Invertebrate trace fossil-bearing wairakite layer from the Cretaceous Haman Formation, Gyeongsang Basin, Korea: Occurrence, origin, and paleoenvironmental implications

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Lithium Isotope Geochemistry in the Barton Peninsula, King George Island, Antarctica

Lithium (Li) has two stable isotopes, 6Li and 7Li, whose large relative mass difference is responsible for significant isotopic fractionation during physico-chemical processes, allowing Li isotopes to be a good tracer of continental chemical weathering. Although physical erosion is dominant in the Polar regions due to glaciers, increasing global surface temperature may enhance chemical weathering, with possible consequences on carbon biogeochemical cycle and nutriment flux to the ocean. Here, we examined elemental and Li isotope geochemistry of meltwaters, suspended sediments, soils, and bedrocks in the Barton Peninsula, King George Island, Antarctica. Li concentrations range from 8.7 nM to 23.3 μM in waters, from 0.01 to 1.43 ppm in suspended sediments, from 9.56 to 36.9 ppm in soils, and from 0.42 to 28.3 ppm in bedrocks. δ7Li values are also variable, ranging from +16.4 to +41.1‰ in waters, from −0.4 to +13.4‰ in suspended sediments, from −2.5 to +6.9‰ in soils, and from −1.8 to +11.7‰ in bedrocks. Elemental and Li isotope geochemistry reveals that secondary phase formation during chemical weathering mainly control dissolved δ7Li values, rather than a mixing with sea salt inputs from atmosphere or ice melting. Likewise, δ7Li values of suspended sediments and soils lower than those of bedrocks indicate modern chemical weathering with mineral neoformation. This study suggests that increasing global surface temperature enhances modern chemical weathering in Antarctica, continuing to lower δ7Li values in meltwater with intense water-rock interactions

Biodegradable magnesium alloy (WE43) in bone-fixation plate and screw

The purpose of the present study was to evaluate the mechanical strength and the absorption rate of WE43 material and to develop an absorbable metallic plate and screw for craniofacial application. The extruded WE43 plate and screw were evaluated using a LeFort I osteotomy canine model of 10 beagle dogs. Animals were divided into two groups: five dogs in the experimental group and five dogs in the control group. mu CT was acquired at 4, 12, and 24 weeks. At 24 weeks after the operation, all animals were sacrificed, and histologic evaluation was performed. Swelling and gas formation were observed in three dogs in the experimental groups at 8 weeks. From 12 weeks, infraorbital fistula and inflammation were observed in three dogs in the experimental group, which gradually decreased and disappeared at 24 weeks. Other two dogs showed less gas formation at 12 weeks. The plates were completely absorbed, and gas formation was not observed at 24 weeks in these two dogs. New bone was well formed around the plates and screws in both groups. Histologic examination showed no specific differences between two groups. The mechanical strength of extruded WE43 was sufficient for mid-facial application. Plates and screws made with appropriately treated WE43 have the potential to be useful clinically.N

Stream Water and Groundwater Interaction Revealed by Temperature Monitoring in Agricultural Areas

Variations in stream water, streambed, adjacent stream sediment, and groundwater temperatures in the Haean basin, Korea were examined using time series analyses including auto-correlation, spectral density, and cross-correlation functions. The temperatures of the ambient air, stream water, streambed (depth = 10 cm), and adjacent stream sediment (depth = 10 cm) showed distinctive diurnal variations with long-term seasonal cooling trends, while groundwater temperature showed only a seasonal decreasing trend with little diurnal variations. Auto-correlations and spectral densities of the stream water, streambed, and sediment temperatures also revealed strong daily cyclical behaviors, with longer periodic cycles varying from weekly to monthly. Amplitudes and lag times of the streambed thermal signals were also affected by the hydraulic conductivities of the sediments. Lower hydraulic conductivity indicates a more attenuated and slower thermal response for the streambed. The calculated vertical water flow velocities of the streambed revealed that the investigated stream locations were under losing or gaining conditions, depending on the location and time

Evolution of Depositional Environments in Response to the Holocene Sea-Level Change in the Lower Delta Plain of Nakdong River Delta, Korea

The Nakdong River delta, located in southeastern Korea, preserves thick and wide sediments, which are suitable for the high-resolution study of the evolution of depositional environments in the lower delta plain area. This study traces the Holocene evolution of the Nakdong River delta using deep drill core (ND-3; 46.60 m thick) sediments from the present delta plain. Sedimentary units of the sediments were classified based on grain size compositions and sedimentary structures: (A) alluvial zone, (B) estuarine zone, (C) shallow marine, (D) prodelta, (E) delta front, and (F) delta plain. The weathered sediment, paleosol, was observed at 43.16 m below the surface. There is an unconformity (43.10 m) to separate a Pleistocene sediment layer in the lowermost part differentiating from a Holocene sediment layer in the upper part of the core. The shallow marine sedimentary unit (32.20~23.50 m), in which grain size decreases upward is overlain by the prodelta unit (23.50~15.10 m), which consists of fine-grained sediments and relatively homogeneous sedimentary facies. The boundary between the delta front unit (15.10~8.00 m) and the delta plain unit (8.00~0.00 m) appears to lie at 8.0 m, and the variation in grain size is different; coarsening upward in the delta front unit and fining upward in the delta front unit, respectively. These sediments are characterized by a lot of sand–mud couplets and mica flakes aligned along with cross-stratification, which may be deposited in relatively high-energy environments. Until 13 cal ka BP, the sea level was 70 m below the present level and the drilling site might be located onshore. At 10 cal ka BP, the sea level was located 50 m below the present level and the drilling site might be moved to an estuarine environment. From 8 to 6 cal ka BP, a transgression phase occurred as a result of coastline invasion by the rapid rise of the sea level. Thus, the drilling site was drowned in a shallow marine environment. After 6 cal ka BP, the sea level reached the present level, and, since then, progradation might begin to form, primarily by more sediment input. After this period, the progradation phase continues as the sediments have advanced and the delta grows

Chronostratigraphy of the sedimentary record of Limnopolar Lake, Byers Peninsula, Livingston Island, Antarctica

15 páginas, 7 figuras, 2 tablas.The chronostratigraphy of the sedimentary record of Limnopolar Lake, located on Byers Peninsula (Livingston Island, South Shetland Islands, Maritime Antarctica), is described based on radionuclides and radiocarbon age dating. The oldest moss macrofossil age was 6700 ± 50 yr BP (7510 ± 80 cal yr BP) from which the age/depth model estimates a basal age for the sedimentary record of c. 8300 cal yr BP, suggesting an earlier deglaciation of Byers Peninsula than reported in previous studies. Lithological units and other stratigraphic zones are described throughout the sediment core, showing different mineralogical composition and a fine alternation of clays and silty clays and moss layers of Drepanocladus longifolius. Based on magnetic susceptibility analyses, a number of probable primary and reworked tephra layers were identified, seven of them confirmed by SEM observations, and most of them in agreement with the regional tephrachronology stratigraphy for the north-west Antarctic Peninsula. Sedimentation rates showed no significant changes during the last 5000 years with the exception of an abrupt event that took place around 5400 cal yr BP, which implied the sedimentation of c. 30 cm of clays in a very short time, probably related to a period of glacial re-advance that caused abrupt changes in geomorphological processes in the catchment.Field work was supported by grants REN2000-0435-ANT from the Science and Technology Ministry (Spain) and POL2006-06635/CGL from the Education and Culture Ministry (Spain) in the framework of the International Polar Year 2007–09 activities. Laboratory analyses were supported by grants CTM2009-07869-E/ANT and CSD2007-00067 from the Science and Innovation Ministry (Spain) and grant PP12020 from KOPRI (Korea Polar Research Institute). Publication expenses have been covered by grant CTM2011-12973-E from the Science and Innovation Ministry (Spain). A. Quesada, A. Justel and C. Rochera, from the Limnopolar Project team, helped with coring in 2003 and S. Fassnacht helped in 2008. UTM (Maritime Technology Unit, CSIC) and the captain and crew of the Spanish Navy ship Las Palmas provided us with the logistical support necessary for the expedition.Peer reviewe

Biodegradable Magnesium Alloy (ZK60) with a Poly(l-lactic)-Acid Polymer Coating for Maxillofacial Surgery

The purpose of this study was to evaluate the mechanical strength and biodegradation of a ZK60 plate coated with poly(l-lactic)-acid polymer (PLLA) in a LeFort I osteotomy canine model for maxillofacial applications. The PLLA-coated ZK60 plate and screw were evaluated using a LeFort I osteotomy canine model based on five beagles. The presence of wound dehiscence, plate exposure, gas formation, inflammation, pus formation, occlusion, food intake, and fistula formation were evaluated. After 12 weeks, these dogs were sacrificed, and an X-ray micro-computed tomography (µCT) was conducted. Plate exposure, gas formation, and external fistula were not observed, and the occlusion remained stable. Wound dehiscence did not heal for 12 weeks. CT images did not show plates in all the five dogs. A few screw bodies fixed in the bone remained, and screw heads were completely absorbed after 12 weeks. These findings may be attributed to the inability to optimize the absorption rate with PLLA coating. Rapid biodegradation of the PLLA-coated ZK60 occurred due to the formation of microcracks during the bending process. Further improvement to the plate system with PLLA-coated ZK60 is required using other surface coating methods or alternative Mg alloys