An Absorption Band of Formaldoxime at lambda9572

The third harmonic of the O [Single Bond] H band in formaldoxime vapor has been found to lie at lambda9572 (10,444.1 cm^—1) and under high dispersion has been resolved and found to resemble a parallel band of a symmetric rotator. Owing to the weakness of the lines near the center of the band a definitely unique rotational analysis could not be made but the harmonic mean of the two larger moments of inertia appears to lie between the limits 73.3 and 76.6×10^—40 g cm^2. The hydroxyl hydrogen does not rotate freely and indeed its torsional oscillation appears not to have a very low frequency. It is not possible to locate this hydrogen uniquely until other parameters of the molecule have been determined by electron diffraction. The possible effect of resonance on the O [Single Bond] H frequency is discussed

Structure of the O[Single Bond]H Bands in the Vapors of Halogen Substituted Alcohols

In the study of the infra-red absorption of organic substances containing hydroxyl groups it has been found that the O-H bands sometimes occur as multiplets even though only one such group is present per molecule. This has been observed both in the spectra of vapors (1) and of solutions (2,3) though in the latter case less structure is resolvable in some instances. The phenomenon has been explained by saying that the hydroxyl hydrogen is not free to rotate around the C-O bond, but may be found in more than one position of potential minimum in which the O-H frequency may be somewhat different (1,4). Though this explanation appears plausible it has seemed desirable to investigate the matter further by a quantitative study of some relatively simple substances in the vapor phase. Consequently a series of halogen substituted alcohols has been investigated with interesting results

The N[Single Bond]H Harmonic Bands of Pyrrole at lambda9900, and the Structure of the Pyrrole Molecule

In their study of the infra-red absorption of organic substances in carbon tetrachloride solution Wulf and Liddell (1) found that the strong second harmonic N-H band of pyrrole is accompanied by a weak satellite which lies approximately 50 cm^-1 to the long wave side and has roughly one-twentieth the intensity of the main band. The main band has been attributed by Pauling (2) to a planar pyrrole molecule and the weak satellite to a second molecular species in which the imino hydrogen lies out of the plane of the other atoms

Distribution of Spectral Characteristics and the Cosmological Evolution of GRBs

We investigate the cosmological evolution of GRBs, using the total gamma ray fluence as a measure of the burst strength. This involves an understanding of the distributions of the spectral parameters of GRBs as well as the total fluence distribution - both of which are subject to detector selection effects. We present new non-parametric statistical techniques to account for these effects, and use these methods to estimate the true distribution of the peak of the nu F_nu spectrum, E_p, from the raw distribution. The distributions are obtained from four channel data and therefore are rough estimates. Here, we emphasize the methods and present qualitative results. Given its spectral parameters, we then calculate the total fluence for each burst, and compute its cumulative and differential distributions. We use these distributions to estimate the cosmological rate evolution of GRBs, for three cosmological models. Our two main conclusions are the following: 1) Given our estimates of the spectral parameters, we find that there may exist a significant population of high E_p bursts that are not detected by BATSE, 2) We find a GRB co-moving rate density quite different from that of other extragalactic objects; in particular, it is different from the recently determined star formation rate.Comment: 20 pages, including 10 postscript figures. Submitted to Ap

Cosmological versus Intrinsic: The Correlation between Intensity and the Peak of the nu F_nu Spectrum of Gamma Ray Bursts

We present results of correlation studies, examining the association between the peak of the nu F_nu spectrum of gamma ray bursts, E_p, with the burst's energy fluence and photon peak flux. We discuss methods to account for data truncation in E_p and fluence or flux when performing the correlation analyses. However, because bursts near the detector threshold are not usually able to provide reliable spectral parameters, we focus on results for the brightest bursts in which we can better understand the selection effects relevant to E_p and burst strength. We find that there is a strong correlation between total fluence and E_p. We discuss these results in terms of both cosmological and intrinsic effects. In particular, we show that for realistic distributions of the burst parameters, cosmological expansion alone cannot account for the correlation between E_p and total fluence; the observed correlation is likely a result of an intrinsic relation between the burst rest-frame peak energy and the total radiated energy. We investigate this latter scenario in the context of synchrotron radiation from external and internal shock models of GRBs. We find that the internal shock model is consistent with our interpretation of the correlation, while the external shock model cannot easily explain this intrinsic relation between peak energy and burst radiated energy.Comment: 23 pages, including 8 postscript figures. Submitted to Ap

Semantics of Input-Consuming Logic Programs

Input-consuming programs are logic programs with an additional restriction on the selectability (actually, on the resolvability) of atoms. this class of programs arguably allows to model logic programs employing a dynamic selection rule and constructs such as delay declarations: as shown also in [5], a large number of them are actually input-consuming. \ud in this paper we show that - under some syntactic restrictions - the tex2html_wrap_inline117-semantics of a program is correct and fully abstract also for input-consuming programs. this allows us to conclude that for a large class of programs employing delay declarations there exists a model-theoretic semantics which is equivalent to the operational one

The Birmingham-CfA cluster scaling project - I: gas fraction and the M-T relation

We have assembled a large sample of virialized systems, comprising 66 galaxy clusters, groups and elliptical galaxies with high quality X-ray data. To each system we have fitted analytical profiles describing the gas density and temperature variation with radius, corrected for the effects of central gas cooling. We present an analysis of the scaling properties of these systems and focus in this paper on the gas distribution and M-T relation. In addition to clusters and groups, our sample includes two early-type galaxies, carefully selected to avoid contamination from group or cluster X-ray emission. We compare the properties of these objects with those of more massive systems and find evidence for a systematic difference between galaxy-sized haloes and groups of a similar temperature. We derive a mean logarithmic slope of the M-T relation within R_200 of 1.84+/-0.06, although there is some evidence of a gradual steepening in the M-T relation, with decreasing mass. We recover a similar slope using two additional methods of calculating the mean temperature. Repeating the analysis with the assumption of isothermality, we find the slope changes only slightly, to 1.89+/-0.04, but the normalization is increased by 30%. Correspondingly, the mean gas fraction within R_200 changes from (0.13+/-0.01)h70^-1.5 to (0.11+/-0.01)h70^-1.5, for the isothermal case, with the smaller fractional change reflecting different behaviour between hot and cool systems. There is a strong correlation between the gas fraction within 0.3*R_200 and temperature. This reflects the strong (5.8 sigma) trend between the gas density slope parameter, beta, and temperature, which has been found in previous work. (abridged)Comment: 27 pages, accepted for publication in MNRAS; uses longtable.sty & lscape.st

Teaching Teachers for the Future (TTF) Project: Development of the TTF TPACK survey instrument

This paper presents a summary of the key findings of the TTF TPACK Survey developed and administered for the Teaching the Teachers for the Future (TTF) Project implemented in 2011. The TTF Project, funded by an Australian Government ICT Innovation Fund grant, involved all 39 Australian Higher Education Institutions which provide initial teacher education. TTF data collections were undertaken at the end of Semester 1 (T1) and at the end of Semester 2 (T2) in 2011. A total of 12881 participants completed the first survey (T1) and 5809 participants completed the second survey (T2). Groups of like-named items from the T1 survey were subject to a battery of complementary data analysis techniques. The psychometric properties of the four scales: Confidence - teacher items; Usefulness - teacher items; Confidence - student items; Usefulness- student items, were confirmed both at T1 and T2. Among the key findings summarised, at the national level, the scale: Confidence to use ICT as a teacher showed measurable growth across the whole scale from T1 to T2, and the scale: Confidence to facilitate student use of ICT also showed measurable growth across the whole scale from T1 to T2. Additional key TTF TPACK Survey findings are summarised