Collision-induced dissociation processes of Nb4+ and Fe4+: fission vs. evaporation

Journal ArticleDespite the extensive effort devoted to research on gasphase metal clusters, quantitative thermodynamic data on such species are scarce. Such information is key to understanding and predicting the physical and chemical properties of clusters. Presently, bond energies are available primarily for transition metal1 dimers2 and some trimers,3 although ionization potentials have been measured for a broader range of sizes.

Oxidation reactions at variably sized transition metal centers: Fen+ and Nbn+ + O2 (N=1-3)

Journal ArticleCross sections for the reactions of Fen+ and Nbn+ (n = 1-3) with 02 are measured as a function of kinetic energy over a range of 0 to > 10 eV. In all systems, analysis yields insight into the kinetics and thermochemistry of the oxidation processes. Nbn+ reaction with 02 exothermically near the Langevin-Gioumousis-Stevenson close-collision limit, driven by formation of strong NbO+ and NbO bonds. Fen+ are less reactive, although oxidation becomes progressively more facile as the size of the reactant increases from Fe+ to Fe3+

Collision-induced dissociation of Fen+ (n=2-10) with Xe: ionic and neutral iron binding energies

Journal ArticleCross sections for collision-induced dissociation (CID) of Fen+ with Xe, 2≤n≤10, are presented. Experiments were performed on a newly constructed guided ion beam mass spectrometer, the design and capabilities of which are described in detail. The single mechanism for dissociation of iron cluster ions is sequential loss of iron atoms with increasing collision energies

Theory of monolayers with boundaries: Exact results and Perturbative analysis

Domains and bubbles in tilted phases of Langmuir monolayers contain a class of textures knows as boojums. The boundaries of such domains and bubbles may display either cusp-like features or indentations. We derive analytic expressions for the textures within domains and surrounding bubbles, and for the shapes of the boundaries of these regions. The derivation is perturbative in the deviation of the bounding curve from a circle. This method is not expected to be accurate when the boundary suffers large distortions, but it does provide important clues with regard to the influence of various energetic terms on the order-parameter texture and the shape of the domain or bubble bounding curve. We also look into the effects of thermal fluctuations, which include a sample-size-dependent effective line tension.Comment: replaced with published version, 21 pages, 16 figures include

High-energy gamma-ray observations of the accreting black hole V404 Cygni during its June 2015 outburst

We report on Fermi/Large Area Telescope observations of the accreting black hole low-mass X-ray binary V404 Cygni during its outburst in June-July 2015. Detailed analyses reveal a possible excess of $\gamma$-ray emission on 26 June 2015, with a very soft spectrum above $100$ MeV, at a position consistent with the direction of V404 Cyg (within the $95\%$ confidence region and a chance probability of $4 \times 10^{-4}$). This emission cannot be associated with any previously-known Fermi source. Its temporal coincidence with the brightest radio and hard X-ray flare in the lightcurve of V404 Cyg, at the end of the main active phase of its outburst, strengthens the association with V404 Cyg. If the $\gamma$-ray emission is associated with V404 Cyg, the simultaneous detection of $511\,$keV annihilation emission by INTEGRAL requires that the high-energy $\gamma$ rays originate away from the corona, possibly in a Blandford-Znajek jet. The data give support to models involving a magnetically-arrested disk where a bright $\gamma$-ray jet can re-form after the occurrence of a major transient ejection seen in the radio.Comment: 5 pages, 3 figures, accepted for publication in MNRA

Truncated-Determinant Diagrammatic Monte Carlo for Fermions with Contact Interaction

For some models of interacting fermions the known solution to the notorious sign-problem in Monte Carlo (MC) simulations is to work with macroscopic fermionic determinants; the price, however, is a macroscopic scaling of the numerical effort spent on elementary local updates. We find that the {\it ratio} of two macroscopic determinants can be found with any desired accuracy by considering truncated (local in space and time) matices. In this respect, MC for interacting fermionic systems becomes similar to that for the sign-problem-free bosonic systems with system-size independent update cost. We demonstrate the utility of the truncated-determinant method by simulating the attractive Hubbard model within the MC scheme based on partially summed Feynman diagrams. We conjecture that similar approach may be useful in other implementations of the sign-free determinant schemes.Comment: results of the actual Hubbard model simulations are adde

Graphene Transport at High Carrier Densities using a Polymer Electrolyte Gate

We report the study of graphene devices in Hall-bar geometry, gated with a polymer electrolyte. High densities of 6 $\times 10^{13}/cm^{2}$ are consistently reached, significantly higher than with conventional back-gating. The mobility follows an inverse dependence on density, which can be correlated to a dominant scattering from weak scatterers. Furthermore, our measurements show a Bloch-Gr\"uneisen regime until 100 K (at 6.2 $\times10^{13}/cm^{2}$), consistent with an increase of the density. Ubiquitous in our experiments is a small upturn in resistivity around 3 $\times10^{13}/cm^{2}$, whose origin is discussed. We identify two potential causes for the upturn: the renormalization of Fermi velocity and an electrochemically-enhanced scattering rate.Comment: 13 pages, 4 figures, Published Versio

Bioaccessibility of Carotenoids and Tocopherols in Marine Microalgae, Nannochloropsis sp. and Chaetoceros sp.

Microalgae can produce various natural products such as pigments, enzymes, unique fatty acids and vitamin that benefit humans. The objective of the study is to study the bioaccessibility of carotenoids (β-carotene and lycopene) and vitamin E (α- and β- tocopherol) of Nannochloropsis oculata and Chaetoceros calcitrans. Analyses were carried out for both the powdered forms of N. oculata and C. calcitrans, and the dried extract forms of N. oculata and C. calcitrans. In vitro digestion method together with RP-HPLC was used to determine the bioaccessibility of carotenoids and vitamin E for both forms of microalgae. Powdered form of N. oculata had the highest bioaccessibility of β-carotene (28.0 ± 0.6 g kg-1), followed by dried extract N. oculata (21.5 ± 1.1 g kg-1), dried extract C. calcitrans (16.9 ± 0.1 g kg-1), and powdered C. calcitrans (15.6 ± 0.1 g kg-1). For lycopene, dried extract of N. oculata had the highest bioaccessibility of lycopene (42.6 ± 1.1 g kg- 1), followed by dried extract C. calcitrans (41.9 ± 0.6 g kg-1), powdered C. calcitrans (39.7 ± 0.1 g kg-1) and powdered N. oculata (32.6 ± 0.7 g kg-1). Dried extract C. calcitrans had the highest bioaccessibility of α-tocopherol (72.1 ± 1.2 g kg-1). However, β-tocopherol was not detected in both dried extract and powdered form of C. calcitrans. In conclusion, all samples in their dried extract forms were found to have significantly higher bioaccessibilities than their powdered forms. This may be due to the disruption of the food matrix contributing to a higher bioaccessibility of nutrients shown by the dried extract form

Pairing Correlations in the Two-Dimensional Hubbard Model

We present the results of a quantum Monte Carlo study of the extended $s$ and the $d_{x^2-y^2}$ pairing correlation functions for the two-dimensional Hubbard model, computed with the constrained-path method. For small lattice sizes and weak interactions, we find that the $d_{x^2-y^2}$ pairing correlations are stronger than the extended $s$ pairing correlations and are positive when the pair separation exceeds several lattice constants. As the system size or the interaction strength increases, the magnitude of the long-range part of both correlation functions vanishes.Comment: 4 pages, RevTex, 4 figures included; submitted to Phys. Rev. Let

9-(4-Hy­droxy­phen­yl)-3,3,6,6-tetra­methyl-4,5,6,9-tetra­hydro-3H-xanthene-1,8(2H,7H)-dione

In the title compound, C23H26O4, the two cyclo­hexene rings adopt envelope conformations whereas the pyran ring adopts a boat conformation. In the crystal, pairs of inter­molecular O—H⋯O hydrogen bonds link the mol­ecules into inversion dimers