Rapid analysis of pyrethroid insecticides in aquaculture seawater samples via membrane-assisted solvent extraction coupled with gas chromatography-electron capture detection

A simple, efficient, and environmentally friendly membrane-assisted solvent extraction (MASE) method for the extraction and preconcentration of six pyrethroid insecticides from aquaculture seawater samples followed by gas chromatography-electron capture detection (GC-ECD) was successfully proposed. The operating conditions for MASE, such as the extraction solvent, solvent volume, NaCl concentration, stirring rate, extraction time, and temperature, were optimized. Compared to conventional Florisil-solid phase extraction (SPE), higher extraction recoveries (85.9% to 105.9%) of three spiked levels of the six pyrethroid pesticides in aquaculture seawater were obtained using MASE, and the RSD values were lower than 7.9%. The limits of detection (LOD, signal-to-noise ratio (S/N)=3) and quantification (LOQ, S/N = 10) were in the range of 0.037–0.166 and 0.12–0.55 µg L-1, respectively. The results demonstrate the excellent applicability of the MASE method in analyzing the six pyrethroid pesticides in aqueous samples. The proposed method exhibited a high potential for routine monitoring analysis of pyrethroid insecticides in seawater samples

Effect of Tensor Correlations on Gamow-Teller States in 90Zr and 208Pb

The tensor terms of the Skyrme effective interaction are included in the self-consistent Hartree-Fock plus Random Phase Approximation (HF+RPA) model. The Gamow-Teller (GT) strength function of 90Zr and 208Pb are calculated with and without the tensor terms. The main peaks are moved downwards by about 2 MeV when including the tensor contribution. About 10% of the non-energy weighted sum rule is shifted to the excitation energy region above 30 MeV by the RPA tensor correlations. The contribution of the tensor terms to the energy weighted sum rule is given analytically, and compared to the outcome of RPA.Comment: 13 pages, 2 figures,2 table

Particle Motion Around Tachyon Monopole

Recently, Li and Liu have studied global monoole of tachyon in a four dimensional static space-time. We analyze the motion of massless and massive particles around tachyon monopole. Interestingly, for the bending of light rays due to tachyon monopole instead of getting angle of deficit we find angle of surplus. Also we find that the tachyon monopole exerts an attractive gravitational force towards matter.Comment: 14 pages, 7 figure

Nucleon-nucleon momentum correlation function for light nuclei

Nucleon-nucleon momentum correlation function have been presented for nuclear reactions with neutron-rich or proton-rich projectiles using a nuclear transport theory, namely Isospin-Dependent Quantum Molecular Dynamics model. The relationship between the binding energy of projectiles and the strength of proton-neutron correlation function at small relative momentum has been explored, while proton-proton correlation function shows its sensitivity to the proton density distribution. Those results show that nucleon-nucleon correlation function is useful to reflect some features of the neutron- or proton-halo nuclei and therefore provide a potential tool for the studies of radioactive beam physics.Comment: Talk given at the 18th International IUPAP Conference on Few-Body Problems in Physics (FB18), Santos, Brasil, August 21-26, 2006. To appear in Nucl. Phys.

Neutron/proton ratio of nucleon emissions as a probe of neutron skin

The dependence between neutron-to-proton yield ratio ($R_{np}$) and neutron skin thickness ($\delta_{np}$) in neutron-rich projectile induced reactions is investigated within the framework of the Isospin-Dependent Quantum Molecular Dynamics (IQMD) model. The density distribution of the Droplet model is embedded in the initialization of the neutron and proton densities in the present IQMD model. By adjusting the diffuseness parameter of neutron density in the Droplet model for the projectile, the relationship between the neutron skin thickness and the corresponding $R_{np}$ in the collisions is obtained. The results show strong linear correlation between $R_{np}$ and $\delta_{np}$ for neutron-rich Ca and Ni isotopes. It is suggested that $R_{np}$ may be used as an experimental observable to extract $\delta_{np}$ for neutron-rich nuclei, which is very significant to the study of the nuclear structure of exotic nuclei and the equation of state (EOS) of asymmetric nuclear matter.Comment: 7 pages, 5 figures; accepted by Phys. Lett.

Detection of herb-symptom associations from traditional chinese medicine clinical data

YesTraditional Chinese medicine (TCM) is an individualized medicine by observing the symptoms and signs (symptoms in brief) of patients. We aim to extract the meaningful herb-symptom relationships from large scale TCM clinical data. To investigate the correlations between symptoms and herbs held for patients, we use four clinical data sets collected from TCM outpatient clinical settings and calculate the similarities between patient pairs in terms of the herb constituents of their prescriptions and their manifesting symptoms by cosine measure. To address the large-scale multiple testing problems for the detection of herb-symptom associations and the dependence between herbs involving similar efficacies, we propose a network-based correlation analysis (NetCorrA) method to detect the herb-symptom associations. The results show that there are strong positive correlations between symptom similarity and herb similarity, which indicates that herb-symptom correspondence is a clinical principle adhered to by most TCM physicians. Furthermore, the NetCorrA method obtains meaningful herb-symptom associations and performs better than the chi-square correlation method by filtering the false positive associations. Symptoms play significant roles for the prescriptions of herb treatment. The herb-symptom correspondence principle indicates that clinical phenotypic targets (i.e., symptoms) of herbs exist and would be valuable for further investigations

Nanosized superparamagnetic precipitates in cobalt-doped ZnO

The existence of semiconductors exhibiting long-range ferromagnetic ordering at room temperature still is controversial. One particularly important issue is the presence of secondary magnetic phases such as clusters, segregations, etc... These are often tedious to detect, leading to contradictory interpretations. We show that in our cobalt doped ZnO films grown homoepitaxially on single crystalline ZnO substrates the magnetism unambiguously stems from metallic cobalt nano-inclusions. The magnetic behavior was investigated by SQUID magnetometry, x-ray magnetic circular dichroism, and AC susceptibility measurements. The results were correlated to a detailed microstructural analysis based on high resolution x-ray diffraction, transmission electron microscopy, and electron-spectroscopic imaging. No evidence for carrier mediated ferromagnetic exchange between diluted cobalt moments was found. In contrast, the combined data provide clear evidence that the observed room temperature ferromagnetic-like behavior originates from nanometer sized superparamagnetic metallic cobalt precipitates.Comment: 20 pages, 6 figures; details about background subtraction added to section III. (XMCD

Phantom Field with O(N) Symmetry in Exponential Potential

In this paper, we study the phase space of phantom model with O(\emph{N}) symmetry in exponential potential. Different from the model without O(\emph{N}) symmetry, the introduction of the symmetry leads to a lower bound $w>-3$ on the equation of state for the existence of stable phantom dominated attractor phase. The reconstruction relation between the potential of O(\textit{N}) phantom system and red shift has been derived.Comment: 5 pages, 3 figures, replaced with the version to appear on Phys. Rev.

S-matrix elements and off-shell tachyon action with non-abelian gauge symmetry

We propose that there is a unique expansion for the string theory S-matrix elements of tachyons that corresponds to non-abelian tachyon action. For those S-matrix elements which, in their expansion, there are the Feynman amplitudes resulting from the non-abelian kinetic term, we give a prescription on how to find the expansion. The gauge invariant action is an $\alpha'$ expanded action, and the tachyon mass $m$ which appears as coefficient of many different couplings, is arbitrary. We then analyze in details the S-matrix element of four tachyons and the S-matrix element of two tachyons and two gauge fields, in both bosonic and superstring theories, in favor of this proposal. In the superstring theory, the leading terms of the non-abelian gauge invariant couplings are in agreement with the symmetrised trace of the direct non-abelian generalization of the tachyonic Born-Infeld action in which the tachyon potential is consistent with $V(T)=e^{\pi\alpha' m^2T^2}$. In the bosonic theory, on the other hand, the leading terms are those appear in superstring case as well as some other gauge invariant couplings which spoils the symmetrised trace prescription. These latter terms are zero in the abelian case.Comment: Latex, 27 pages, no figures,v4:change the introduction section, add some notes to clarify the idea, add reference

Cross Breeding and Hybrid Identification of Sulphite-tolerant Hybrids of Saccharomyces uvarum

Yeast species belonging to Saccharomyces have great potential for the wine industry. However, the sulphite tolerance of most S. uvarum strains is quite poor compared with that of the other Saccharomyces strains. Inorder to get new S. uvarum strains with tolerance to sulphite, and also with good fermentation characteristics, 21 candidates were screened from three different crossing combinations of sensitive S. uvarum strains to one sulphitetolerant strain. Ten of these hybrids were sulphite tolerant and contained the FZF1 gene from both parents. Intersimple sequence repeat (ISSR) analysis confirmed their hybrid status, based on six primers that produced 55 clear and reproducible bands, including 32 that were polymorphic. Two hybrids had identical fingerprints, indicating that it was the same clone. Thus, nine different novel sulphite-resistant hybrids of S. uvarum were obtained. The selected hybrid strains fermented very well at 30ºC in Sauvignon Blanc grape juice containing 2 mM of sodium sulphite, with minor differences in fermentation performance. Two strains (namely C13 and C21) performed very similarly to the sulphite-tolerant parent A9 and a commercial S. cerevisiae strain EC1118, and the production offermentation aromas, namely propanol, isobutanol and isoamyl alcohol by C13 was found to be the highest. This is the first report of using hybridisation to breed the sulphite-tolerant S. uvarum strains