451 research outputs found

    Collisional excitation of singly deuterated ammonia NH2_2D by H2_2

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    The availability of collisional rate coefficients with H2_2 is a pre-requisite for interpretation of observations of molecules whose energy levels are populated under non local thermodynamical equilibrium conditions. In the current study, we present collisional rate coefficients for the NH2_2D / para--H2_2(J2=0,2J_2 = 0,2) collisional system, for energy levels up to Jτ=77J_\tau = 7_7 (EuE_u\sim735 K) and for gas temperatures in the range T=5300T = 5-300K. The cross sections are obtained using the essentially exact close--coupling (CC) formalism at low energy and at the highest energies, we used the coupled--states (CS) approximation. For the energy levels up to Jτ=42J_\tau = 4_2 (EuE_u\sim215 K), the cross sections obtained through the CS formalism are scaled according to a few CC reference points. These reference points are subsequently used to estimate the accuracy of the rate coefficients for higher levels, which is mainly limited by the use of the CS formalism. Considering the current potential energy surface, the rate coefficients are thus expected to be accurate to within 5\% for the levels below Jτ=42J_\tau = 4_2, while we estimate an accuracy of 30\% for higher levels

    Basel and Abyssinia, 1830-1855. Protestant Mission and Jewish identity in Abyssinia

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    The notion of the possible existence of Black African Jews intrigued Rabbinical Jewry in Europe throughout the Middle Ages, fed by reports and rumours such as the travel descriptions of the 9th Century Jewish traveller Eldad Ha-Dani. Knowledge of the geography of the African continent however remained very scant, not allowing any precise identification of who or where these Jews (sometimes termed “Israelites”) were; before the modern period no permanent channels of communication existed that ..

    Collisional excitation of doubly and triply deuterated ammonia ND2_2H and ND3_3 by H2_2

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    The availability of collisional rate coefficients is a prerequisite for an accurate interpretation of astrophysical observations, since the observed media often harbour densities where molecules are populated under non--LTE conditions. In the current study, we present calculations of rate coefficients suitable to describe the various spin isomers of multiply deuterated ammonia, namely the ND2_2H and ND3_3 isotopologues. These calculations are based on the most accurate NH3_3--H2_2 potential energy surface available, which has been modified to describe the geometrical changes induced by the nuclear substitutions. The dynamical calculations are performed within the close--coupling formalism and are carried out in order to provide rate coefficients up to a temperature of TT = 50K. For the various isotopologues/symmetries, we provide rate coefficients for the energy levels below \sim 100 cm1^{-1}. Subsequently, these new rate coefficients are used in astrophysical models aimed at reproducing the NH2_2D, ND2_2H and ND3_3 observations previously reported towards the prestellar cores B1b and 16293E. We thus update the estimates of the corresponding column densities and find a reasonable agreement with the previous models. In particular, the ortho--to--para ratios of NH2_2D and NHD2_2 are found to be consistent with the statistical ratios

    Computer simulation of the dipole artifact in three-dimensional NMR imaging

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    Thesis (B.S.) in Chemistry -- University of Illinois at Urbana-Champaign, 1989.Includes bibliographical references (leaves 18-19)Microfiche of typescript. [Urbana, Ill.]: Photographic Services, University of Illinois, U of I Library, [1989]. 1 microfiche (38 frames): negative.s 1989 ilu n

    Nitrogen isotopic ratios in Barnard 1: a consistent study of the N2H+, NH3, CN, HCN and HNC isotopologues

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    The 15N isotopologue abundance ratio measured today in different bodies of the solar system is thought to be connected to 15N-fractionation effects that would have occured in the protosolar nebula. The present study aims at putting constraints on the degree of 15N-fractionation that occurs during the prestellar phase, through observations of D, 13C and 15N-substituted isotopologues towards B1b. Both molecules from the nitrogen hydride family, i.e. N2H+ and NH3, and from the nitrile family, i.e. HCN, HNC and CN, are considered in the analysis. As a first step, we model the continuum emission in order to derive the physical structure of the cloud, i.e. gas temperature and H2 density. These parameters are subsequently used as an input in a non-local radiative transfer model to infer the radial abundances profiles of the various molecules. Our modeling shows that all the molecules are affected by depletion onto dust grains, in the region that encompasses the B1-bS and B1-bN cores. While high levels of deuterium fractionation are derived, we conclude that no fractionation occurs in the case of the nitrogen chemistry. Independently of the chemical family, the molecular abundances are consistent with 14N/15N~300, a value representative of the elemental atomic abundances of the parental gas. The inefficiency of the 15N-fractionation effects in the B1b region can be linked to the relatively high gas temperature ~17K which is representative of the innermost part of the cloud. Since this region shows signs of depletion onto dust grains, we can not exclude the possibility that the molecules were previously enriched in 15N, earlier in the B1b history, and that such an enrichment could have been incorporated into the ice mantles. It is thus necessary to repeat this kind of study in colder sources to test such a possibility.Comment: accepted in A&
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