Retrieval of Seasonal Leaf Area Index from Simulated EnMAP Data through Optimized LUT-Based Inversion of the PROSAIL Model

The upcoming satellite mission EnMAP offers the opportunity to retrieve information on the seasonal development of vegetation parameters on a regional scale based on hyperspectral data. This study aims to investigate whether an analysis method for the retrieval of leaf area index (LAI),developed and validated on the 4 m resolution scale of six airborne datasets covering the 2012 growing period, is transferable to the spaceborne 30 m resolution scale of the future EnMAP mission. The widely used PROSAIL model is applied to generate look-up-table (LUT) libraries, by which the model is inverted to derive LAI information. With the goal of defining the impact of different selection criteria in the inversion process, different techniques for the LUT based inversion are tested, such as several cost functions, type and amount of artificial noise, number of considered solutions and type of averaging method. The optimal inversion procedure (Laplace, median, 4% inverse multiplicative noise, 350 out of 100, 000 averages) is identified by validating the results against corresponding in-situ measurements (n = 330) of LAI. Finally, the best performing LUT inversion (R-2 = 0.65, RMSE = 0.64) is adapted to simulated EnMAP data, generated from the airborne acquisitions. The comparison of the retrieval results to upscaled maps of LAI, previously validated on the 4 m scale, shows that the optimized retrieval method can successfully be transferred to spaceborne EnMAP data

Retrieval of Seasonal Leaf Area Index from Simulated EnMAP Data through Optimized LUT-Based Inversion of the PROSAIL Model

The upcoming satellite mission EnMAP offers the opportunity to retrieve information on the seasonal development of vegetation parameters on a regional scale based on hyperspectral data. This study aims to investigate whether an analysis method for the retrieval of leaf area index (LAI),developed and validated on the 4 m resolution scale of six airborne datasets covering the 2012 growing period, is transferable to the spaceborne 30 m resolution scale of the future EnMAP mission. The widely used PROSAIL model is applied to generate look-up-table (LUT) libraries, by which the model is inverted to derive LAI information. With the goal of defining the impact of different selection criteria in the inversion process, different techniques for the LUT based inversion are tested, such as several cost functions, type and amount of artificial noise, number of considered solutions and type of averaging method. The optimal inversion procedure (Laplace, median, 4% inverse multiplicative noise, 350 out of 100, 000 averages) is identified by validating the results against corresponding in-situ measurements (n = 330) of LAI. Finally, the best performing LUT inversion (R-2 = 0.65, RMSE = 0.64) is adapted to simulated EnMAP data, generated from the airborne acquisitions. The comparison of the retrieval results to upscaled maps of LAI, previously validated on the 4 m scale, shows that the optimized retrieval method can successfully be transferred to spaceborne EnMAP data

Anion-driven tetrel bond-induced engineering of lead(II) architectures with N′-(1-(2-pyridyl)ethylidene)nicotinohydrazide : experimental and theoretical findings

The evaluation of N′-(1-(2-pyridyl)ethylidene)nicotinohydrazide (HL) as a linker for the PbII tagged extended structures is described. The reaction of Pb(ClO4)2 or Pb(OAc)2 with HL in MeOH at 60 °C and room temperature, respectively, leads to heteroleptic complexes {[PbL]ClO4}n·nH2O and [PbL(OAc)]2, while the same reaction of Pb(ClO4)2 with HL at 60 °C in the presence of two equivalents of NaOAc or NaNO2 leads to heteroleptic complexes {[Pb(HL)(OAc)]ClO4}n and [PbL(NO2)]n, respectively. Using Pb(NO3)2 as a source of PbII in the same reaction with HL and two equivalents of NaN3 or NaNCS at room temperature yields [PbLN3]n and [Pb2(HL)2(NO3)2(NCS)2], respectively. The room temperature reaction of Pb(NO3)2 with HL in the presence of two equivalents of NaClO4 leads to the transformation of the parent ligand to its perchlorate salt [H2L]ClO4. In all the obtained PbII structures, HL or its deprotonated form L acts both as a chelating and a bridging ligand. The nature of the inorganic anion also influences the final structure. In all complexes the PbII center exhibits a hemidirected coordination geometry with all the covalent bonds being concentrated on one hemisphere of the coordination sphere with the closest approach of two atoms on the other side varying from 151° to 232°. The sterically available PbII ion participates in tetrel bonding as evidenced from the detailed structural analysis of the described complexes. As a result of tetrel bonding, the structures of all the six compounds can be extended to a higher dimensional framework, which is further stabilized by π⋯π stacking interactions between the aromatic rings. The DFT based charge and energy decomposition (ETS-NOCV) calculations are performed in order to shed light on the nature of non-covalent interactions that determine the stability of the obtained structures