Experimental investigation of imbibition in oil-wet carbonates under low IFT conditions

Natural reservoir drives and waterflooding in naturally fractured carbonate reservoirs with an oil-wet matrix generate very low oil production. Surfactants enhance oil recovery in these reservoirs by altering wettability and reducing interfacial tension (IFT). The main purpose of this research was to determine how to scale up low IFT surfactant imbibition from the lab to fractured, oil-wet carbonate reservoirs. A series of imbibition experiments were conducted using cores with different horizontal (i.e. diameter) and vertical (i.e. height) dimensions. Their fractional oil recoveries (% OOIP) were systematically measured to better understand how to scale up the surfactant imbibition process. There was a particular need to perform experiments using cores with larger horizontal dimensions since almost all previous experiments in the literature used cores with a small diameter, typically 3.8 cm. The core diameters in this study varied from 3.8 to 20 cm. The traditional static imbibition experimental method was adapted and modified by periodically flushing out fluids surrounding the cores inside the cells to better estimate the oil recovery, including the significant amount of oil produced as an emulsion. The high performance surfactant formulations for the oils used on in this study were developed using microemulsion phase behavior tests. These surfactants gave ultra-low IFT (on the order of 0.001 dynes/cm) at optimal salinity and good aqueous stability. Although most of the experiments used ultra-low IFT formulations, experiments using higher IFT (on the order of 0.1 dynes/cm) formulations were also performed for comparison. Even for the higher IFT experiments, the capillary pressure is very small compared to gravity and viscous pressure gradients. In addition, experiments were done to understand the role of other variables on oil recovery, such as matrix permeability, surfactant and co-solvent concentrations, microemulsion viscosity, and oil viscosity. A simple analytical model was developed to predict the oil recovery as a function of vertical and horizontal fracture spacing, rock and fluid properties, and time. The model and experimental data are in good agreement considering the many simplifications made to derive the model. Both experimental data and the model showed that the oil recovery was lower for cores with larger horizontal and vertical dimensions. However, the decrease was not proportional to an increase in these dimensions. The scaling implied by the model is significantly different than the traditional scaling groups in the literature.Petroleum and Geosystems Engineerin

The a priori Tan Theta Theorem for spectral subspaces

Let A be a self-adjoint operator on a separable Hilbert space H. Assume that the spectrum of A consists of two disjoint components s_0 and s_1 such that the set s_0 lies in a finite gap of the set s_1. Let V be a bounded self-adjoint operator on H off-diagonal with respect to the partition spec(A)=s_0 \cup s_1. It is known that if ||V||<\sqrt{2}d, where d=\dist(s_0,s_1), then the perturbation V does not close the gaps between s_0 and s_1 and the spectrum of the perturbed operator L=A+V consists of two isolated components s'_0 and s'_1 grown from s_0 and s_1, respectively. Furthermore, it is known that if V satisfies the stronger bound ||V||< d then the following sharp norm estimate holds: ||E_L(s'_0)-E_A(s_0)|| \leq sin(arctan(||V||/d)), where E_A(s_0) and E_L(s'_0) are the spectral projections of A and L associated with the spectral sets s_0 and s'_0, respectively. In the present work we prove that this estimate remains valid and sharp also for d \leq ||V||< \sqrt{2}d, which completely settles the issue.Comment: v3: some typos fixed; Examples adde

Global Monopole in Asymptotically dS/AdS Spacetime

In this paper, we investigate the global monopole in asymptotically dS/Ads spacetime and find that the mass of the monopole in the asymptotically dS spacetime could be positive if the cosmological constant is greater than a critical value. This shows that the gravitational field of the global monopole could be attractive or repulsive depending on the value of the cosmological constant.Comment: 5 pages, 1 figure, to appear in Phys. Rev.

Resolution studies of cosmic-ray tracks in a TPC with GEM readout

A large volume TPC is a leading candidate for the central tracking detector at a future high energy linear collider. To improve the resolution a new readout based on micro-pattern gas detectors is being developed. Measurements of the spatial resolution of cosmic-ray tracks in a GEM TPC are presented. We find that the resolution suffers if the readout pads are too wide with respect to the charge distribution at the readout plane due to insufficient charge sharing. For narrow pads of 2 x 6 mm**2 we measure a resolution of 100 micometer at short drift distances in the absence of an axial magnetic field. The dependence of the spatial resolution as a function of drift distance allows the determination of the underlying electron statistics. Our results show that the present technique uses about half the statistical power available from the number of primary electrons. The track angle effect is observed as expected.Comment: 18 pages, 8 figures, version as published in Nucl. Inst. Met

Controlled Growth, Patterning and Placement of Carbon Nanotube Thin Films

Controlled growth, patterning and placement of carbon nanotube (CNT) thin films for electronic applications are demonstrated. The density of CNT films is controlled by optimizing the feed gas composition as well as the concentration of growth catalyst in a chemical vapor deposition process. Densities of CNTs ranging from 0.02 CNTs/{\mu}m^2 to 1.29 CNTs/{\mu}m^2 are obtained. The resulting pristine CNT thin films are then successfully patterned using either pre-growth or post-growth techniques. By developing a layered photoresist process that is compatible with ferric nitrate catalyst, significant improvements over popular pre-growth patterning methods are obtained. Limitations of traditional post-growth patterning methods are circumvented by selective transfer printing of CNTs with either thermoplastic or metallic stamps. Resulting as-grown patterns of CNT thin films have edge roughness (< 1 {\mu}m) and resolution (< 5 {\mu}m) comparable to standard photolithography. Bottom gate CNT thin film devices are fabricated with field-effect mobilities up to 20 cm^2/Vs and on/off ratios of the order of 10^3. The patterning and transfer printing methods discussed here have a potential to be generalized to include other nanomaterials in new device configurations

A Performance Comparison Using HPC Benchmarks: Windows HPC Server 2008 and Red Hat Enterprise Linux 5

This document was developed with support from the National Science Foundation (NSF) under Grant No. 0910812 to Indiana University for ”FutureGrid: An Experimental, High-Performance Grid Test-bed.” Any opinions, findings, and conclusions or recommendations expressed in this material are those of the author(s) and do not necessarily reflect the views of the NSF.A collection of performance benchmarks have been run on an IBM System X iDataPlex cluster using two different operating systems. Windows HPC Server 2008 (WinHPC) and Red Hat Enterprise Linux v5.4 (RHEL5) are compared using SPEC MPI2007 v1.1, the High Performance Computing Challenge (HPCC) and National Science Foundation (NSF) acceptance test benchmark suites. Overall, we find the performance of WinHPC and RHEL5 to be equivalent but significant performance differences exist when analyzing specific applications. We focus on presenting the results from the application benchmarks and include the results of the HPCC microbenchmark for completeness

A Comparison of the LVDP and {\Lambda}CDM Cosmological Models

We compare the cosmological kinematics obtained via our law of linearly varying deceleration parameter (LVDP) with the kinematics obtained in the {\Lambda}CDM model. We show that the LVDP model is almost indistinguishable from the {\Lambda}CDM model up to the near future of our universe as far as the current observations are concerned, though their predictions differ tremendously into the far future.Comment: 6 pages, 5 figures, 1 table, matches the version to be published in International Journal of Theoretical Physic

Cosmological models with linearly varying deceleration parameter

We propose a new law for the deceleration parameter that varies linearly with time and covers Berman's law where it is constant. Our law not only allows one to generalize many exact solutions that were obtained assuming constant deceleration parameter, but also gives a better fit with data (from SNIa, BAO and CMB), particularly concerning the late time behavior of the universe. According to our law only the spatially closed and flat universes are allowed; in both cases the cosmological fluid we obtain exhibits quintom like behavior and the universe ends with a big-rip. This is a result consistent with recent cosmological observations.Comment: 12 pages, 7 figures; some typo corrections; to appear in International Journal of Theoretical Physic

Full Stark control of polariton states on a spin-orbit hypersphere

The orbital angular momentum and the polarization of light are physical quantities widely investigated for classical and quantum information processing. In this work we propose to take advantage of strong light-matter coupling, circular-symmetric confinement, and transverse-electric transverse-magnetic splitting to exploit states where these two degrees of freedom are combined. To this end we develop a model based on a spin-orbit Poincaré hypersphere. Then we consider the example of semiconductor polariton systems and demonstrate full ultrafast Stark control of spin-orbit states. Moreover, by controlling states on three different spin-orbit spheres and switching from one sphere to another we demonstrate the control of different logic bits within one single physical system