Postcritical Behavior of Cables Undergoing Two Simultaneous Galloping Modes

A nonlinear two degree-of-freedom model, describing a flexible elastic suspended cable undergoing galloping oscillations, is analyzed. By using a perturbative approach, the critical conditions occuring for different values of the aerodynamic coefficients are described. Two different type of critical conditions, corresponding to simple or double Hopf bifurcations are found. The nonlinear postcritical behavior of single taut strings in 1:1 primary internal resonance is studied through the multiple scale perturbation method. In the double Hopf bifurcation case the influence of the detuning between the critical eigenvalues on the postcritical behavior is illustrated. It is found that quasi-periodic motions, which are likely to occur in the linear field when the two critical frequencies are incommensurable, are really unstable in the nonlinear range. Therefore, the postcritical behavior of the string consists of stable periodic motions for any detuning values

Low-velocity impact behaviour of fibreglass-aluminium laminates

Low-velocity impact tests were performed on fibreglass–aluminium composites made of 2024 T3 sheets and S2-glass/epoxy prepreg layers, using an instrumented falling weight machine. For comparison purposes, similar tests were carried out on monolithic 2024 T3 sheets of equivalent thickness. In the tests, the impact speed, mass, and energy were varied, to ascertain the influence of these parameters on the material response. From the results obtained, the overall force–displacement curve only depends on the impact energy, rather than on the mass and speed separately. Further, the energy required for penetration is higher for monolithic aluminium than for the fibreglass– aluminium. However, the latter material seems to offer better performance than carbon fibre- and glass fibre-reinforced laminates in terms of penetration energy, damage resistance, and inspectability. The main failure modes of fibreglass – aluminium were assessed by both ultrasonic C-scan and chemical grinding of aluminium sheets. It was found that the energy required for first failure is very low, whereas the energy level resulting in first fibre failure is similar to that inducing first cracking in the 2024 T3 sheets. From the experimental data, simple empirical relationships were found for the calculation of maximum contact force, energy, and residual displacement as a function of the maximum displacement

On the mechanics of caldera resurgence of Ischia Island (southern Italy)

A model of caldera resurgence was applied to the Island of Ischia to explain uplift, volcanic activity and tectonics on Mount Epomeo, as well as historical seismicity and slow ground movements recorded for the past 2000 years. A two-dimensional mechanical model was utilized for the crust, which was considered to be an elastic plate overlying a laccolith. Geometric dimensions and mechanical parameters were constrained using geological, geophysical and geochemical data. We propose that a laccolith, with a diameter L of c. 10 km, and a depth of up to 1 km in the centre of the island, triggered the caldera resurgence after the Mount Epomeo Green Tuff eruption forming the caldera (55 000 a BP). A bending phase and a punched laccolith phase are thought to have caused the observed deformations in the caldera. These processes control the tectonics at the boundary of the Mount Epomeo resurgent structure, volcanic activity and dynamics of the island

Resurgence and flank failure of Mt. Epomeo, Ischia Island (Southern Italy)

Risorgenza e collasso laterale del Monte Epomeo, Isola d’Ischia Il Monte Epomeo (787 m a.s.l.), ubicato nel settore centrale dell’isola d’Ischia, mostra lo smantellamento del settore meridionale, depositi di debris e franamenti diffusi che testimoniano la natura instabile del monte. A seguito dell’eruzione ignimbritica del Tufo Verde dell’Epomeo (55.000 anni), che genera una struttura calderica (10x7 km2), inizia la risorgenza della caldera fino alla formazione del Monte Epomeo. Il sollevamento, generato dall’intrusione di un laccolite fino a circa 1 km di profondità, avrebbe determinato una forte instabilità gravitativa del blocco risorgente e prodotto uno o più collassi laterali. Questi hanno lasciato una struttura a ferro di cavallo, tipica di processi da “avalancing”, aperta verso sud, e depositi con topografia “hummocky” estesi a sud dell’Epomeo e rilevati recentemente da esplorazioni sul fondo marino. Il processo che ha generato il collasso e la formazione di un avalanche caldera è stato esaminato attraverso l’analisi della dinamica e dei caratteri geologici, geomorfologici e strutturali dell’area. Attualmente l’isola è caratterizzata da una fase di stasi della risorgenza testimoniata da una condizione di moderata stabilità dei versanti dell’Epomeo. Quanto osservato indicherebbe una bassa dinamica endogena nell’isola

Sea level changes, ground deformations, human settlements in the bay of Naples

Ground deformations in active volcanoes are considered precursors of eruptions according to the most tested models; therefore monitoring networks of ground deformations are installed on inhabited dangerous volcanoes. Direct measurements of such deformations are carried out since 1861 when Luigi Palmieri monitored the eruption at Mt. Vesuvius with levelings along the shoreline near the town of Torre del Greco. Relative sea level changes were measured at Serapeo in Pozzuoli in the middle of 19th century to record soil uplifts which are locally known as bradyseism. To enlarge the time series of data on these phenomena it is necessary to utilize historical and prehistorical informations on the location of shore-line of human settlements. As regards the regions of active volcanoes as the Neapolitan one three processes contribute to sea level changes as eustatism, regional tectonics and local intrusive and effusive phenomena. Therefore at the same time the relative sea level should be different at far-away places only few kilometres according to the volcanic activity. In fact eustatic and tectonic processes contribute to sea level changes with very lesser rates than volcanic activity. The Neapolitan region for its geological history is an excellent laboratory for testing the validation of new paradigms for some natural phenomena

Two-to-one resonant multi-modal dynamics of horizontal/inclined cables. Part I : theoretical formulation and model validation

This paper is first of the two papers dealingwith analytical investigation of resonant multimodal dynamics due to 2:1 internal resonances in the finite-amplitude free vibrations of horizontal/inclined cables. Part I deals with theoretical formulation and validation of the general cable model. Approximate nonlinear partial differential equations of 3-D coupled motion of small sagged cables - which account for both spatio-temporal variation of nonlinear dynamic tension and system asymmetry due to inclined sagged configurations - are presented. A multidimensional Galerkin expansion of the solution ofnonplanar/planar motion is performed, yielding a complete set of system quadratic/cubic coefficients. With the aim of parametrically studying the behavior of horizontal/inclined cables in Part II [25], a second-order asymptotic analysis under planar 2:1 resonance is accomplished by the method of multiple scales. On accounting for higher-order effectsof quadratic/cubic nonlinearities, approximate closed form solutions of nonlinear amplitudes, frequencies and dynamic configurations of resonant nonlinear normal modes reveal the dependence of cable response on resonant/nonresonant modal contributions. Depending on simplifying kinematic modeling and assigned system parameters, approximate horizontal/inclined cable models are thoroughly validated by numerically evaluating statics and non-planar/planar linear/non-linear dynamics against those of the exact model. Moreover, the modal coupling role and contribution of system longitudinal dynamics are discussed for horizontal cables, showing some meaningful effects due to kinematic condensation

Lc and nmr studies for identification and characterization of degradation byproducts of olmesartan acid, elucidation of their degradation pathway and ecotoxicity assessment

The discovery of various sartans, which are among the most used antihypertensive drugs in the world, is increasingly frequent not only in wastewater but also in surface water and, in some cases, even in drinking or groundwater. In this paper, the degradation pathway of olmesartan acid, one of the most used sartans, was investigated by simulating the chlorination process normally used in a wastewater treatment plant to reduce similar emerging pollutants. The structures of nine isolated degradation byproducts (DPs), eight of which were isolated for the first time, were separated via chromatography column and HPLC methods, identified by combining nuclear magnetic resonance and mass spectrometry, and justified by a proposed mechanism of formation beginning from the parent drug. Ecotoxicity tests on olmesartan acid and its nine DPs showed that 50% of the investigated byproducts inhibited the target species Aliivibrio fischeri and Raphidocelis subcapitata, causing functional decreases of 18% and 53%, respectively

Amoxicillin in water: Insights into relative reactivity, byproduct formation, and toxicological interactions during chlorination

In recent years, many studies have highlighted the consistent finding of amoxicillin in waters destined for wastewater treatment plants, in addition to superficial waters of rivers and lakes in both Europe and North America. In this paper, the amoxicillin degradation pathway was investigated by simulating the chlorination process normally used in a wastewater treatment plant to reduce similar emerging pollutants at three different pH values. The structures of 16 isolated degradation byproducts (DPs), one of which was isolated for the first time, were separated on a C-18 column via a gradient HPLC method. Combining mass spectrometry and nuclear magnetic resonance, we then compared commercial standards and justified a proposed formation mechanism beginning from the parent drug. Microbial growth inhibition bioassays with Escherichia coli, Klebsiella pneumoniae, and Staphylococcus aureus were performed to determine the potential loss of antibacterial activity in isolated degradation byproducts. An increase of antibacterial activity in the DPs was observed compared to the parent compound

Complete characterization of degradation byproducts of olmesartan acid, degradation pathway, and ecotoxicity assessment

Antihypertensive drugs are among the most prescribed drugs. Olmesartan acid, of the sartan class, belongs to a relatively new generation of antihypertensive drugs called angiotensin II receptor blockers. There are very few studies on the presence and fate of sartans in the environment, despite them being marketed in huge quantities, metabolized in low percentages, and detected in wastewater and water bodies. This paper presents a study on the less abundant and more polar fractions that have been neglected in previous studies, which led to the isolation by chromatographic methods of thirteen degradation byproducts (DPs), six of which are new, identified by nuclear magnetic resonance and mass spectrometry. A mechanism of degradation from the parent drug was proposed. The ecotoxicity of olmesartan acid and identified compounds was evaluated in Aliivibrio fischeri bacteria and Raphidocelis subcapitata algae to assess acute and chronic toxicity. For 75% of the DPs, acute and chronic exposure to the compounds, at concentrations of 5 mg/L, inhibited population growth in the algae and decreased bioluminescence in the bacteria