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Facile production of ultra-fine silicon nanoparticles
A facile procedure for the synthesis of ultra-fine silicon nanoparticles without the need for a Schlenk vacuum line is presented. The process consists of the production of a (HSiO1.5)n sol鈥揼el precursor based on the polycondensation of low-cost trichlorosilane (HSiCl3), followed by its annealing and etching. The obtained materials were thoroughly characterized after each preparation step by electron microscopy, Fourier transform and Raman spectroscopy, X-ray dispersion spectroscopy, diffraction methods and photoluminescence spectroscopy. The data confirm the formation of ultra-fine silicon nanoparticles with controllable average diameters between 1 and 5 nm depending on the etching time
Wp艂yw dodecylosiarczanu sodu na zachowanie termoczu艂ych polimer贸w i ich mieszanin w roztworze
The process of thermal aggregation in water of thermoresponsive (co)polymers poly(N-isopropylacrylamide) PNIPAM, poly{[di(ethylene glycol) monomethyl ether methacrylate]-co-[oligo(ethylene glycol) monomethyl ether methacrylate]} P(D-co-O300), the bioconjugate of P(D-co-O300) with the peptide metenkephalin (MetDns) and their mixtures was investigated. The effect of the SDS (sodium dodecyl sulfate) addition on the behavior of thermoresponsive chains was evaluated by UV-Vis (ultraviolet-visible spectroscopy) and DLS (dynamic light scattering) methods. It was found that the presence of SDS influences the polymer transition temperature. It also reduces the size of the aggregates, which explains the higher transmittance value of the solution above phase transition.Zbadano proces termicznej agregacji w wodzie termoczu艂ych (ko)polimer贸w PNIPAM [poli(N-izopropyloakryloamidu)], P(D-co-O300) [poli(metakrylanu eteru monometylowego glikolu dietylenowego-co-metakrylanu eterumonometylowego glikolu oligoetylenowego)], koniugatu P(D-co-O300) z peptydem metenkefalin膮 (MetDns) oraz ich mieszanin. Metodami UV-Vis (spektroskopia w ultrafiolecie i 艣wietle widzialnym) i DLS (dynamiczne rozpraszanie 艣wiat艂a) oceniono wp艂yw dodatku dodecylosiarczanu sodu (SDS) na zachowanie termoczu艂ych 艂a艅cuch贸w. Stwierdzono, 偶e obecno艣膰 SDS wp艂ywa na temperatur臋 przej艣cia polimer贸w. Powoduje tak偶e zmniejszenie rozmiaru agregat贸w, co wyja艣nia wi臋ksz膮 warto艣膰 transmitancji roztworu powy偶ej przej艣cia
Micellization of Polystyrene-b-Polyglycidol in Dioxane and Water/Dioxane Solutions
In this work, the self-assembly of a series of amphiphilic polystyrene-b-polyglycidol (PS-b-PGL) diblock copolymers in dioxane and dioxane/water mixtures is presented. The PS-b-PGL have an average degree of polymerization (DP) of PS block equal to 29 units and varied degrees of polymerization for the glycidol segments with DPs of 13, 42, 69 and 117. In dioxane, amphiphilic diblock copolymers form micelles with the hydrophilic PGL placed in the core. Critical micelle concentration (CMC) was determined based on the intensity of scattered light vs. concentration. The micelle size was measured by dynamic light scattering and transmission electron microscopy. Also, the behaviour of the copolymer was studied in water/dioxane solutions by following the changes of scattered light intensity with the addition of water to the system. Critical water content (CWC) of the studied systems decreased as the initial PS-b-PGL concentration in dioxane increased. This process was accompanied by a decrease in the size of aggregate formed. For a given initial copolymer concentration, the size of copolymer aggregates decreased linearly with increasing the length of the PGL bloc
Stimuli-Responsive Lyotropic Liquid Crystalline Nanosystems with Incorporated Poly(2-Dimethylamino Ethyl Methacrylate)-b-Poly(Lauryl Methacrylate) Amphiphilic Block Copolymer
Exciplex Enhancement as a Tool to Increase OLED Device Efficiency
Organic electronics, mainly due to advancements in OLED (organic light-emitting diode) technology, is a fast developing research area having already revolutionized the displays market. This direction presents the use of exciplex emitters and thermally activated delayed fluorescence (TADF) in OLEDs, to give efficient, stable emitters that do not use scarce and expensive materials such as iridium. Here, it is shown for the first time several diketopyrrolopyrrole (DPP) derivatives that could be used as emitters in OLED devices. We were able to improve the efficiency of DPP materials by forming exciplex-enhanced OLED devices. These organic materials were also characterized by electrochemical and spectroscopic methods in order to elucidate each molecule's interaction and decrease the photoluminescence efficiency
Smart Polymeric Nanocarriers of Met-enkephalin
This study describes a novel approach
to polymeric nanocarriers
of the therapeutic peptide met-enkephalin based on the aggregation
of thermoresponsive polymers. Thermoresponsive bioconjugate poly颅((di颅(ethylene
glycol) monomethyl ether methacrylate)-<i>ran</i>-(oligo颅(ethylene
glycol) monomethyl ether methacrylate) is synthesized by AGET ATRP
using modified met-enkephalin as a macroinitiator. The abrupt heating
of bioconjugate water solution leads to the self-assembly of bioconjugate
chains and the formation of mesoglobules of controlled sizes. Mesoglobules
formed by bioconjugates are stabilized by coating with cross-linked
two-layer shell via nucleated radical polymerization of <i>N</i>-isopropylacrylamide using a degradable cross-linker. The targeting
peptide RGD, containing the fluorescence marker carboxyfluorescein,
is linked to a nanocarrier during the formation of the outer shell
layer. In the presence of glutathione, the whole shell is completely
degradable and the met-enkephalin conjugate is released. It is anticipated
that precisely engineered nanoparticles protecting their cargo will
emerge as the next-generation platform for cancer therapy and many
other biomedical applications