration parameters on the resulting material properties. We report newly developed methodologies that extend the LPI to the realisation of multicomponent and 3D inorganic nanostructures. Finally, the recently reported implementation of LPI into different applications such as photonics, plasmonics and electronics are highlighted

Hyperbolic Metamaterials via Hierarchical Block Copolymer Nanostructures

Hyperbolic metamaterials (HMMs) offer unconventional properties in the field of optics, enabling opportunities for confinement and propagation of light at the nanoscale. In‐plane orientation of the optical axis, in the direction coinciding with the anisotropy of the HMMs, is desirable for a variety of novel applications in nanophotonics and imaging. Here, a method for creating localized HMMs with in‐plane optical axis, based on block copolymer (BCP) blend instability, is introduced. The dewetting of BCP thin film over topographically defined substrates generates droplets composed of highly ordered lamellar nanostructures in hierarchical configuration. The hierarchical nanostructures represent a valuable platform for the subsequent pattern transfer into a Au/air HMM, exhibiting hyperbolic behavior in a broad wavelength range in the visible spectrum. A computed Purcell factor as high as 32 at 580 nm supports the strong reduction in the fluorescence lifetime of defects in nanodiamonds placed on top of the HMM

Ultrathin random copolymer-grafted layers for block copolymer self-assembly

Hydroxyl-terminated P(S-r-MMA) random copolymers (RCPs) with molecular weights (Mn) from 1700 to 69000 and a styrene unit fraction of approximately 61% were grafted onto a silicon oxide surface and subsequently used to study the orientation of nanodomains with respect to the substrate, in cylinder-forming PS-b-PMMA block copolymer (BCP) thin films. When the thickness (H) of the grafted layer is greater than 5-6 nm, a perpendicular orientation is always observed because of the efficient decoupling of the BCP film from the polar SiO2 surface. Conversely, if H is less than 5 nm, the critical thickness of the grafted layer, which allows the neutralization of the substrate and promotion of the perpendicular orientation of the nanodomains in the BCP film, is found to depend on the Mn of the RCP. In particular, when Mn = 1700, a 2.0 nm thick grafted layer is sufficient to promote the perpendicular orientation of the PMMA cylinders in the PS-b-PMMA BCP film. A proximity shielding mechanism of the BCP molecules from the polar substrate surface, driven by chain stretching of the grafted RCP molecules, is proposed

Comparison of field measurement methods of nitrous oxide soil emissions: from the chamber to the vial

Nitrous oxide (N2O) is a greenhouse gas that contributes substantially to global climate change. The N2O soil emissions have a large uncertainty because of its low atmospheric concentration levels and enormous spatial and temporal variability, which hinders its correct field measurement. For this reason, there are many papers focused on improving the N2O measurements in the field, which focus on different parts of the measurement process. However, no studies have focused on determining the appropriate method, in terms of simplicity and precision, for the sample extraction from inside of the chambers and its transfer to the storage vials, although this step is key in the sampling process. This study aimed to assess and compare the accuracies of three simple and economical methods in transfer soil emitted N2O from inside of the chambers to the vials. For this, a highly accepted method (vacuum by manual pump) and two simpler alternative methods (gas exchange by displacement and vacuum by syringe) were compared. Thirty static chambers were assessed with the quantified N2O emission values varied from 0 to 450 µg m-2 h-1 of N-N2O. Out of the three assessed methods, the vacuum method through the use of a manual vacuum pump was the best to quantifying N2O soil emissions (capturing 57 % of the highest emission values), followed by the gas exchange method by displacement (30 %), and finally by the vacuum method by syringe extraction (13%).Fil: Cosentino, Vanina Rosa Noemi. Instituto Nacional de Tecnología Agropecuaria (INTA). Instituto de Suelos; Argentina. Universidad de Buenos Aires. Facultad de Agronomía. Cátedra de Fertilidad y Fertilizantes; ArgentinaFil: Romaniuk, Romina Ingrid. Instituto Nacional de Tecnología Agropecuaria (INTA). Instituto de Suelos; ArgentinaFil: Lupi, Ana Maria. Instituto Nacional de Tecnología Agropecuaria (INTA). Instituto de suelos; ArgentinaFil: Gomez, Federico. Universidad de Buenos Aires. Facultad de Agronomía. Cátedra de Fertilidad y Fertilizantes; Argentina.Fil Rimski Korsakov, Helena Universidad de Buenos Aires, Facultad de Agronomía, Ciudad Autónoma de Buenos Aires, Buenos Aires, ArgentinaFil: Alvarez, Carina Rosa. Universidad de Buenos Aires. Facultad de Agronomía; ArgentinaFil: Ciarlo, Esteban Universidad de Buenos Aires, Facultad de Agronomía, Ciudad Autónoma de Buenos Aires, Argentin

Structure and stability of 7-mercapto-4-methylcoumarin self-assembled monolayers on gold: an experimental and computational analysis

Self-assembled monolayers (SAM) of 7-mercapto-4-methylcoumarin (MMC) on a flat gold surface were studied by molecular dynamics (MD) simulations, reference-free grazing incidence X-ray fluorescence (GIXRF) and X-ray photoelectron spectroscopy (XPS), to determine the maximum monolayer density and to investigate the nature of the molecule/surface interface. In particular, the protonation state of the sulfur atom upon adsorption was analyzed, since some recent literature presented evidence for physisorbed thiols (preserving the S-H bond), unlike the common picture of chemisorbed thiyls (losing the hydrogen). MD with a specifically tailored force field was used to simulate either thiol or thiyl monolayers with increasing number of molecules, to determine the maximum dynamically stable densities. This result was refined by computing the monolayer chemical potential as a function of the density with the bennet acceptance ratio method, based again on MD simulations. The monolayer density was also measured with GIXRF, which provided the absolute quantification of the number of sulfur atoms in a dense self-assembled monolayer (SAM) on flat gold surfaces. The sulfur core level binding energies in the same monolayers were measured by XPS, fitting the recorded spectra with the binding energies proposed in the literature for free or adsorbed thiols and thiyls, to get insight on the nature of the molecular species present in the layer. The comparison of theoretical and experimental SAM densities, and the XPS analysis strongly support the picture of a monolayer formed by chemisorbed, dissociated thiyls

Influence of the long-range ordering of gold-coated Si nanowires on SERS

Controlling the location and the distribution of hot spots is a crucial aspect in the fabrication of surface-enhanced Raman spectroscopy (SERS) substrates for bio-analytical applications. The choice of a suitable method to tailor the dimensions and the position of plasmonic nanostructures becomes fundamental to provide SERS substrates with significant signal enhancement, homogeneity and reproducibility. In the present work, we studied the influence of the long-range ordering of different flexible gold-coated Si nanowires arrays on the SERS activity. The substrates are made by nanosphere lithography and metal-assisted chemical etching. The degree of order is quantitatively evaluated through the correlation length (ξ) as a function of the nanosphere spin-coating speed. Our findings showed a linear increase of the SERS signal for increasing values of ξ, coherently with a more ordered and dense distribution of hot spots on the surface. The substrate with the largest ξ of 1100 nm showed an enhancement factor of 2.6 · 103 and remarkable homogeneity over square-millimetres area. The variability of the signal across the substrate was also investigated by means of a 2D chemical imaging approach and a standard methodology for its practical calculation is proposed for a coherent comparison among the data reported in literature

Utilización de tecnología RFID/NFC para el desarrollo de un sistema de llenado selectivo de envases: industria 4.0

Se presenta un sistema de llenado selectivo de envases basado en tecnología RFID/NFC (Identificación por Radio Frecuencia / Comunicación de Campo Cercano). Con el mismo se pretende ejemplificar el uso de dispositivos de tecnología de identificación por radiofrecuencia en la trazabilidad de productos manufacturados. El sistema está formado por un dispositivo electroneumático, un controlador lógico programable, PLC por sus siglas en inglés, y por una computadora. Se detalla el hardware empleado, así como el programa del PLC y el software desarrollado.Eje: Ingeniería en Sistemas Software.Red de Universidades con Carreras en Informátic

Utilización de tecnología RFID/NFC para el desarrollo de un sistema de llenado selectivo de envases: industria 4.0

Se presenta un sistema de llenado selectivo de envases basado en tecnología RFID/NFC (Identificación por Radio Frecuencia / Comunicación de Campo Cercano). Con el mismo se pretende ejemplificar el uso de dispositivos de tecnología de identificación por radiofrecuencia en la trazabilidad de productos manufacturados. El sistema está formado por un dispositivo electroneumático, un controlador lógico programable, PLC por sus siglas en inglés, y por una computadora. Se detalla el hardware empleado, así como el programa del PLC y el software desarrollado.Eje: Ingeniería en Sistemas Software.Red de Universidades con Carreras en Informátic

Desarrollo experimental en industria 4.0: ampliación y mejoramiento de un sistema de llenado selectivo de envases con tecnología RFID/NFC

En el presente trabajo se detallan las ampliaciones y mejoras realizadas al sistema de llenado selectivo de envases basado en tecnología RFID/NFC (Identificación por Radio Frecuencia / Comunicación de Campo Cercano) presentado en el marco del WICC2018. Habiéndose logrado ejemplificar cómo las tecnologías de RFID/NFC se pueden emplear en procesos productivos, tanto para sumar inteligencia al proceso como para mejorar la trazabilidad del producto, se continuó trabajando sobre el sistema mejorando los aspectos mecánicos, incorporando una etapa de etiquetado previa y ampliando el software para permitir la trazabilidad de toda la cadena de suministros. El sistema está formado por un conjunto de elementos electroneumáticos, un controlador lógico programable, PLC por sus siglas en inglés, un módulo de expansión de entradas y salidas, sensores y por una computadora. Se detalla el hardware empleado, así como el programa del PLC y el software desarrollado.Eje: Innovación en Sistemas de Software.Red de Universidades con Carreras en Informátic